Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
473 words
A photo-stabilized polymer composition comprising a polymer and as an ultraviolet absorber, at least one compound selected from the group consisting of cyclic imino esters represented by the following formula (I) ##STR43## wherein X 1 represents 1,2-phenylene, 1,2-naphthylene, 2,3-naphthylene, a group represented by the formula (a) ##STR44## wherein R is --O--, --CO--, --S--, --SO 2 --, --CH 2 --, --CH 2 ) 2 or --C(CH 3 ) 2 --, or a group represented by the formula (b) ##STR45## wherein R is as defined above, n is 1, 2 or 3, R 1 represents a hydrocarbon residue having a valence of n, or when n is 1, R 1 further represents a residue selected from the group consisting of a group represented by the formula (c) ##STR46## wherein R 4 represents an alkylene of 2 to 10 carbon atoms, phenylene or naphthylene, a group of the formula (d) ##STR47## wherein R 5 represents an alkyl having 1 to 10 carbon atoms, a phenyl or a naphthyl, a group of the formula (e) ##STR48## wherein R 4 and R 5 are as defined above, and R 6 is hydrogen atom or any one of the groups defined for R 5 , and a group represented by the formula (f) ##STR49## wherein R 4 and R 6 are as defined above, and R 7 is hydrogen atom or any one of the groups defined for R 5 , and when n is 2, R 1 further represents a direct bond, a residue selected from the group consisting of a group represented by the formula (g) ##STR50## wherein R 8 is any one of the groups defined for R 4 , and a group represented by the formula (h) ##STR51## wherein R 8 is as defined above, R 9 is any one of the groups defined for R 4 , and R 10 is any one of the groups defined for R 6 , wherein each of the above groups defined for X 1 and R 1 may be substituted by a substituent selected from the group consisting of alkyl groups having 1 to 10 carbon atoms, aryl groups having 6 to 12 carbon atoms, cycloalkyl groups having 5 to 12 carbon atoms, aralkyl groups having 8 to 20 carbon atoms, alkoxy groups having 1 to 10 carbon atoms, carboacyl groups having 2 to 10 carbon atoms, halogen atoms and nitro groups, and cyclic imino esters represented by the following formula (II) ##STR52## wherein A represents a group of the following formula (II)-a ##STR53## or a group of the following formula (II)-b ##STR54## wherein R 2 and R 3 are identical or different and each represents a monovalent hydrocarbon residue; and X 2 represents a tetravalent aromatic residue selected from the groups represented by the formulae: ##STR55## wherein R is as defined above, in the unreacted state.
Claim 2
Dependent Claim
473 words
A photo-stabilized polymer composition comprising a polymer and as an ultraviolet absorber, at least one compound selected from the group consisting of cyclic imino esters represented by the following formula (I) ##STR43## wherein X 1 represents 1,2-phenylene, 1,2-naphthylene, 2,3-naphthylene, a group represented by the formula (a) ##STR44## wherein R is --O--, --CO--, --S--, --SO 2 --, --CH 2 --, --CH 2 ) 2 or --C(CH 3 ) 2 --, or a group represented by the formula (b) ##STR45## wherein R is as defined above, n is 1, 2 or 3, R 1 represents a hydrocarbon residue having a valence of n, or when n is 1, R 1 further represents a residue selected from the group consisting of a group represented by the formula (c) ##STR46## wherein R 4 represents an alkylene of 2 to 10 carbon atoms, phenylene or naphthylene, a group of the formula (d) ##STR47## wherein R 5 represents an alkyl having 1 to 10 carbon atoms, a phenyl or a naphthyl, a group of the formula (e) ##STR48## wherein R 4 and R 5 are as defined above, and R 6 is hydrogen atom or any one of the groups defined for R 5 , and a group represented by the formula (f) ##STR49## wherein R 4 and R 6 are as defined above, and R 7 is hydrogen atom or any one of the groups defined for R 5 , and when n is 2, R 1 further represents a direct bond, a residue selected from the group consisting of a group represented by the formula (g) ##STR50## wherein R 8 is any one of the groups defined for R 4 , and a group represented by the formula (h) ##STR51## wherein R 8 is as defined above, R 9 is any one of the groups defined for R 4 , and R 10 is any one of the groups defined for R 6 , wherein each of the above groups defined for X 1 and R 1 may be substituted by a substituent selected from the group consisting of alkyl groups having 1 to 10 carbon atoms, aryl groups having 6 to 12 carbon atoms, cycloalkyl groups having 5 to 12 carbon atoms, aralkyl groups having 8 to 20 carbon atoms, alkoxy groups having 1 to 10 carbon atoms, carboacyl groups having 2 to 10 carbon atoms, halogen atoms and nitro groups, and cyclic imino esters represented by the following formula (II) ##STR52## wherein A represents a group of the following formula (II)-a ##STR53## or a group of the following formula (II)-b ##STR54## wherein R 2 and R 3 are identical or different and each represents a monovalent hydrocarbon residue; and X 2 represents a tetravalent aromatic residue selected from the groups represented by the formulae: ##STR55## wherein R is as defined above, in the unreacted state.
