Modified polyesters

Claim 2

A novel modified polyester resin comprising the reaction product of (A) an imide derived from an alkanolamine and an imide-forming reactant selected from phthalic acid, trimellitic acid, pyromellitic acid, maleic acid, succinic acid, anhydrides of the foregoing, and mixtures thereof, said imide having the formula ##STR10## whereln R represents a branched alkyl group having about 2 to 10 carbon atoms; Y represents the residue of said imide-forming reactant; and Z represents hydrogen or the residue of a carboxylic acid or derivative thereof, provided that said imide provides at least one hydroxyl or carboxyl group which is available for reaction; (B) a polyester-forming polyol; (C) a polyester-forming multifunctional acid or derivative thereof; and, optionally, (D) a fatty oil or an unsaturated fatty acid having about 12 to 24 carbon atoms derived from said oil, wherein said alkanolamine is provided in an amount of about 0.5 to 30 percent by weight, based upon the total weight of reactants, and wherein said fatty oil or acid, if present, comprises about 30 to 60 percent by weight of said resin.

Claim 3

The resin of claim 1 wherein said alkanolamine comprises 2-aminomethyl-2-ethyl-1-hexanol, 2-aminomethyl-2-ethyl-1-pentanol, 2-aminomethyl-2-ethyl-1-butanol, 2-aminomethyl-2-methyl-1-butanol, 2,2-dimethyl-3-amino-1-propanol, or a mixture thereof.

Claim 4

The resin of claim 1 wherein said imide-forming reactant comprises phthalic anhydride, trimellitic anhydride, pyromellitic dianhydride, succinic anhydride, maleic anhydride, or a mixture thereof.

Claim 5

The resin of claim 1 wherein said imide has the formula ##STR11## wherein R represents a branched alkyl group having about 2 to 10 carbon atoms; X represents a carboxylic acid moiety, wherein n is 0 to 2; and Z represents hydrogen or the residue of a carboxylic acid or derivative thereof, provided that said imide provides at least one hydroxyl or carboxyl group which is available for reaction.

Claim 6

The resin of claim 4 wherein said imide-forming reactant comprises phthalic anhydride, trimellitic anhydride, pyromellitic dianhydride, or a mixture thereof.

Claim 7

The resin of claim 1 wherein said polyester-forming polyol comprises trimethylolpropane, trimethylolethane, pentaerythritol, 1,2-propylene glycol, neopentyl glycol, or a mixture thereof.

Claim 8

The resin of claim 1 wherein said polyester-forming multifunctional acid or derivative thereof comprises trimellitic anhydride, phthalic anhydride, isophthalic acid, adipic acid, azelaic acid, terephthalic acid, or a mixture thereof.

Claim 9

The resin of claim 1 wherein said fatty acid comprises linoleic acid, linolenic acid, oleic acid, or a mixture thereof.

Claim 10

The resin of claim 1 wherein said resin exhibits a number average molecular weight of about 600 to 3000.

Claim 11

A novel modified polyester resin comprising the reaction product of (A) an imide derived from (i) an alkanolamine comprising 2-aminomethyl-2-ethyl-1-hexanol, 2-aminomethyl-2-ethyl-1-pentanol, 2-aminomethyl-2-ethyl-1-butanol, 2-aminomethyl-2-methyl-1-butanol, 2,2-dimethyl-3-amino-1-propanol, or a mixture thereof, and (ii) an imide-forming reactant comprising phthalic anhydride, trimellitic anhydride, pyromellitic dianhydride, succinic anhydride, maleic anhydride, or a mixture thereof, wherein said imide provides at least one hydroxyl or carboxyl group which is available for reaction; (B) a polyol comprising trimethylolpropane, trimethylolethane, pentaerythritol, 1,2-propylene glycol, neopentyl glycol, or a mixture thereof; (C) a multifunctional acid or derivative thereof comprising trimellitic anhydride, phthalic anhydride, isophthalic acid, terephthalic acid, azelaic acid, adipic acid, or a mixture thereof; and, optionally, (D) an unsaturated fatty acid comprising linoleic acid, linolenic acid, oleic acid, or a mixture thereof, wherein said alkanolamine is provided in an amount of about 0.5 to 30 percent by weight, based upon the total weight of reactants, and wherein said unsaturated fatty acid, if present, comprises about 30 to 60 percent by weight of said resin.

