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US4435491A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrophotographic process for the production of lithographic printing plates and light-sensitive materials for use therein

Assignee: Fujifilm Holdings Corp
•
Filing: 1981-11-25
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Granted: 1984-03-06
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Expires: 2001-11-25
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Abstract

Abstract A process for the production of lithographic printing plates, and a light-sensitive material for use in the process are described. The light-sensitive material comprises an electrically conductive support having a hydrophilic surface, and a positive type light-sensitive layer and a photoconductive insulative layer on the support, wherein the positive type light-sensitive layer and the photoconductive insulative layer are provided on the support as a unit layer or individually in that order, and the photoconductive insulative layer can be charged either positively or negatively. The desired lithographic printing plate can be prepared by treating the light-sensitive material by the simple process of the invention.

Inventors

  • 👤 Takashi Kitamura
  • 👤 Hiroshi Kokado

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 03:37
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/20; G03F7/2002; G03F7/2014; G03F7/2016; G03F7/2018; G03F7/004; G03F7/09; G03F7/105; G03G; G03G13/00; G03G13/26; G03G5/00; G03G5/153; Y; Y10; Y10S; Y10S430/00; Y10S430/141

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 212 words
A process for producing a lithographic printing plate using a light-sensitive material comprising an electrically conductive support having a hydrophilic surface, and a positive working light-sensitive layer and a photoconductive insulative layer containing an alkali-soluble resin on the support, said process comprising the steps of: (A) forming an electrophotographic latent image on the photoconductive layer of the light-sensitive material; (B) developing the latent image with a liquid developer containing developer particles which are opaque to light having a wavelength to which the positive working light-sensitive layer is sensitive; (C) exposing to light the positive working light-sensitive layer through the developed image obtained in step (B); and (D) selectively removing with an alkali solution the area of the positive working light-sensitive layer not bearing the developed image together with areas corresponding to said areas of the positive working light-sensitive layer not bearing the developed image of the photoconductive layer; wherein: the positive working light-sensitive layer and the photoconductive insulative layer are provided on the support as a unit layer, or are individually provided in that order; and the photoconductive insulative layer is substantially chargable either positively or negatively, and contains said alkali-soluble resin in such an amount as to not inhibit the selective removal of the positive working light-sensitive layer in step (D).
Claim 2
Dependent Claim 212 words
A process for producing a lithographic printing plate using a light-sensitive material comprising an electrically conductive support having a hydrophilic surface, and a positive working light-sensitive layer and a photoconductive insulative layer containing an alkali-soluble resin on the support, said process comprising the steps of: (A) forming an electrophotographic latent image on the photoconductive layer of the light-sensitive material; (B) developing the latent image with a liquid developer containing developer particles which are opaque to light having a wavelength to which the positive working light-sensitive layer is sensitive; (C) exposing to light the positive working light-sensitive layer through the developed image obtained in step (B); and (D) selectively removing with an alkali solution the area of the positive working light-sensitive layer not bearing the developed image together with areas corresponding to said areas of the positive working light-sensitive layer not bearing the developed image of the photoconductive layer; wherein: the positive working light-sensitive layer and the photoconductive insulative layer are provided on the support as a unit layer, or are individually provided in that order; and the photoconductive insulative layer is substantially chargable either positively or negatively, and contains said alkali-soluble resin in such an amount as to not inhibit the selective removal of the positive working light-sensitive layer in step (D).
Claim 3
Dependent Claim 81 words
