US4434082A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Palladium/heteropolyacid/surfactant catalyst system
Assignee: Phillips Petroleum Co
•
Filing: 1982-04-12
•
Granted: 1984-02-28
•
Expires: 2002-04-12
Abstract
Abstract A Pd/heteropolyacid/surfactant catalyst system, when used with proper diluents, improves the oxidation of olefins to ketones, while reducing corrosive effects.
Inventors
- 👤 Timothy P. Murtha
- 👤 Tad K. Shioyama
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 12:42
CPC Classifications
B; B01; B01J; B01J31/00; B01J31/26; B01J31/28; B01J31/30; B01J23/00; B01J23/002; B01J27/00; B01J27/14; B01J27/186; B01J27/195; B01J27/198; B01J27/199; B01J31/02; B01J31/0215; B01J31/0225; B01J31/0234; B01J31/0235; B01J31/0239; C; C07; C07C; C07C45/00; C07C45/27; C07C45/32; C07C45/33; C07C45/34; B01J2231/00; B01J2231/70; B01J2523/00
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
156 words
Composition useful for the catalytic oxidation of olefins to carbonyl compounds comprising: (a) one or more palladium components; (b) one or more heteropolyacid components conforming to the general formula H.sub.m [X.sub.x Mo.sub.a V.sub.b M.sub.y O.sub.z ] in which X is B, Si, Ge, P, As, Se, Te or I; M is W, Nb, Ta or Re; m, a, b and z are integers; x is zero or an integer; and y is zero or an integer such that ≦ (y+a+b)/z≦12 and m+Nx+6a+5b+N'y≦2z; in which each of N and N' is the number of the group of the periodic table to which X and M respectively belong; (c) one or more surfactants selected from the group consisting of: quaternary ammonium salts, alkali metal alkyl sulfates, alkali metal salts of alkanoic acids, alkali metal salts of alkaryl sulfonic acids, and 1-alkyl pyridinium salts; and (d) two or more liquid phases comprising an aqueous phase and an organic phase.
Claim 2
Dependent Claim
156 words
Composition useful for the catalytic oxidation of olefins to carbonyl compounds comprising: (a) one or more palladium components; (b) one or more heteropolyacid components conforming to the general formula H.sub.m [X.sub.x Mo.sub.a V.sub.b M.sub.y O.sub.z ] in which X is B, Si, Ge, P, As, Se, Te or I; M is W, Nb, Ta or Re; m, a, b and z are integers; x is zero or an integer; and y is zero or an integer such that ≦ (y+a+b)/z≦12 and m+Nx+6a+5b+N'y≦2z; in which each of N and N' is the number of the group of the periodic table to which X and M respectively belong; (c) one or more surfactants selected from the group consisting of: quaternary ammonium salts, alkali metal alkyl sulfates, alkali metal salts of alkanoic acids, alkali metal salts of alkaryl sulfonic acids, and 1-alkyl pyridinium salts; and (d) two or more liquid phases comprising an aqueous phase and an organic phase.
Claim 3
Dependent Claim
17 words
The composition of claim 1 wherein (a) is selected from palladium metal, palladium compounds and mixtures thereof.
Claim 4
Dependent Claim
19 words
The composition of claim 1 wherein (b) is selected from heteropolyacids having redox potentials in excess of 0.5 volts.
Claim 5
Dependent Claim
22 words
The composition of claim 1 wherein (a) is palladium chloride and (b) is H 9 [PMo 6 V 6 O 40 ].
Claim 6
Dependent Claim
10 words
The composition of claim 4 wherein (c) is cetyltrimethylammonium bromide.
Claim 7
Dependent Claim
11 words
The composition of claim 5 wherein (d) contains water and decane.
Claim 8
Dependent Claim
21 words
The composition of claim 1 wherein the molar ratio of olefinic reactant to (a) is from about 5:1 to about 1000:1.
Claim 9
Dependent Claim
19 words
The composition of claim 1 wherein the molar ratio of (b) to (a) is not more than about 50:1.
Claim 10
Dependent Claim
19 words
The composition of claim 8 wherein the molar ratio of (c) to (a) is about 0.01:1 to about 10:1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-02-27 | 1987-08-29 | 1988-02-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-02-27 | 1991-08-29 | 1992-02-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-02-27 | 1995-08-29 | 1996-02-28 | $7700.00 | Window Closed / Lapsed |