Claim 12

A novel modified polyester resin comprising the reaction product of (A) an imide derived from (i) an alkanolamine comprising 2-aminomethyl-2-ethyl-1-hexanol, 2-aminomethyl-2-ethyl-1-pentanol, 2-aminomethyl-2-ethyl-1-butanol, 2-aminomethyl-2-methyl-1-butanol, 2,2-dimethyl-3-amino-1-propanol, or a mixture thereof, and (ii) an imide-forming reactant comprising phthalic anhydride, trimellitic anhydride, pyromellitic dianhydride, succinic anhydride, maleic anhydride, or a mixture thereof, wherein said imide provides at least one hydroxyl or carboxyl group which is available for reaction; (B) a polyol comprising trimethylolpropane, trimethylolethane, pentaerythritol, 1,2-propylene glycol, neopentyl glycol, or a mixture thereof; (C) a multifunctional acid or derivative thereof comprising trimellitic anhydride, phthalic anhydride, isophthalic acid, terephthalic acid, azelaic acid, adipic acid, or a mixture thereof; and, optionally, (D) an unsaturated fatty acid comprising linoleic acid, linolenic acid, oleic acid, or a mixture thereof, wherein said alkanolamine is provided in an amount of about 0.5 to 30 percent by weight, based upon the total weight of reactants, and wherein said unsaturated fatty acid, if present, comprises about 30 to 60 percent by weight of said resin.

Claim 13

The resin of claim 10 wherein said alkanolamine is provided in an amount of about 5 to 15 percent by weight.

Claim 14

The resin of claim 10 wherein said alkanolamine comprises 2,2-dimethyl-3-amino-1-propanol.

Claim 15

The resin of claim 12 wherein said imide-forming reactant comprises phthalic anhydride.

Claim 16

The resin of claim 13 wherein said imide has the formula ##STR12## where M represents hydrogen or the residue of a multifunctional acid or derivative thereof.

Claim 17

The resin of claim 12 wherein said imide-forming reactant comprises trimellitic anhydride.

Claim 18

The resin of claim 15 wherein said imide has the formula ##STR13## where Z represents hydrogen or the residue of a carboxylic acid or derivative thereof.

Claim 19

The resin of claim 10 wherein said fatty acid, if present, comprises about 40 to 50 percent by weight of said resin.

Claim 20

The resin of claim 10 wherein said resin exhibits a number average molecular weight of about 600 to 3000.

Claim 21

The resin of claim 18 wherein said resin exhibits a number average molecular weight of about 1250 to 2250.

Claim 22

The resin of claim 10 wherein said resin has an acid number less than about 20.

Claim 23

A novel modified polyester resin comprising the reaction product of (A) an imide having the formula ##STR14## where M represents hydrogen or the residue of a multifunctional carboxylic acid or derivative thereof, or ##STR15## where Z represents hydrogen or the residue of a carboxylic acid or derivative thereof; (B) a polyol comprising trimethylolpropane, trimethylolethane, pentaerythritol, 1,2-propylene glycol, neopentyl glycol, or a mixture thereof; (C) a multifunctional acid or derivative thereof comprising phthalic anhydride, trimellitic anhydride, terephthalic acid, isophthalic acid, azelaic acid, adipic acid, or a mixture thereof; and, optionally, (D) 40 to 50 percent by weight of an unsaturated fatty acid comprising linoleic acid, linolenic acid, oleic acid, or a mixture thereof, wherein said imide is provided in an amount such that the alkanoxyamino moiety thereof comprises about 5 to 15 percent by weight of said resin and wherein said resin exhibits a number average molecular weight of about 1250 to 2250 and an acid number less than about 20.