A light-sensitive material comprising an electrically conductive support having a hydrophilic surface, and a positive type light-sensitive layer and a photoconductive insulative layer on the support, wherein: the positive type light-sensitive layer and the photoconductive insulative layer are provided on the support as a unit layer or individually in that order; and the photoconductive insulative layer is substantially chargable either positively or negatively, and does not inhibit selective removal of areas of the positive type light-sensitive layer having a developed image.
Claim 4
Dependent Claim 81 words
A light-sensitive material comprising an electrically conductive support having a hydrophilic surface, and a positive type light-sensitive layer and a photoconductive insulative layer on the support, wherein: the positive type light-sensitive layer and the photoconductive insulative layer are provided on the support as a unit layer or individually in that order; and the photoconductive insulative layer is substantially chargable either positively or negatively, and does not inhibit selective removal of areas of the positive type light-sensitive layer having a developed image.
Claim 5
Dependent Claim 24 words
A light-sensitive material as in claim 2, further having an intermediate layer provided between the photoconductive insulative layer and the positive type light-sensitive layer.
Claim 6
Dependent Claim 21 words
The process of claim 1 wherein said electrophotographic latent image is formed using a voltage of from 10 to 300 V.
Claim 7
Dependent Claim 14 words
The process of claim 1 wherein said exposing to light is with ultraviolet light.
Claim 8
Dependent Claim 72 words
The process of claim 1 wherein an electrically conductive intermediate layer is present between said positive working light-sensitive layer and said photoconductive insulative layer and wherein said electrically conductive intermediate layer is electrically conductive so as to accelerate electric charges having the opposite polarity to that of the electric charges on the surface of the photoconductive insulative layer being maintained on the positive working light-sensitive layer side of the electrically conductive support.
Claim 9
Dependent Claim 19 words
The process of claim 1 wherein said photoconductive insulative layer has a thickness of from 0.5 to 5 microns.
Claim 10
Dependent Claim 15 words
The process of claim 6 wherein said intermediate layer comprises a water-soluble electrically conductive resin.
Claim 11
Dependent Claim 65 words
The process of claim 1, wherein the positive working light-sensitive layer and the photoconductive insulative layer are individually provided on the support in that order, and the photoconductive insulative layer comprises from 5 to 30% by weight of photoconductive substance, from 0 to 30% by weight of insulative resin other than said alkali-soluble resin and from 50 to 85% by weight of said alkali-soluble resin.
Claim 12
Dependent Claim 66 words
The process of claim 9, wherein said alkali-soluble resin is selected from the group consisting of a phenol-formaldehyde resin, a methacresol-formaldehyde resin, a styrene-maleic anhydride copolymer, a polyacrylic acid-polyacrylic acid amide copolymer, a fumaric acid-ethylene glycol copolymer, a methyl vinyl ether-maleic anhydride copolymer, an acryloylglycine-vinyl acetate copolymer, polyvinyl pyrrolidone, polyvinyl alcohol, a polyamide, an alkali-soluble azide resin, a halogenated polystyrene, shellac, a protein or a glue.
Claim 13
Dependent Claim 70 words
The process of claim 9, wherein said insulative resin is selected from the group consisting of polyethylene terephthalate, polyimide, polycarbonate, polyacrylate, polymethyl methacrylate, polyvinyl fluoride, polyvinyl chloride, polyvinyl acetate, polystyrene, a styrene butadiene copolymer, a polymethacrylate, a silicone resin, a chlorinated rubber, an epoxy resin, an alkyd resin, a modified alkyd resin, polymethyl methacrylate, poly-n-butyl methacrylate, cellulose acetate, a ketone resin, polyethylene, polypropylene, polyacrylonitrile, rosin derivatives, polyvinylidene chloride, or nitrocellulose.
Claim 14
Dependent Claim 19 words
The process of claim 9, wherein said positive working light-sensitive layer comprises an o-quinonediazide compound and an alkali-soluble resin.
Claim 15
Dependent Claim 12 words
The process of claim 9, wherein said support is an aluminum plate.

References Cited (Backward Citations)

US2939787A Cited
US3305359A Cited
US3944417A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-03-06 1987-09-05 1988-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-03-06 1991-09-05 1992-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-03-06 1995-09-05 1996-03-06 $7700.00 Window Closed / Lapsed

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