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US4435488A Expired / Lapsed US ⏱️ 0.0 years remaining

Gelling agent for alkaline cells

Assignee: Duracell Inc USA
•
Filing: 1982-03-08
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Granted: 1984-03-06
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Expires: 2002-03-08
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Abstract

Abstract A novel gelling agent comprised of cross-linked CMC (carboxymethyl cellulose) is utilized as a gelling agent in the anode of alkaline electrochemical cells with improved cell performance and reduced cell gassing as compared to the commonly utilized non cross-linked CMC.

Inventors

  • 👤 William S. Bahary
  • 👤 Rowland A. Griffin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 16:21
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/22; H01M4/00; H01M4/02; H01M4/06; H01M4/62; H01M4/621; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 26 words
A method of gelling anodes for alkaline cells comprising the step of gelling an anode active material with cross-linked carboxymethyl cellulose and an alkaline electrolyte solution.
Claim 2
Independent Claim 26 words
A method of gelling anodes for alkaline cells comprising the step of gelling an anode active material with cross-linked carboxymethyl cellulose and an alkaline electrolyte solution.
Claim 3
Dependent Claim 14 words
The method of claim 1 wherein said anode active material is comprised of zinc.
Claim 4
Dependent Claim 16 words
The method of claim 1 wherein said alkaline electrolyte solution is comprised of a KOH solution.
Claim 5
Dependent Claim 31 words
The method of claim 1 wherein the degree of cross linking in said cross-linked carboxymethyl cellulose is between 0.01 to 10% based upon the number of individual glucose anhydride units therein.
Claim 6
Dependent Claim 16 words
The method of claim 4 wherein said degree of cross linking is between 0.1 to 4%.
Claim 7
Dependent Claim 27 words
The method of claim 1 wherein said alkaline cells contain cathodes comprised of a member of the group consisting of manganese dioxide, silver oxide and mercury oxide.
Claim 8
Dependent Claim 20 words
The method of claim 1 wherein said cross-linked carboxymethyl cellulose comprises between 0.5% to 7% by weight of said anode.
Claim 9
Dependent Claim 20 words
The method of claim 7 wherein said cross-linked carboxymethyl cellulose comprises between 1.6% to 4% by weight of said anode.
Claim 10
Dependent Claim 16 words
An anode blend for an electrochemical cell comprising an anode active powder and cross-linked carboxymethyl cellulose.
Claim 11
Dependent Claim 16 words
An anode blend for an electrochemical cell comprising an anode active powder and cross-linked carboxymethyl cellulose.
Claim 12
Dependent Claim 15 words
The anode blend of claim 8 wherein said active anode powder is comprised of zinc.
Claim 13
Dependent Claim 15 words
The anode blend of claim 10 wherein said blend further includes an aqueous KOH solution.
Claim 14
Dependent Claim 32 words
The anode blend of claim 10 wherein the degree of cross linking of said cross-linked carboxymethyl cellulose is between 0.01 to 10% based upon the number of individual glucose anhydride units therein.
Claim 15
Dependent Claim 17 words
The anode blend of claim 12 wherein said degree of cross linking is between 0.1 to 4%.
Claim 16
Dependent Claim 22 words
The anode blend of claim 9 wherein said cross-linked carboxymethyl cellulose comprises between 2.5% to 3% by weight of said anode blend.
Claim 17
Dependent Claim 24 words
An electrochemical cell comprising a gelled anode, a cathode and an aqueous alkaline electrolyte characterized in that said gelled anode contains cross-linked carboxymethyl cellulose.
Claim 18
Dependent Claim 24 words
An electrochemical cell comprising a gelled anode, a cathode and an aqueous alkaline electrolyte characterized in that said gelled anode contains cross-linked carboxymethyl cellulose.
Claim 19
Dependent Claim 15 words
The cell of claim 15 wherein said anode contains zinc as the active material thereof.
Claim 20
Dependent Claim 16 words
The cell of claim 16 wherein said aqueous alkaline electrolyte is comprised of a KOH solution.
Claim 21
Dependent Claim 28 words
The cell of claims 15, 16 or 17 wherein said cathode is comprised of a member of the group consisting of manganese dioxide, silver oxide and mercury oxide.
Claim 22
Dependent Claim 31 words
The cell of claim 15 wherein the degree of cross linking in said cross-linked carboxymethyl cellulose is between 0.01 to 10% based upon the number of individual glucose anhydride units therein.
Claim 23
Dependent Claim 16 words
The cell of claim 19 wherein said degree of cross linking is between 0.1 to 4%.
Claim 24
Dependent Claim 20 words
The cell of claim 15 wherein said cross-linked carboxymethyl cellulose comprises between 0.5% to 7% by weight of said anode.
Claim 25
Dependent Claim 20 words
The cell of claim 21 wherein said cross-linked carboxymethyl cellulose comprises between 1.6% to 4% by weight of said anode.

References Cited (Backward Citations)

US3918989A Cited
US3877983A Cited
US3954501A Cited
US3884721A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-03-06 1987-09-05 1988-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-03-06 1991-09-05 1992-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-03-06 1995-09-05 1996-03-06 $7700.00 Window Closed / Lapsed

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