Aromatic polyols made from recycled polyethylene terephthalate waste streams, alkylene glycol and dibasic acid waste streams

Claim 2

A mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, being produced by the process comprising a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step.

Claim 3

The mixture of aromatic polyols of claim 1 in which the alkylene glycol has the formula ##STR4## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3.

Claim 4

The mixture of polyols of claim 1 in which the alkylene glycol is a glycol waste stream.

Claim 5

The mixture of polyols of claim 1 in which the approximate mole ratio of the reactants polyethylene terephthalate scrap:dibasic acid waste:alkylene glycol is 1:1:2.

Claim 6

The mixture of polyols of claim 1 in which the reactions are conducted at a temperature between 140° to 220° C.

Claim 7

The mixture of polyols of claim 1 in which the average hydroxyl number of the resultant mixture is between 100 and 400.

Claim 8

A mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, being produced by the process comprising a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids selected from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol waste stream containing alkylene glycols of the formula ##STR5## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3, to produce a polyester polyol, and b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step, such that the reactions are conducted at a temperature between 140° to 220° C. and in which the average hydroxyl number of the resultant polyol mixture is between 100 and 400.

Claim 9

A mixture of aromatic polyols having hydroxyl and ester functionalities for use in preparing rigid foams, being produced by the process comprising a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids selected from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol waste stream containing alkylene glycols of the formula ##STR5## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3, to produce a polyester polyol, and b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step, such that the reactions are conducted at a temperature between 140° to 220° C. and in which the average hydroxyl number of the resultant polyol mixture is between 100 and 400.

Claim 12

The method of claim 8 in which the alkylene glycol is a glycol waste stream comprising alkylene glycols of the formula ##STR6## where R is hydrogen or lower alkyl of 1 to 4 carbon atoms and n is from 1 to 3, and

Claim 13

The method of claim 8 in which the approximate mole ratio of the reactants recycled polyethylene terephthalate:dibasic acid waste:alkylene glycol is 1:1:2.

Claim 14

The method of claim 8 in which the reactions are conducted at a temperature between 140° and 220° C. and at a pressure between one atmosphere and subatmospheric.

Claim 15

The method of claim 8 in which the average hydroxyl number of the resultant mixture is between 100 and 400.

Claim 16

A rigid polyurethane foam obtained by reacting in the presence of a blowing agent and a catalyst of polyurethane formation an organic polyisocyanate and a polyol blend comprising a. from about 5 to 100 percent by weight of a mixture of aromatic polyols having ester functionalities which is the reaction product from (1) esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and (2) transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step, and b. from about 95 to 0 percent by weight of a nitrogen-containing polyol which is the reaction product from (1) reacting one mole of phenol or nonylphenol with one to 2 moles of diethanolamine to give a Mannich reaction product and (2) subsequently reacting one mole of the Mannich reaction product with 2 to 3 moles of propylene oxide.

Claim 17

A rigid polyurethane foam obtained by reacting in the presence of a blowing agent and a catalyst of polyurethane formation an organic polyisocyanate and a polyol blend comprising a. from about 5 to 100 percent by weight of a mixture of aromatic polyols having ester functionalities which is the reaction product from (1) esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and (2) transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step, and b. from about 95 to 0 percent by weight of a nitrogen-containing polyol which is the reaction product from (1) reacting one mole of phenol or nonylphenol with one to 2 moles of diethanolamine to give a Mannich reaction product and (2) subsequently reacting one mole of the Mannich reaction product with 2 to 3 moles of propylene oxide.

Claim 18

The rigid polyurethane foam of claim 13 in which the polyol blend has an average hydroxyl number in the range from 100 to 500.

Claim 19

The rigid polyurethane foam of claim 13 in which the blowing agent is trichlorofluoromethane.

Claim 20

A rigid polyisocyanurate foam which is obtained by reacting in the presence of a blowing agent and a trimerization catalyst of polyisocyanate formation, an organic polyisocyanate and a mixture of aromatic polyols having ester functionalities which is the reaction product of the process comprising a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step.

Claim 21

A rigid polyisocyanurate foam which is obtained by reacting in the presence of a blowing agent and a trimerization catalyst of polyisocyanate formation, an organic polyisocyanate and a mixture of aromatic polyols having ester functionalities which is the reaction product of the process comprising a. esterifying, in the absence of a catalyst, a residue from dibasic acid manufacture which comprises one or more acids from the group consisting of glutaric acid, succinic acid and adipic acid, with an alkylene glycol to produce a polyester polyol and b. transesterifying, in the absence of a catalyst, recycled polyethylene terephthalate with the polyester polyol reaction product from the previous step.

Claim 22

The rigid polyisocyanurate foam of claim 16 in which the mixture of aromatic polyols have an average hydroxyl number in the range of 100 to 400.

Claim 23

The rigid polyisocyanurate foam of claim 16 in which the blowing agent is trichlorofluoromethane.