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US4444930A
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Fire-resistant synthetic resin composition containing a polycarbonate, a phosphorous fireproofing additive, and possibly other additives and/or fillers, and articles made from this composition
Assignee: ATO Chimie SA
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Filing: 1982-08-24
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Granted: 1984-04-24
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Expires: 2002-08-24
Abstract
Abstract The invention relates to a fire-resistant synthetic resin composition containing a polycarbonate, more specifically a bisphenol A derivative, a phosphorous fireproofing additive derived from phosphonic acid, and possibly other additives and/or fillers. The fireproofing additive is a Li, Na or K hemiester of a phosphonic acid derived from an aromatic or cycloaliphatic hydrocarbon, or from a polynuclear aromatic compound, and is added at the rate of 0.01 to 0.4 weight % in relation to polycarbonate. This small amount of additive improves the fire-resistant properties of the polycarbonate, without affecting its mechanical properties.
Inventors
- 👤 Bernard Guerin
- 👤 Pierre Poisson
- 👤 Georges Sturtz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 08:54
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/49; C08K5/51; C08K5/53; C08K5/5317; C08K5/5333
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
210 words
A fire-resistant synthetic resin composition, containing a polycarbonate, a non-reactive fireproofing additive derived from phosphonic acid, and possibly other additives and/or fillers, and characterized by the fact that the fireproofing additive has the general formula ##STR23## where Y is a q-valent organic radical, derived, by the loss of q hydrogen atoms, from one of the group consisting of cycloalkanes containing 6 to 8 carbon atoms, benzene hydrocarbons containing 6 to 12 carbon atoms, di- or trinuclear aromatic hydrocarbons with enchained nuclei containing 12 to 20 carbon atoms, di- or trinuclear aromatic hydrocarbons with condensed nuclei containing 10 to 20 carbon atoms, aromatic compounds with the formula Ar-Z-Ar, in which Ar is a monovalent aryl radical containing 6 to 12 carbon atoms, and Z represents --S--, --O--, --SO 2 --, --SO--, --CO--, and brominated or chlorinated derivatives of such aromatic hydrocarbons and compounds; q is a number equal to 1, 2, 3; n is a number equal to 0, 1, 2; R is an alkyl radical containing 1 to 6 carbon atoms, a phenyl radical or a cyclohexyl radical; and M is an atom of an alkaline metal belonging to the group comprising Li, Na and K, the concentration of this additive in the polycarbonate being between 0.01 and 0.4 weight%.
Claim 2
Dependent Claim
210 words
A fire-resistant synthetic resin composition, containing a polycarbonate, a non-reactive fireproofing additive derived from phosphonic acid, and possibly other additives and/or fillers, and characterized by the fact that the fireproofing additive has the general formula ##STR23## where Y is a q-valent organic radical, derived, by the loss of q hydrogen atoms, from one of the group consisting of cycloalkanes containing 6 to 8 carbon atoms, benzene hydrocarbons containing 6 to 12 carbon atoms, di- or trinuclear aromatic hydrocarbons with enchained nuclei containing 12 to 20 carbon atoms, di- or trinuclear aromatic hydrocarbons with condensed nuclei containing 10 to 20 carbon atoms, aromatic compounds with the formula Ar-Z-Ar, in which Ar is a monovalent aryl radical containing 6 to 12 carbon atoms, and Z represents --S--, --O--, --SO 2 --, --SO--, --CO--, and brominated or chlorinated derivatives of such aromatic hydrocarbons and compounds; q is a number equal to 1, 2, 3; n is a number equal to 0, 1, 2; R is an alkyl radical containing 1 to 6 carbon atoms, a phenyl radical or a cyclohexyl radical; and M is an atom of an alkaline metal belonging to the group comprising Li, Na and K, the concentration of this additive in the polycarbonate being between 0.01 and 0.4 weight%.
Claim 3
Dependent Claim
61 words
A composition as defined in claim 1, in which the fireproofing additive is selected from those with the formula ##STR24## where Y 1 is a monovalent radical derived, by the loss of a nuclear hydrogen atom, from a compound belonging to the group consisting of benzene, toluene, ethylbenzene, bromobenzene, cyclohexane and diphenylether, and R 1 is a methyl or ethyl radical.
Claim 4
Dependent Claim
66 words
A composition as defined in claim 1, in which the fireproofing additive is selected from those with the formula ##STR25## where Y 2 is a divalent radical derived, by the loss of two hydrogen atoms, each located in a different nucleus, from a compound belonging to the group consisting of diphenyl, diphenyloxide, diphenylsulphone, diphenyl-2.2 propane and naphthalene, and R 1 is a methyl or ethyl radical.
Claim 5
Dependent Claim
39 words
A composition as defined in claim 1, in which the fireproofing additive is selected from those with the formula ##STR26## where m is a number equal to 0 or 1, and R 1 is a methyl or ethyl radical.
Claim 6
Dependent Claim
39 words
A composition as defined in claim 1, in which the fireproofing additive is selected from those with the formula ##STR27## where m is a number equal to 0 or 1, and R 1 is a methyl or ethyl radical.
Claim 7
Dependent Claim
23 words
A composition as defined in any one of claims 1 to 5, in which the alkaline metal atom M is a potassium atom.
Claim 8
Dependent Claim
59 words
A composition as defined in claim 1, in which the fireproofing additive is selected from the group comprising ethyl and potassium phenylphosphonate, ethyl and potassium benzylphosphonate, methyl and potassium benzylphosphonate, ethyl and potassium bromo-4 benzylphosphonate, diethyl and dipotassium paraxylylene diphosphonate, dimethyl and dipotassium paraxylylene diphosphonate, diethyl and dipotassium paraphenylene diphosphonate, ethyl and potassium cyclohexylmethylphosphonate, and diethyl and dipotassium diphenylene-4.4'diphosphonate,
Claim 9
Dependent Claim
43 words
A composition as defined in any one of claims 1 to 5, in which the polycarbonate is a polycarbonate or copolycarbonate derived from one or more bisphenols selected from the group comprising bis(hydroxy-4 phenyl)-2.2 propane, bis(dimethyl-3.5 hydroxy-4 phenyl)-2.2 propane, and bis(hydroxy-4 phenyl)-1.1 cyclohexane.
Claim 10
Dependent Claim
29 words
A composition as defined in any one of claims 1 to 5, in which the concentration of fireproofing additive is between 0.01 and 0.15 weight% in relation to polycarbonate.
Claim 11
Dependent Claim
32 words
A composition as defined in any one of claims 1 to 5, characterized by the fact that it contains between 10 and 35 weight % of glass fibre in relation to polycarbonate.
Claim 12
Dependent Claim
19 words
A composition as defined in claim 1, characterized by the fact that it contains an agent to reduce dripping.
Claim 13
Dependent Claim
30 words
A composition as defined in claim 11, in which the drip-reducing agent is a polytetrafluoroethylene, added at the rate of 0.1 to 1% in relation to the weight of polycarbonate.
Claim 14
Dependent Claim
14 words
Shaped articles manufactured from a fireproofed polycarbonate resin composition as defined in claim 1.
Claim 15
Dependent Claim
19 words
A composition as defined in claim 11, wherein the agent to reduce dripping is a polysiloxane or a polytetrafluoroethylene.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-04-24 | 1987-10-24 | 1988-04-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-04-24 | 1991-10-24 | 1992-04-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-04-24 | 1995-10-24 | 1996-04-24 | $7700.00 | Window Closed / Lapsed |