Claim 3
Dependent Claim
30 words
The composition of claim 1 wherein the ultraviolet absorber is at least one compound of formula (I), and R 1 is an aromatic hydrocarbon residue having a valence of n.
Claim 4
Dependent Claim
17 words
The composition of claim 2 wherein in formula (I), R 1 is a divalent aromatic hydrocarbon residue.
Claim 5
Dependent Claim
29 words
The composition of claim 2 wherein in formula (I), R 1 is a divalent aromatic hydrocarbon residue in which the two bonds extend from positions farthest from each other.
Claim 6
Dependent Claim
28 words
The composition of claim 1 wherein the amount of the cyclic imino ester is 0.05 to 5 parts by weight per 100 parts by weight of the polymer.
Claim 7
Dependent Claim
25 words
The composition of claim 1 wherein the amount of the cyclic imino ester is 0.1 to 3 parts by weight per 100 parts by weight.
Claim 8
Dependent Claim
19 words
The composition of claim 1 wherein the polymer is a thermoplastic resin, a thermosetting resin or an uncured elastomer.
Claim 9
Dependent Claim
22 words
The composition of claim 7 wherein the polymer is a thermoplastic resin which is a polyester, polyamide, polycarbonate, polyolefin, polyether or polysulfone.
Claim 10
Dependent Claim
29 words
The composition of claim 7 wherein the polymer is a thermosetting resin which is a phenol-formaldehyde resin, melamine resin, polyurethan resin, urea resin, epoxy resin or unsaturated polyester resin.
Claim 11
Dependent Claim
19 words
The composition of claim 7 wherein the polymer is an uncured elastomer which is a natural or synthetic rubber.
Claim 12
Dependent Claim
66 words
A method for protecting from ultraviolet light a molded article of a polymer whose deterioration by ultraviolet light is required to be retarded or prevented, which comprises applying to said polymer article an amount, effective for retarding or preventing said ultraviolet deterioration, of at least one compound selected from the cyclic imino esters of formulae (I) and (II) defined in claim 1 in the unreacted state.
Claim 13
Dependent Claim
17 words
The method of claim 11 wherein said polymer is a substantially linear polymer or a crosslinked polymer.
Claim 14
Dependent Claim
16 words
The method of claim 12 wherein the polymer is the substantially linear polymer which is thermoplastic.
Claim 15
Dependent Claim
19 words
The method of claim 13 wherein the substantially linear polymer is a polyester, polyamide, polycarbonate, polyolefin, polyether or polysulfone.
Claim 16
Dependent Claim
22 words
The method of claim 12 wherein the polymer is the crosslinked polymer which is a cured thermosetting resin or a cured elastomer.
Claim 17
Dependent Claim
30 words
The method of claim 15 wherein the crosslinked polymer is the thermosetting resin which is a phenol-formaldehyde resin, melamine resin, polyurethan resin, urea resin, epoxy resin or unsaturated polyester resin.
Claim 18
Dependent Claim
21 words
The method of claim 15 wherein the crosslinked polymer is a cured elastomer which is a cured natural or synthetic rubber.
Claim 19
Dependent Claim
35 words
The method of claim 11 wherein the application of the cyclic imino ester to the polymer article is effected by incorporating the cyclic imino ester in the unreacted state in the polymer of the article.
Claim 20
Dependent Claim
35 words
The method of claim 11 wherein the application of the cyclic imino ester to the polymer article is effected by forming a coating containing the cyclic imino ester on the surface of the polymer article.
Claim 21
Dependent Claim
32 words
The method of claim 11 wherein the amount of the cyclic imino ester applied is 0.05 to 5 parts by weight per 100 parts by weight of the polymer of the article.
Claim 22
Dependent Claim
59 words
A method for protecting from ultraviolet light an object subject to deleterious effects under ultraviolet light, which comprises substantially shielding said object from ultraviolet light by means of a polymer article to which at least one compound selected from the cyclic imino esters of formulae (I) and (II) defined in claim 1 has been applied in the unreacted state.
Claim 23
Dependent Claim
17 words
The method of claim 21 wherein the polymer article is substantially transparent or semitransparent to visible light.
Claim 24
Dependent Claim
17 words
The method of claim 21 or 22 wherein the polymer article is a planar or hollow article.
Claim 25
Dependent Claim
32 words
The method of claim 21 wherein the amount of the cyclic imino ester applied is 0.05 to 5 parts by weight per 100 parts by weight of the polymer of the article.
Claim 26
Dependent Claim
30 words
The method of claim 11 or 21 wherein the cyclic imino ester is a compound of the following formula (I)-1 ##STR56## wherein R 11 represents a divalent aromatic hydrocarbon residue.
Claim 27
Dependent Claim
29 words
The method of claim 25 wherein in formula (I)-1, R 11 is a divalent aromatic hydrocarbon residue in which the two bands extend from positions farthest from each other.
Claim 28
Dependent Claim
16 words
The method of claim 26 wherein in formula (I)-1, R 11 is p-phenylene, p,p'-biphenylene, or 2,6-naphthylene.
Claim 29
Dependent Claim
19 words
The composition of claim 1 wherein the ultraviolet absorber is at least one cyclic imino ester of formula (II).