← Back to Patent Explorer
US4443364A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent composition containing an antifoaming agent for cleaning hard surfaces and method of using the same

Assignee: Hoechst AG
•
Filing: 1981-12-14
•
Granted: 1984-04-17
•
Expires: 2001-12-14
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A detergent composition which is particularly suitable for the mechanical cleaning of hard surfaces, in particular glass, porcelain and the like, in a cleaning liquor within the alkaline range, is described. This detergent composition comprises (A) a nonionic surfactant selected from the group comprising polyalkylene glycol monoalkyl ethers containing ethylene oxide and propylene oxide units, polyglycol ether formals containing ethylene oxide units and, if appropriate, propylene oxide units, or polyalkylene glycol dialkyl ethers containing ethylene oxide units and, if appropriate, propylene oxide units, (B) a selected quaternary ammonium compound as a cationic surfactant, and (C) a fluorinated alcohol as an antifoaming agent. These compositions are particularly suitable for industrial crockery-cleaning and bottle-cleaning plants which are operated with considerable mechanical agitation of the liquor within a highly alkaline pH range.

Inventors

  • 👤 Wolfgang Klinger
  • 👤 Eckhard Milewski

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 22:20
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/24; C11D3/245; C11D1/00; C11D1/66; C11D1/835; C11D1/8355; C11D1/38; C11D1/62; C11D1/72; C11D1/721; C11D1/722

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 318 words
A detergent composition for the mechanical cleaning of hard surfaces in aqueous alkaline cleaning liquors, which comprises (A) 20 to 95% by weight, of the total weight of the mixture A+B, of a nonionic surfactant of the formula ##STR10## or a mixture of the formulae (A 1 ), (A 2 ) and/or (A 3 ), in which R 1 is an alkyl radical having 6 to 22 C atoms, R 2 is an alkyl radical having 1 to 6 C atoms, R 3 is an alkyl radical having 1 to 4 C atoms, a is a statistical average value within the range from 2 to 10, b is a statistical average value within the range from 1 to 8, c is a statistical average value within the range from 5 to 20 and d is a statistical average value within the range from 0 to 3, and (B) 5 to 80% by weight, of the total weight of the mixture A+B, of a cationic surfactant of the formula ##STR11## in which R 4 and R 5 are identical or different alkyl radicals having 1 to 12 C atoms, R 6 is an alkyl radical having 1 to 8 C atoms and R 7 is an alkyl radical having 1 to 4 C atoms or a benzyl radical, and A denotes an anion, and, additionally, (C) 0.001 to 20% by weight, relative to the total weight A+B=100, of a fluorinated alcohol of the formula ##STR12## in which Rf is a perfluoromethyl or perfluoroisopropyl radical, R 8 is an alkyl radical having 1 to 3 C atoms, R 9 is hydrogen or an alkyl radical having 1 to 3 C atoms, e denotes an integer from 5 to 15, f denotes an integer from 0 to 4 and g assumes the value 0 in the case of f=1 to 4, and assumes the value 1 in the case of f=0.
Claim 2
Dependent Claim 318 words
A detergent composition for the mechanical cleaning of hard surfaces in aqueous alkaline cleaning liquors, which comprises (A) 20 to 95% by weight, of the total weight of the mixture A+B, of a nonionic surfactant of the formula ##STR10## or a mixture of the formulae (A 1 ), (A 2 ) and/or (A 3 ), in which R 1 is an alkyl radical having 6 to 22 C atoms, R 2 is an alkyl radical having 1 to 6 C atoms, R 3 is an alkyl radical having 1 to 4 C atoms, a is a statistical average value within the range from 2 to 10, b is a statistical average value within the range from 1 to 8, c is a statistical average value within the range from 5 to 20 and d is a statistical average value within the range from 0 to 3, and (B) 5 to 80% by weight, of the total weight of the mixture A+B, of a cationic surfactant of the formula ##STR11## in which R 4 and R 5 are identical or different alkyl radicals having 1 to 12 C atoms, R 6 is an alkyl radical having 1 to 8 C atoms and R 7 is an alkyl radical having 1 to 4 C atoms or a benzyl radical, and A denotes an anion, and, additionally, (C) 0.001 to 20% by weight, relative to the total weight A+B=100, of a fluorinated alcohol of the formula ##STR12## in which Rf is a perfluoromethyl or perfluoroisopropyl radical, R 8 is an alkyl radical having 1 to 3 C atoms, R 9 is hydrogen or an alkyl radical having 1 to 3 C atoms, e denotes an integer from 5 to 15, f denotes an integer from 0 to 4 and g assumes the value 0 in the case of f=1 to 4, and assumes the value 1 in the case of f=0.
Claim 3
Dependent Claim 36 words
A detergent composition comprising a surfactant-containing mixture as claimed in claim 1, which mixture comprises 30 to 70% by weight of the nonionic surfactant (A) and 70 to 30% by weight of the cationic surfactant (B).
Claim 4
Dependent Claim 29 words
A detergent composition comprising a surfactant-containing mixture as claimed in claim 1 or 2, wherein an effective quantity of an organic solubilizer has been added to the fluorinated alcohol.
Claim 5
Dependent Claim 34 words
A method for the mechanical cleaning of hard surfaces, which comprises treating said hard surfaces with an aqueous alkaline cleaning liquor containing an effective amount of the detergent composition as claimed in claim 1.
Claim 6
Dependent Claim 15 words
The method of claim 4, wherein the aqueous alkaline liquor has a pH of ≧10.
Claim 7
Dependent Claim 15 words
The method of claim 4, wherein the aqueous alkaline liquor has a pH of ≧12.
Claim 8
Dependent Claim 39 words
The method of claim 4, wherein the aqueous alkaline cleaning liquor has a pH of at least 10, and the method of treating said hard surfaces includes the step of vigorous mechanical agitation of the aqueous alkaline cleaning liquor.
Claim 9
Dependent Claim 24 words
The method of claim 7, wherein the vigorous mechanical agitation takes place in the presence of protein-containing soil and glue and printing ink residues.
Claim 10
Dependent Claim 33 words
A detergent composition comprising the surfactant mixture of claim 1 in combination with sufficient sodium hydroxide to adjust the pH of said composition, when in said aqueous alkaline liquor, to at least 10.
Claim 11
Dependent Claim 13 words
A detergent composition of claim 8, wherein said pH is at least 12.

References Cited (Backward Citations)

GB873214A Cited
GB994607A Cited
DE2523588A1 Cited
US4174304A Cited
GB2004534A Cited
US4284532A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-17 1987-10-17 1988-04-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-17 1991-10-17 1992-04-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-17 1995-10-17 1996-04-17 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag