US4444862A
Expired / Lapsed
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Electrophotographic photosensitive materials having layer of organic metal compound
Assignee: Fujifilm Business Innovation Corp
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Filing: 1982-07-28
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Granted: 1984-04-24
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Expires: 2002-07-28
Abstract
Abstract An electrophotographic photosensitive material is disclosed. The material is comprised of a conductive support base. On the surface of the base is a photoconductive layer. On a surface of the photoconductive layer is an interlayer comprised of organic metal compound as its main component. On top of the interlayer is a low-resistant protective layer. The material can achieve electrostatic contrast greatly superior to that of conventional photosensitive materials.
Inventors
- 👤 Shigeru Yagi
- 👤 Koichi Yamamoto
- 👤 Yasutoshi Okugawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 22:01
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/14; G03G5/142; G03G5/147
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
48 words
An electrophotographic photosensitive material, comprising: a conductive support having a surface; a photoconductive layer formed on the surface; an interlayer formed on the photoconductive layer by curing a coating solution of an organic metal compound as its main component; and a low-resistance protective layer positioned over the interlayer.
Claim 2
Dependent Claim
48 words
An electrophotographic photosensitive material, comprising: a conductive support having a surface; a photoconductive layer formed on the surface; an interlayer formed on the photoconductive layer by curing a coating solution of an organic metal compound as its main component; and a low-resistance protective layer positioned over the interlayer.
Claim 3
Dependent Claim
70 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the organic metal compound is selected from the group consisting of aluminum tris(acetylacetonate), iron tris(acetylacetonate), cobalt bis(acetylacetonate), copper bis(acetylacetonate), magnesium bis(acetylacetonate), manganese(II) bis(acetylacetonate), nickel(II) bis(acetylacetonate), vanadium tris(acetylacetonate), zinc bis(acetylacetonate), tin bis(acetylacetonate), aluminum isopropylate, mono-sec-butoxy aluminum diisopropylate, aluminum sec-butyrate, ethylacetoacetate aluminum diisopropylate, vanadium ethylate, vanadium n-propylate, vanadium isobutyrate, aluminum di-n-butoxide mono-ethylacetoacetate, aluminum oxide octate, aluminum oxide stearate and aluminum oxide acrylate.
Claim 4
Dependent Claim
22 words
An electrophotographic photosensitive material as claimed in claim 2, wherein the organic metal compound is aluminum tri(acetylacetonate), cobalt bis(acetylacetonate) or zinc bis(acetylacetonate).
Claim 5
Dependent Claim
18 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the organic metal compound is an organotitanium compound.
Claim 6
Dependent Claim
28 words
An electrophotographic photosensitive material as claimed in claim 4, wherein the organotitanium compound is selected from the groups consisting of titanium orthoesters, polyorthotitanic acid esters, and titanium chelates.
Claim 7
Dependent Claim
40 words
An electrophotographic photosensitive material as claimed in claim 5, wherein the organotitanium compounds is selected from the group consisting of tetramethyl orthotitanate, tetraethyl orthotitanate, tetra-n-propyl orthotitanate, tetraisopropyl orthotitanate, tetrabutyl orthotitanate, tetraisobutyl orthotitanate, tetracresyl titanate, tetrabutyl polytitanate and diisopropoxy titane bis(acetylacetonate).
Claim 8
Dependent Claim
18 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the organic metal compound is an organozirconium compound.
Claim 9
Dependent Claim
25 words
An electrophotographic photosensitive material as claimed in claim 7, wherein the organozirconium compound is selected from the groups consisting of zirconium complexes and zirconium esters.
Claim 10
Dependent Claim
31 words
An electrophotographic photosensitive material as claimed in claim 8, wherein the organozirconium compound is selected from the group consisting of zirconium tetrakis(acetylacetonate), zirconium dibutoxy bis(acetylacetonate), zirconium tributoxy acetylacetonate and zirconium n-butyrate.
Claim 11
Dependent Claim
18 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the interlayer is 10 μm thick or less.
Claim 12
Dependent Claim
18 words
An electrophotographic photosensitive material as claimed in claim 10, wherein the interlayer is 1 μm thick or less.
Claim 13
Dependent Claim
24 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the interlayer has an electric resistance of from 10 8 to 10 14 Ωcm.
Claim 14
Dependent Claim
24 words
An electrophotographic photosensitive material as claimed in claim 12, wherein the interlayer has an electric resistance of from 10 10 to 10 13 Ωcm.
Claim 15
Dependent Claim
23 words
An electrophotographic photosensitive material as claimed in any of claims 1, 12 or 13, wherein the coating solution further contains a resistance-controlling agent.
Claim 16
Dependent Claim
26 words
An electrophotographic photosensitive material as claimed in claim 14, wherein the resistance-controlling agent is selected from the group consisting of silicate compounds and silane coupling agents.
Claim 17
Dependent Claim
25 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the coating solution further contains a catalyst for accelerating the curing reaction of the interlayer.
Claim 18
Dependent Claim
27 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the protective layer is composed of an organic polymer containing an electron donor and/or an electron acceptor.
Claim 19
Dependent Claim
35 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the protective layer is composed of an organic polymer having dispersed therein an metal or metal oxide having an average particle size below 0.3 μm.
Claim 20
Dependent Claim
25 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the photoconductive layer is a vacuum deposited layer of Se, Se-Te alloy, or Se-As alloy.
Claim 21
Dependent Claim
20 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the photoconductive layer is a layer of an organic photoconductor.
Claim 22
Dependent Claim
22 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the photoconductive layer is a layer of ZnO dispersed in a binder.
Claim 23
Dependent Claim
22 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the photoconductive layer is a layer of CdS dispersed in a binder.
Claim 24
Dependent Claim
18 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the protective layer is adjacent to the interlayer.
Claim 25
Dependent Claim
23 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the coating solution consists essentially of an organic metal compound and a solvent.
Claim 26
Dependent Claim
35 words
An electrophotographic photosensitive material as claimed in claim 16, wherein the catalyst is added in an amount of 1 to 10% by weight based on the weight of the solid component in the coating solution.
Claim 27
Dependent Claim
39 words
An electrophotographic photosensitive material as claimed in claim 17, wherein the organic polymer is selected from the group consisting of polystyrene, acryl resins, polyamides, polyesters, polyurethanes, polycarbonates, polyvinyl formal, polyvinyl acetal, polyvinyl butyral, ethyl cellulose, nitrocellulose and cellulose acetate.
Claim 28
Dependent Claim
122 words
An electrophotographic photosensitive material as claimed in claim 1, wherein the protective layer contains a material selected from the group consisting of metallocene and a compound having at least one metallocene skeleton in its molecular structure; tetrazole and a compound having at least one tetrazole skeleton in its molecular structure; a powder of a metal selected from the group consisting of gold, silver, aluminum, iron, copper and nickel having a mean particle size of less than 0.3μ; a powder of a metal oxide selected from the group consisting of zinc oxide, titanium oxide, tin oxide, bismuth oxide, indium oxide and antimony oxide having a mean particle size below 0.3μ; and a powder comprising tin oxide and antimony oxide in a single particle.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-04-24 | 1987-10-24 | 1988-04-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-04-24 | 1991-10-24 | 1992-04-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-04-24 | 1995-10-24 | 1996-04-24 | $7700.00 | Window Closed / Lapsed |