US4437975A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Manufacture of lube base stock oil
Assignee: Mobil Oil AS
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Filing: 1982-09-30
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Granted: 1984-03-20
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Expires: 2002-09-30
Abstract
Abstract Lube base stock oil of low pour point and excellent stability is produced from a waxy crude oil fraction by solvent refining, catalytic dewaxing over a zeolite catalyst in the nature of zeolite ZSM-5 and hydrotreating under specified conditions.
Inventors
- 👤 Bernard M. Gillespie
- 👤 Michael S. Sarli
- 👤 Kenneth W. Smith
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 17:42
CPC Classifications
C; C10; C10G; C10G45/00; C10G45/58; C10G45/60; C10G45/64; C10G2400/00; C10G2400/12
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
182 words
In a process for preparing a lube base stock oil from a deasphalted short residuum of a waxy crude, said deasphalted short residuum having a pour point substantially higher than +30° F., said process comprising dewaxing said deasphalted short residuum and recovering a dewaxed residuum having a pour point from about -25° F. to not higher than +30° F., the improvement, whereby increasing the yield of said dewaxed residuum, which comprises: catalytically dewaxing said deasphalted short residuum by contact, in the presence of hydrogen, with a dewaxing catalyst contained in a dewaxing zone, said dewaxing catalyst comprising an aluminosilicate zeolite having a silica/alumina ratio of at least about 12 and a Constraint Index of about 1 to about 12, said contacting being at a temperature from 500° to about 675° F. and at a hydrogn partial pressure at the reactor inlet of about 150-1500 psia, and cascading the effluent from said dewaxing zone to a hydrotreating zone wherein it is contacted with a hydrotreating catalyst at a temperature of 500° to 575° F., thereby increasing the oxidation stability of said dewaxed residuum.
Claim 2
Dependent Claim
182 words
In a process for preparing a lube base stock oil from a deasphalted short residuum of a waxy crude, said deasphalted short residuum having a pour point substantially higher than +30° F., said process comprising dewaxing said deasphalted short residuum and recovering a dewaxed residuum having a pour point from about -25° F. to not higher than +30° F., the improvement, whereby increasing the yield of said dewaxed residuum, which comprises: catalytically dewaxing said deasphalted short residuum by contact, in the presence of hydrogen, with a dewaxing catalyst contained in a dewaxing zone, said dewaxing catalyst comprising an aluminosilicate zeolite having a silica/alumina ratio of at least about 12 and a Constraint Index of about 1 to about 12, said contacting being at a temperature from 500° to about 675° F. and at a hydrogn partial pressure at the reactor inlet of about 150-1500 psia, and cascading the effluent from said dewaxing zone to a hydrotreating zone wherein it is contacted with a hydrotreating catalyst at a temperature of 500° to 575° F., thereby increasing the oxidation stability of said dewaxed residuum.
Claim 3
Dependent Claim
12 words
The process described in claim 1 wherein said aluminosilicate zeolite is ZSM-5.
Claim 4
Dependent Claim
47 words
The process described in claim 2 including the step of partially solvent dewaxing said deasphalted residuum to a pour point of from 10° to about 50° F. prior to said catalytic dewaxing step wherein the pour point is further reduced by at least an additional 10° F.
Claim 5
Dependent Claim
21 words
The process described in claim 1 wherein said deasphalted short residuum is solvent extracted prior to said step of catalytic dewaxing.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-03-20 | 1987-09-19 | 1988-03-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-03-20 | 1991-09-19 | 1992-03-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-03-20 | 1995-09-19 | 1996-03-20 | $7700.00 | Window Closed / Lapsed |