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US4446218A Expired / Lapsed US ⏱️ 0.0 years remaining

Sulfur and/or amide-containing exposure accelerators for light-sensitive coatings with diazonium compounds

Assignee: CNA Holdings LLC
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Filing: 1982-03-18
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Granted: 1984-05-01
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Expires: 2002-03-18
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Abstract

Abstract This invention relates to proof film-type light sensitive diazonium materials containing accelerators selected from sulfur and/or amide-containing compounds which are capable of accelerating the contact exposure of negative-working diazonium compounds when such diazonium compounds are subjected to UV radiation. These accelerators enhance essentially photosensitivity speed. The invention also relates to presensitized reproduction materials comprising diazonium materials containing these accelerators.

Inventors

  • 👤 Major S. Dhillon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 01:15
CPC Classifications
G; G03; G03F; G03F3/00; G03F3/10; G03F7/00; G03F7/004; G03F7/016; G03F7/0166

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 102 words
A composition comprising a light sensitive diazonium compound and an accelerator selected from the group consisting of 1,1-thiobis(2-naphthol), diresorcinol sulfide, diphenyl sulfone, phenothiazine, dibenzothiophene sulfone, N-(3-hydroxyphenyl)-2-hydroxy-3-naphthamide, 2,3-dihydroxy naphthoic acid ethanolamide, N,N'-ethylene-bis-acetoacetamide, 4-bromo-3,5-resorcyclic acid ethanolamide, 3,5-resorcyclic acid ethanolamide 2,4-resorcyclic acid ethanol amide, acetoacetbenzylamide, 2-mercaptobenzothiazole, and 2-benzoxazolethiol, wherein said diazonium compound is selected from the group consisting of the condensation products of Formula I, Formula II and Formula IV as set forth herein such that said accelerator is present in said composition in an amount from about 0.005 to about 1.5 parts by weight of accelerator per part by weight of said diazonium compound.
Claim 2
Dependent Claim 102 words
A composition comprising a light sensitive diazonium compound and an accelerator selected from the group consisting of 1,1-thiobis(2-naphthol), diresorcinol sulfide, diphenyl sulfone, phenothiazine, dibenzothiophene sulfone, N-(3-hydroxyphenyl)-2-hydroxy-3-naphthamide, 2,3-dihydroxy naphthoic acid ethanolamide, N,N'-ethylene-bis-acetoacetamide, 4-bromo-3,5-resorcyclic acid ethanolamide, 3,5-resorcyclic acid ethanolamide 2,4-resorcyclic acid ethanol amide, acetoacetbenzylamide, 2-mercaptobenzothiazole, and 2-benzoxazolethiol, wherein said diazonium compound is selected from the group consisting of the condensation products of Formula I, Formula II and Formula IV as set forth herein such that said accelerator is present in said composition in an amount from about 0.005 to about 1.5 parts by weight of accelerator per part by weight of said diazonium compound.
Claim 3
Dependent Claim 40 words
The composition of claim 1 wherein said accelerator is selected from the group consisting of 1,1-thiobis(2-naphthol), diresorcinol sulfide, phenothiazine, dibenzothiophene sulfone, N-(3-hydroxyphenyl)-2-hydroxy-3-naphthamide, 2,3-dihydroxy naphthoic acid ethanolamide, N,N'-ethylene-bis-acetoacetamide, 4-bromo-3,5-resorcyclic acid amide, 3,5-resorcyclic acid ethanolamide, 2,4-resorcyclic acid ethanolamide, acetoacetbenzylamide, 2-mercaptobenzothiazole, and 2-benzoxathiazolethiol.
Claim 4
Dependent Claim 19 words
A light sensitive reproduction material comprising a support and a reproduction layer thereon having the composition of claim 1.
Claim 5
Dependent Claim 36 words
The reproduction material of claim 3 wherein said support is selected from the group of supports which are comprised of aluminum, polyester, polystyrene, polyamide, polycarbonate, polypropylene, cellulose acetate films, glass, metal coated material and the like.
Claim 6
Dependent Claim 34 words
The reproduction material of claim 4 wherein said reproduction layer contains the accelerator which is present at a level of about 0.005 to about 1.5 by weight per part by weight of diazonium compound.
Claim 7
Dependent Claim 10 words
The composition of claim 1 wherein said accelerator is phenothiazine.
Claim 8
Dependent Claim 10 words
The composition of claim 1 wherein said accelerator is 1,1-thiobis(2-naphthol).
Claim 9
Dependent Claim 10 words
The composition of claim 1 wherein said accelerator is 2-mercaptobenzothiazol.
Claim 10
Dependent Claim 14 words
The composition of claim 1 wherein said accelerator is 3,5 resorcylic acid ethanol amide.
Claim 11
Dependent Claim 20 words
The composition of claim 1 wherein said diazonium compound is the condensation product of Formula I as set forth herein.
Claim 12
Dependent Claim 20 words
The composition of claim 1 wherein said diazonium compound is the condensation product of Formula II as set forth herein.
Claim 13
Dependent Claim 20 words
The composition of claim 1 wherein said diazonium compound is the condensation product of Formula IV as set forth herein.
Claim 14
Dependent Claim 20 words
The composition of claim 6 wherein said diazonium compound is the condensation product of Formula IV as set forth herein.
Claim 15
Dependent Claim 20 words
The composition of claim 7 wherein said diazonium compound is the condensation product of Formula IV as set forth herein.
Claim 16
Dependent Claim 20 words
The composition of claim 8 wherein said diazonium compound is the condensation product of Formula IV as set forth herein.
Claim 17
Dependent Claim 20 words
The composition of claim 9 wherein said diazonium compound is the condensation product of Formula IV as set forth herein.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-01 1987-10-31 1988-05-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-01 1991-10-31 1992-05-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-01 1995-10-31 1996-05-01 $7700.00 Window Closed / Lapsed

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