US4443640A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the preparation of an aromatic hydrocarbon mixture
Assignee: Shell USA Inc
•
Filing: 1982-05-07
•
Granted: 1984-04-17
•
Expires: 2002-05-07
Abstract
Abstract A process is disclosed for the preparation of aromatic hydrocarbon mixtures having high benzene content by contacting non-aromatic organic compounds with certain crystalline non-aluminum silicates having a SiO 2 /Fe 2 O 3 molar ratio of 100-300 and A SiO 2 /Al 2 O 3 molar ratio of 135-1900.
Inventors
- 👤 Johannes van der Meijden
- 👤 Auke F. de Vries
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 13:52
CPC Classifications
C; C10; C10G; C10G35/00; C10G35/04; C10G35/06; C10G35/065; B; B01; B01J; B01J29/00; B01J29/88; C07; C07C; C07C2/00; C07C2529/00; C07C2529/88; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
183 words
In a process for the preparation of an aromatic hydrocarbon mixture, which comprises contacting at a temperature in the range from about 300°-650° C., a pressure of from 1-50 bar, and a space velocity of from 0.1-10 g.g -1 .h -1 a feed comprising one or more non-aromatic organic compounds with a crystalline metal silicate which, after one hour's calcination in air at 500° C., has the following properties: (a) thermally stable up to a temperature of at least 600° C., (b) an X-ray powder diffraction pattern in which the strongest lines are the four lines listed in Table 1 of this specification; the improvement comprising that said product shall have enhanced benzene content when in the formula which represents the composition of the silicate, expressed in moles of the oxides, and which, in addition to SiO 2 , comprises both Fe 2 O 3 , and Al 2 O 3 , the SiO 2 /Fe 2 O 3 molar ratio is in the range of 100-300, and the SiO 2 /Al 2 O 3 molar ratio is in the range of 135-1900.
Claim 2
Dependent Claim
183 words
In a process for the preparation of an aromatic hydrocarbon mixture, which comprises contacting at a temperature in the range from about 300°-650° C., a pressure of from 1-50 bar, and a space velocity of from 0.1-10 g.g -1 .h -1 a feed comprising one or more non-aromatic organic compounds with a crystalline metal silicate which, after one hour's calcination in air at 500° C., has the following properties: (a) thermally stable up to a temperature of at least 600° C., (b) an X-ray powder diffraction pattern in which the strongest lines are the four lines listed in Table 1 of this specification; the improvement comprising that said product shall have enhanced benzene content when in the formula which represents the composition of the silicate, expressed in moles of the oxides, and which, in addition to SiO 2 , comprises both Fe 2 O 3 , and Al 2 O 3 , the SiO 2 /Fe 2 O 3 molar ratio is in the range of 100-300, and the SiO 2 /Al 2 O 3 molar ratio is in the range of 135-1900.
Claim 3
Dependent Claim
18 words
A process as in claim 1, wherein said feed comprises more than 20% w of non-aromatic organic compounds.
Claim 4
Dependent Claim
39 words
A process as in claim 1 or 2, wherein said feed is a hydrocarbon mixture in which the hydrocarbons contain at least three carbon atoms and in which a major portion of said hydrocarbon mixture boils below 250° C.
Claim 5
Dependent Claim
39 words
A process as in claim 3, characterized in that the feed is a hydrocarbon mixture in which the hydrocarbons contain at least four carbon atoms and in which a major portion of the hydrocarbon mixture boils below 225° C.
Claim 6
Dependent Claim
33 words
A process as in any one of claims 1-4, wherein said feed is a distillate hydrocarbon fraction obtained as a by-product in the preparation of ethene and/or propene by thermal cracking of hydrocarbons.
Claim 7
Dependent Claim
18 words
A process as in claim 5, wherein said feed is the C 5 fraction of a pyrolysis gasoline.
Claim 8
Dependent Claim
32 words
A process as in claim 5, wherein said feed is the C 5 fraction of a pyrolysis gasoline from which C 5 fraction at least part of the diolefins have been separated.
Claim 9
Dependent Claim
42 words
A process as in any one of claims 1-2, wherein in the overall formula of the crystalline metal silicate the SiO 2 /Fe 2 O 3 molar ratio is 120-250 and the SiO 2 /Al 2 O 3 molar ratio is 175-1500.
Claim 10
Dependent Claim
24 words
A process as in any one of claims 1-2, wherein the crystalline metal silicate has an alkali metal content of less than 0.05% w.
Claim 11
Dependent Claim
33 words
A process as in claim 9, carried out at a temperature of from 425°-600° C., a pressure of from 2.5-25 bar and a space velocity of from 0.5-5 g.g -1 1h -1 .
References Cited (Backward Citations)
US4208305A
Cited
EP0021475A1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-04-17 | 1987-10-17 | 1988-04-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-04-17 | 1991-10-17 | 1992-04-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-04-17 | 1995-10-17 | 1996-04-17 | $7700.00 | Window Closed / Lapsed |