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US4440622A Expired / Lapsed US ⏱️ 0.0 years remaining

Integration of short-contact-time liquefaction and critical solvent deashing with gasification through methanol-to-gasoline

Assignee: Mobil Oil AS
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Filing: 1982-06-23
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Granted: 1984-04-03
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Expires: 2002-06-23
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Abstract

Abstract Coal is processed by liquefying the coal with a hydrogen-donor solvent under a short-contact-time liquefaction, separating the coal liquid effluent into liquid phases of distinct polarity and an undissolved coal residue, upgrading a portion of the liquid phase, gasifying the residue and high polarity coal liquid to produce a synthesis gas which is used to form methanol. The methanol is catalytically converted to gasoline products. Solvents for liquefaction and effluent separation can be derived from the upgraded liquid phase, methanol and gasoline products. Hydrogen for liquefaction, methanol synthesis and upgrading is derived from the synthesis gas.

Inventors

  • 👤 Francis J. Derbyshire
  • 👤 Philip Varghese
  • 👤 Darrell D. Whitehurst

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 07:16
CPC Classifications
C; C10; C10G; C10G1/00; C10G1/002

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 280 words
An integrated process for the conversion of solid coal to a wide slate of fuel products comprising: liquefying a portion of said coal by contacting said coal with a solvent to product dissolved coal liquids and an undissolved coal residue, separating a light SRC from said coal liquids by mixing said coal liquids with a light solvent under supercritical conditions of temperature and pressure, whereby said light solvent is converted to a dense-gas phase capable of dissolving said coal liquid, and varying the density of said dense-gas phase to precipitate out said light SRC, said light SRC having a hydrogen concentration greater than said coal feed and remaining portions of said coal liquid, upgrading said light SRC in the presence of hydrogen to produce a plurality of upgraded fuel products, gasifying a mixture of said residue and a portion of said coal liquids under oxidizing conditions to produce a synthesis gas comprising hydrogen and carbon monoxide, shifting the hydrogen to carbon monoxide ratio of said synthesis gas to produce a hydrogen gas stream, combining a portion of said hydrogen gas stream with said synthesis gas, converting said combined hydrogen gas stream and synthesis gas to methanol, passing at least a portion of said methanol in contact with a catalyst capable of converting said methanol to gasoline products, recycling at least one of the product streams for use in the integrated process, said recycle product streams including methanol or said gasoline products for use as said light solvent, light SRC or upgraded fuel products as said solvent for liquefying said coal, or said hydrogen gas stream to upgrade said light SRC or for inclusion with said solvent to liquefy said coal.
Claim 2
Dependent Claim 280 words
An integrated process for the conversion of solid coal to a wide slate of fuel products comprising: liquefying a portion of said coal by contacting said coal with a solvent to product dissolved coal liquids and an undissolved coal residue, separating a light SRC from said coal liquids by mixing said coal liquids with a light solvent under supercritical conditions of temperature and pressure, whereby said light solvent is converted to a dense-gas phase capable of dissolving said coal liquid, and varying the density of said dense-gas phase to precipitate out said light SRC, said light SRC having a hydrogen concentration greater than said coal feed and remaining portions of said coal liquid, upgrading said light SRC in the presence of hydrogen to produce a plurality of upgraded fuel products, gasifying a mixture of said residue and a portion of said coal liquids under oxidizing conditions to produce a synthesis gas comprising hydrogen and carbon monoxide, shifting the hydrogen to carbon monoxide ratio of said synthesis gas to produce a hydrogen gas stream, combining a portion of said hydrogen gas stream with said synthesis gas, converting said combined hydrogen gas stream and synthesis gas to methanol, passing at least a portion of said methanol in contact with a catalyst capable of converting said methanol to gasoline products, recycling at least one of the product streams for use in the integrated process, said recycle product streams including methanol or said gasoline products for use as said light solvent, light SRC or upgraded fuel products as said solvent for liquefying said coal, or said hydrogen gas stream to upgrade said light SRC or for inclusion with said solvent to liquefy said coal.
Claim 3
Dependent Claim 15 words
The process of claim 1 wherein said coal comprises lignites, bituminous coals or sub-bituminous coals.
Claim 4
Dependent Claim 18 words
The process of claim 1 wherein said solvent is process-derived, derived from an external source, or mixtures thereof.
Claim 5
Dependent Claim 35 words
The process of claim 3 wherein said process-derived solvent is selected from the group consisting of solvent derived from said upgraded fuel products, solvent derived from a portion of said coal liquids, and mixtures thereof.
Claim 6
Dependent Claim 13 words
The process of claim 3 wherein said solvent comprises a hydrogen donor solvent.
Claim 7
Dependent Claim 16 words
The process of claim 5 wherein said coal is liquefied in the presence of hydrogen gas.
Claim 8
Dependent Claim 29 words
The process of claim 1 wherein said light SRC is upgraded in the presence of hydrogen and said hydrogen is provided from a portion of said hydrogen gas stream.
Claim 9
Dependent Claim 28 words
The process of claim 1 wherein said coal is liquefied in the presence of hydrogen and said hydrogen is provided from a portion of said hydrogen gas stream.
Claim 10
Dependent Claim 38 words
The process of claim 1 wherein a heavy SRC of generally higher molecular weight and higher polarity than said light SRC is separated from said coal liquid prior to separation of said light SRC from said coal liquid.
Claim 11
Dependent Claim 20 words
The process of claim 9 wherein a mixture of said residue and said heavy SCR is gasified under oxidizing conditions.
Claim 12
Dependent Claim 18 words
The process of claim 9 wherein the hydrogen supplied for upgrading is provided from said hydrogen gas stream.
Claim 13
Dependent Claim 21 words
The process of claim 5 wherein said coal is maintained in contact with said solvent no greater than about six minutes.
Claim 14
Dependent Claim 17 words
The process of claim 12 wherein said contacting takes place at a temperature from about 750°-900° F.
Claim 15
Dependent Claim 21 words
The process of claim 1 wherein said feed coal is dried, premixed with a premixing solvent and comminuted before being liquefied.
Claim 16
Dependent Claim 15 words
The process of claim 14 wherein said premixing solvent comprises distillate or non-distillate product oils.
Claim 17
Dependent Claim 11 words
The process of claim 15 wherein said premixing solvent is process-derived.
Claim 18
Dependent Claim 13 words
The process of claim 16 wherein said premixing solvent is a petroleum product.
Claim 19
Dependent Claim 18 words
The process of claim 1 wherein said light solvent is process-derived, derived from external sources, or mixtures thereof.
Claim 20
Dependent Claim 29 words
The process of claim 18 wherein said process-derived light solvent is selected from the group consisting of said upgraded fuel products, said methanol, said gasoline products and mixtures thereof.

References Cited (Backward Citations)

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US4076761A Cited
US4138442A Cited
US4075079A Cited
US4191700A Cited
US4159237A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-03 1987-10-03 1988-04-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-03 1991-10-03 1992-04-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-03 1995-10-03 1996-04-03 $7700.00 Window Closed / Lapsed

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