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US4436920A Expired / Lapsed US ⏱️ 0.0 years remaining

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Assignee: Fujifilm Holdings Corp
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Filing: 1982-03-11
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Granted: 1984-03-13
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Expires: 2002-03-11
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Abstract

Abstract Recording members having excellent light resistance are obtained by using as a dye precursor specific diarylaminofluoran compounds.

Inventors

  • 👤 Kozo Sato
  • 👤 Ken Iwakura
  • 👤 Akira Igarashi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 13:55
CPC Classifications
C; C09; C09B; C09B11/00; C09B11/04; C09B11/10; C09B11/24; B; B41; B41M; B41M5/00; B41M5/124; B41M5/132; B41M5/136; B41M5/145; B41M5/1455; B41M5/26; B41M5/30; B41M5/323; B41M5/327; B41M5/3275; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 255 words
A diarylaminofluoran dye precursor represented by the formula (I) ##STR77## wherein Ar and Ar' each are selected from the group consisting of a phenyl group, an alkyl-substituted phenyl group, an alkoxy-substituted phenyl group, a halogen-substituted phenyl group, a naphthyl group, an aralkyl-substituted naphthyl group, a halogen-substituted naphthyl group, and an alkoxy-substituted naphthyl group, or wherein Ar and Ar' are heterocyclic rings selected from the group consisting of a furyl group, a pyrrolyl group, a thienyl group, an indolyl group, a carbazolyl group, a phenoxazinyl group, a phenothiazinyl group, and a phenazinyl group, or wherein Ar and Ar' together form a heterocyclic ring selected from the group consisting of ##STR78## wherein R is an alkyl group, R 1 and R 2 each represent hydrogen, an alkyl group, a cycloalkyl group, an aralkyl group, an aryl group or a heterocyclic ring selected from the group consisting of a furyl group, a pyrrolyl group, a thienyl group, an indolyl group, a carbazolyl group, a phenoxazinyl group, a phenothiazinyl group, and a phenazinyl group, or R 1 and R 2 together form a heterocyclic ring selected from the group consisting of ##STR79## wherein R is an alkyl group, R 3 , R 4 and R 5 each represent an alkyl group, an alkoxy group, a halogen atom, a nitro group, an amino group, an alkylamino group, a dialkylamino group, or an acylamino group, x and y are each 0 or an integer of from 1 to 3, and z is 0 or an integer of from 1 to 4.
Claim 2
Dependent Claim 255 words
A diarylaminofluoran dye precursor represented by the formula (I) ##STR77## wherein Ar and Ar' each are selected from the group consisting of a phenyl group, an alkyl-substituted phenyl group, an alkoxy-substituted phenyl group, a halogen-substituted phenyl group, a naphthyl group, an aralkyl-substituted naphthyl group, a halogen-substituted naphthyl group, and an alkoxy-substituted naphthyl group, or wherein Ar and Ar' are heterocyclic rings selected from the group consisting of a furyl group, a pyrrolyl group, a thienyl group, an indolyl group, a carbazolyl group, a phenoxazinyl group, a phenothiazinyl group, and a phenazinyl group, or wherein Ar and Ar' together form a heterocyclic ring selected from the group consisting of ##STR78## wherein R is an alkyl group, R 1 and R 2 each represent hydrogen, an alkyl group, a cycloalkyl group, an aralkyl group, an aryl group or a heterocyclic ring selected from the group consisting of a furyl group, a pyrrolyl group, a thienyl group, an indolyl group, a carbazolyl group, a phenoxazinyl group, a phenothiazinyl group, and a phenazinyl group, or R 1 and R 2 together form a heterocyclic ring selected from the group consisting of ##STR79## wherein R is an alkyl group, R 3 , R 4 and R 5 each represent an alkyl group, an alkoxy group, a halogen atom, a nitro group, an amino group, an alkylamino group, a dialkylamino group, or an acylamino group, x and y are each 0 or an integer of from 1 to 3, and z is 0 or an integer of from 1 to 4.
