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US4441979A Expired / Lapsed US ⏱️ 0.0 years remaining

Nutating probe for gas analysis

Assignee: BA BUSINESS CREDIT Inc
•
Filing: 1983-05-31
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Granted: 1984-04-10
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Expires: 2003-05-31
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Abstract

Abstract A probe immersible in process water or wastewater having oxygen, chlorine or another gas dissolved therein and adapted to continuously and accurately measure the concentration of the gas. The probe includes a noble metal measuring electrode, an oxidizable metal counter-electrode and an electrolyte which in combination with the electrodes defines an electro-chemical cell whose output current depends on the amount of the gas passing into the cell through a diffusion membrane permeable to the gas being analyzed. In order to simulate the effect of rapid sample flow past the membrane and thereby maintain the analytical sensitivity of the instrument, the probe is vertically supported through a flexible coupling and includes an internal motor having an unbalanced rotor secured to its shaft. Rotation of the rotor causes the probe to nutate about its vertical axis to simulate the effect of a rapid sample flow.

Inventors

  • 👤 Leo L. Dailey

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 14:15
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/404; G01N27/4045

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 209 words
A probe immersible in a liquid having a gas dissolved therein and adapted to continuously and accurately measure the concentration of the gas, said probe comprising: A. a hollow casing provided with an upper motor chamber and a lower chamber having an open mouth, the casing being supported in a vertical position for immersion in the liquid by a flexible coupling attached to the upper end thereof, whereby the probe is deflectable from its normal vertical axis; B. a noble metal measuring electrode disposed in said electrolyte chamber adjacent said open mouth; C. a diffusing membrane covering said open mouth, said membrane being permeable to the gas to be measured; D. an oxidizable metal counter-electrode disposed in said electrolytic chamber, the chamber being filled with an electrolyte which bridges the electrodes to form a gas-sensitive electro chemical cell generating a current which is a function of the dissolved gas diffusing through said membrane; and E. a motor mounted in said motor chamber and having a shaft to which is attached an unbalanced rotor mass, whereby when the motor is energized, the rotating mass causes the probe to nutate relative to its normal vertical axis to simulate the effect of a rapid flow of the liquid relative to the membrane.
Claim 2
Dependent Claim 209 words
A probe immersible in a liquid having a gas dissolved therein and adapted to continuously and accurately measure the concentration of the gas, said probe comprising: A. a hollow casing provided with an upper motor chamber and a lower chamber having an open mouth, the casing being supported in a vertical position for immersion in the liquid by a flexible coupling attached to the upper end thereof, whereby the probe is deflectable from its normal vertical axis; B. a noble metal measuring electrode disposed in said electrolyte chamber adjacent said open mouth; C. a diffusing membrane covering said open mouth, said membrane being permeable to the gas to be measured; D. an oxidizable metal counter-electrode disposed in said electrolytic chamber, the chamber being filled with an electrolyte which bridges the electrodes to form a gas-sensitive electro chemical cell generating a current which is a function of the dissolved gas diffusing through said membrane; and E. a motor mounted in said motor chamber and having a shaft to which is attached an unbalanced rotor mass, whereby when the motor is energized, the rotating mass causes the probe to nutate relative to its normal vertical axis to simulate the effect of a rapid flow of the liquid relative to the membrane.
Claim 3
Dependent Claim 25 words
A probe as set forth in claim 1, wherein said coupling is a flexible tube through which is extended the power leads for said motor.
Claim 4
Dependent Claim 22 words
A probe as set forth in claim 1, wherein said gas is chlorine and said diffusing membrane is formed of PTFE material.
Claim 5
Dependent Claim 14 words
A probe as set forth in claim 3, wherein said measuring electrode is gold.
Claim 6
Dependent Claim 13 words
A probe as set forth in claim 4, wherein said counter-electrode is silver.
Claim 7
Dependent Claim 20 words
A probe as set forth in claim 5, wherein said electrolyte is a saturated solution of an alkali bromide salt.
Claim 8
Dependent Claim 21 words
A probe as set forth in claim 6 for measuring free chlorine wherein said solution is buffered to about pH 4.
Claim 9
Dependent Claim 14 words
A probe as set forth in claim 7, wherein the buffer is acetic acid/acetate.
Claim 10
Dependent Claim 22 words
A probe as set forth in claim 6 for measuring total chlorine, wherein said solution has a pH no greater than 2.

References Cited (Backward Citations)

US3275541A Cited
US3445364A Cited
US3360451A Cited
US3413199A Cited
US3496084A Cited
US3948746A Cited
US4176032A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-10 1987-10-10 1988-04-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-10 1991-10-10 1992-04-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-10 1995-10-10 1996-04-10 $7700.00 Window Closed / Lapsed

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