Claim 24

A novel modified polyester resin comprising the reaction product of (A) an imide having the formula ##STR14## where M represents hydrogen or the residue of a multifunctional carboxylic acid or derivative thereof, or ##STR15## where Z represents hydrogen or the residue of a carboxylic acid or derivative thereof; (B) a polyol comprising trimethylolpropane, trimethylolethane, pentaerythritol, 1,2-propylene glycol, neopentyl glycol, or a mixture thereof; (C) a multifunctional acid or derivative thereof comprising phthalic anhydride, trimellitic anhydride, terephthalic acid, isophthalic acid, azelaic acid, adipic acid, or a mixture thereof; and, optionally, (D) 40 to 50 percent by weight of an unsaturated fatty acid comprising linoleic acid, linolenic acid, oleic acid, or a mixture thereof, wherein said imide is provided in an amount such that the alkanoxyamino moiety thereof comprises about 5 to 15 percent by weight of said resin and wherein said resin exhibits a number average molecular weight of about 1250 to 2250 and an acid number less than about 20.

Claim 25

A novel modified polyester resin comprising the reaction product of (A) an amide derived from an alkanolamine and an amide-forming reactant, said amide having the formula ##STR16## wherein R represents a branched alkyl group having about 2 to 10 carbon atoms, Z represents hydrogen or the residue of a carboxylic acid or derivative thereof, and A represents the residue of a carboxylic acid or derivative thereof, provided that said amide provides at least one hydroxyl or carboxyl group which is available for reaction; (B) a polyester-forming polyol; (C) a polyester-forming multifunctional acid or derivative thereof; and, optionally, (D) a fatty oil or an unsaturated fatty acid having about 12 to 24 carbon atoms derived from said oil, wherein said alkanolamine is provided in an amount of about 0.5 to 30 percent by weight, based upon the total weight of reactants, and wherein said fatty oil or acid, if present, comprises about 30 to 60 percent by weight of said resin.

Claim 26

A novel modified polyester resin comprising the reaction product of (A) an amide derived from an alkanolamine and an amide-forming reactant, said amide having the formula ##STR16## wherein R represents a branched alkyl group having about 2 to 10 carbon atoms, Z represents hydrogen or the residue of a carboxylic acid or derivative thereof, and A represents the residue of a carboxylic acid or derivative thereof, provided that said amide provides at least one hydroxyl or carboxyl group which is available for reaction; (B) a polyester-forming polyol; (C) a polyester-forming multifunctional acid or derivative thereof; and, optionally, (D) a fatty oil or an unsaturated fatty acid having about 12 to 24 carbon atoms derived from said oil, wherein said alkanolamine is provided in an amount of about 0.5 to 30 percent by weight, based upon the total weight of reactants, and wherein said fatty oil or acid, if present, comprises about 30 to 60 percent by weight of said resin.

Claim 27

The resin of claim 22 wherein said alkanolamine comprises 2-aminomethyl-2-ethyl-1-hexanol, 2-aminomethyl-2-ethyl-1-pentanol, 2-aminomethyl-2-ethyl-1-butanol, 2-aminomethyl-2-methyl-1-butanol, 2,2-dimethyl-3-amino-1-propanol, or a mixture thereof.

Claim 28

The resin of claim 23 wherein said alkanolamine comprises 2,2-dimethyl-3-amino-1-propanol.

Claim 29

The resin of claim 22 wherein said alkanolamine is provided in an amount of about 5 to 15 percent by weight.

Claim 30

The resin of claim 22 wherein said amide-forming reactant comprises isophthalic acid, terephthalic acid, adipic acid, azelaic acid, fumaric acid, sebacic acid, or a mixture thereof.

Claim 31

The resin of claim 22 wherein said polyester-forming polyol comprises trimethylolpropane, trimethylolethane, pentaerythritol, 1,2-propylene glycol, neopentyl glycol, or a mixture thereof.

Claim 32

The resin of claim 22 wherein said polyester-forming multifunctional acid or derivative thereof comprises trimellitic anhydride, phthalic anhydride, isophthalic acid, terephthalic acid, adipic acid, azelaic acid, or a mixture thereof.

Claim 33

The resin of claim 22 wherein said fatty acid comprises linoleic acid, linolenic acid, oleic acid, or a mixture thereof.

Claim 34

The resin of claim 22 wherein said fatty acid, if present comprises about 40 to 50 percent by weight of said resin.

Claim 35

The resin of claim 22 wherein said resin exhibits a number average molecular weight of about 600 to 3000.

Claim 36

The resin of claim 31 wherein said resin exhibits a number average molecular weight of about 1250 to 2250.

Claim 37

The resin of claim 22 wherein said resin has an acid number less than about 10.