Claim 3
Dependent Claim 26 words
A diarylaminofluoran dye precursor as in claim 1, wherein the alkyl and alkoxy substituent groups have a total number of carbon atoms of 10 or less.
Claim 4
Dependent Claim 15 words
A diarlyaminofluoran dye precursor as in claim 1, wherein x and y are each 0.
Claim 5
Dependent Claim 47 words
A diarylaminofluroan die precursor as in claim 1, wherein the diarylaminofluoran compound is selected from the group consisting of 3-diphenylamino-6-diethylaminofluoran, 3-diphenylamino-6-piperidinofluoran, 3-diphenylamino-6-(N-methyl-N-phenyl)aminofluoran, 3-diphenylamino-6-(N-ethyl-N-tolyl)aminofluoran, 3,6-bis-diphenylaminofluoran, 3-diphenylamino-6-ditolylaminofluoran, 3-diphenylamino-6-(N-phenyl-N-tolyl)aminofluoran, 3-diphenylamino-6-(N-phenyl-N-β-naphthyl)aminofluoran, 3-ditolylamino-6-diethylaminofluoran, 3-ditolylamino-6-(N-ethyl-N-tolyl)aminofluoran, 3,6-bis-ditolylaminofluoran, 3-ditolylamino-6-(N-phenyl-N-tolyl)aminofluoran, 3-ditolylamino-6-(N-phenyl-N-β-naphthyl)aminofluoran, 3-(N-phenyl-N-tolyl)amino-6-diethylaminofluoran, 3,6-bis(N-phenyl-N-tolyl)aminofluoran, 3-(N-phenyl-N-tolyl)-amino-6-(N-phenyl-N-β-naphthyl)aminofluoran, 3-diphenylamino-6-dianisylaminofluoran, 3-ditolylamino-6-dianisylaminofluoran, 3,6-bis-dianisylaminofluoran, 3,6-bis(N-phenyl-N-methoxyphenyl)aminofluoran, 3-diphenylamino-6-[di(p-chloro)amino]fluoran, 3,6-bis[di(p-chlorophenyl)amino]fluoran, 3,6-bis(N-phenyl-N-β-naphthyl)aminofluoran, 3-(9-carbazolyl)-6-diethylaminofluoran, 3-(9-carbazolyl)-6-(N-ethyl-N-tolyl)aminofluoran, 3-(10-phenothiazinyl)-6-diethylaminofluoran, and 3-(10-phenothiazinyl)-6-(N-ethyl-N-tolyl)aminofluoran.
Claim 6
Dependent Claim 39 words
A diarylaminofluoran dye precursor as in claim 4, wherein the diarylaminofluoran compound is selected from the group consisting of 3-diphenylamino-6-(N-methyl-N-phenyl)aminofluoran, 3-diphenylamino-6-(N-ethyl-N-tolyl)aminofluoran, 3,6-bis(diphenylaminofluoran, 3-diphenylamino-6-ditolylaminofluoran, 3-diphenylamino-6-(N-phenyl-N-tolyl)aminofluoran, 3-diphenylamino-6-(N-phenyl-N-β-naphthyl)aminofluoran, 3-ditolylamino-6-(N-ethyl-N-tolyl)aminofluoran, 3,6-bis(ditolylaminofluoran, 3-ditolylamino-6-(N-phenyl-N-tolyl)-aminofluoran, 3-ditolylamino-6-(N-phenyl-N-β-naphthyl)-aminofluoran, 3,6-bis(N-phenyl-N-tolyl)aminofluoran, 3-(N-phenyl-N-tolyl)amino-6-(N-phenyl-N-β-naphthyl)aminofluoran, 3-diphenylamino-6-dianisylaminofluoran, 3-ditolylamino-6-dianisylaminofluoran, 3,6-bis-dianisylaminofluoran, 3,6-bis-(N-phenyl-N-methoxyphenyl)aminofluoran, 3-diphenylamino-6-[di(p-chloro)amino]fluoran, 3,6-bis[di(p-chlorophenyl)amino]fluoran, and 3,6-bis(N-phenyl-N-β-naphthyl)aminofluoran.
Claim 7
Dependent Claim 30 words
A diarylaminofluoran dye precursor as in claim 5, wherein said diarylaminofluoran compound is selected from the group consisting of 3,6-bis-diphenylaminofluoran, 3-diphenylamino-6-ditolylaminofluoran, 3,6-bis-ditolylaminofluoran, 3,6-bis(N-phenyl-N-tolyl)aminofluoran, 3-diphenylamino-6-dianisylaminofluoran, 3-ditolylamino-6-dianisylaminofluoran, 3,6-bis-dianisylaminofluoran, 3-diphenylamino-6-[di(p-chloro)amino]fluoran, 3,6-bis[di(p-chlorophenyl)amino]fluoran, and 3,6-bis(N-phenyl-N-β-naphthyl)aminofluoran.

References Cited (Backward Citations)

US3713770A Cited
US4097288A Cited
US4267251A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-03-13 1987-09-12 1988-03-13 $2000.00 Window Closed / Lapsed
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