← Back to Patent Explorer
US4433121A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymerization process

Assignee: Mitsui Chemicals Inc
•
Filing: 1982-07-06
•
Granted: 1984-02-21
•
Expires: 2002-07-06
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract In a process for polymerizing a monomer capable of being formed, upon polymerization, into a solution having an upper cloud point of the corresponding polymer in a reaction medium being liquid under the reaction conditions, the polymerization being carried out under such conditions that the resulting polymer dissolves in the reaction medium; the improvement wherein (i) the polymerization is carried out in a polymerization zone at a temperature above the upper cloud point of said polymer solution and under conditions which enable the polymer solution to be separated into two phases, (ii) the polymerization is carried out under stirring conditions which maintain the two phases under said phase-separating conditions in a dispersed and mixed state, and (iii) the resulting polymer solution is sent to a separating zone located independently of said polymerization zone, thereby separating it into two phases in the separating zone at a temperature above the upper cloud point, and thereafter, the polymer-rich liquid phase as a lower layer is recovered while the polymer-lean liquid phase as an upper layer is recycled to the polymerization zone.

Inventors

  • 👤 Yasunori Kabu
  • 👤 Masayoshi Yasunaka
  • 👤 Yoshinori Morita
  • 👤 Masanori Motowoka

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 20:06
CPC Classifications
C; C08; C08F; C08F10/00; C08F10/02; C08F210/00; C08F210/16

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 192 words
In a process for polymerizing a monomer capable of being formed, upon polymerization, into a solution having an upper cloud point of the corresponding polymer in a reaction medium being liquid under the reaction conditions, the polymerization being carried out under such conditions that the resulting polymer dissolves in the reaction medium; the improvement wherein (i) the polymerization is carried out in a polymerization zone under a pressure of from atmosphere pressure to about 150 kg/cm 2 ·G and at a temperature above the upper cloud point of said polymer solution and under conditions which enable the polymer solution to be separated into two phases, (ii) the polymerization is carried out under stirring conditions which maintain the two phases under said phase-separating conditions in a dispersed and mixed state, and (iii) the resulting polymer solution is sent to a separating zone located independently of said polymerization zone, thereby separating it into two phases in the separating zone at a temperature above the upper cloud point, and thereafter, the polymer-rich liquid phase as a lower layer is recovered while the polymer-lean liquid phase as an upper layer is recycled to the polymerization zone.
Claim 2
Dependent Claim 192 words
In a process for polymerizing a monomer capable of being formed, upon polymerization, into a solution having an upper cloud point of the corresponding polymer in a reaction medium being liquid under the reaction conditions, the polymerization being carried out under such conditions that the resulting polymer dissolves in the reaction medium; the improvement wherein (i) the polymerization is carried out in a polymerization zone under a pressure of from atmosphere pressure to about 150 kg/cm 2 ·G and at a temperature above the upper cloud point of said polymer solution and under conditions which enable the polymer solution to be separated into two phases, (ii) the polymerization is carried out under stirring conditions which maintain the two phases under said phase-separating conditions in a dispersed and mixed state, and (iii) the resulting polymer solution is sent to a separating zone located independently of said polymerization zone, thereby separating it into two phases in the separating zone at a temperature above the upper cloud point, and thereafter, the polymer-rich liquid phase as a lower layer is recovered while the polymer-lean liquid phase as an upper layer is recycled to the polymerization zone.
Claim 3
Dependent Claim 23 words
The process of claim 1 wherein said monomer is at least one member selected from the group consisting of ethylene, α-olefins and polyenes.
Claim 4
Dependent Claim 31 words
The process of claim 2 wherein the reaction medium is at least one member selected from the group consisting of inert hydrocarbons and the same olefins as used in the polymerization.
Claim 5
Dependent Claim 31 words
The process of claim 1 wherein the polymerization is carried out at a temperature between the upper cloud point and a temperature about 200° C. higher than the upper cloud point.
Claim 6
Dependent Claim 22 words
The process of claim 2 wherein the monomer is ethylene, or a mixture of ethylene and a C 3 -C 18 α-olefin.
Claim 7
Dependent Claim 55 words
The process of claim 2 wherein the polymerization is carried out in the presence of a catalyst composed of (a) a highly active transition metal compound catalyst component capable of forming at least 5,000 g of polymer per millimole of titanium and containing titanium, magnesium and halogen as essential ingredients and (b) an organoaluminum compound.
Claim 8
Dependent Claim 24 words
The process of claim 1 wherein the polymerization is carried out at a pressure of from about 2 to about 70 kg/cm 2 ·G.

References Cited (Backward Citations)

US2945016A Cited
GB1039911A Cited
US3362943A Cited
US3362940A Cited
US4330651A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-02-20 1987-08-22 1988-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-02-20 1991-08-22 1992-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-02-20 1995-08-22 1996-02-21 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag