Precipitation-adsorption process for the decontamination of nuclear waste supernates

Claim 2

Process for the removal of the residual hazardous soluble values from a nuclear waste solution which comprises simultaneously contacting said solution with sufficient sodium tetraphenylboron and sufficient sodium titanate to form an insoluble slurry including said hazardous values and filtering said solution to separate and substantially decontaminate said solution of said hazardous values.

Claim 3

Process as claimed in claim 1 wherein said hazardous soluble values are selected from the group consisting essentially of cesium, plutonium and strontium.

Claim 4

Process as claimed in claim 1 wherein said hazardous values are isotopes of cesium, plutonium and strontium.

Claim 5

Process as claimed in claim 1 wherein said waste solution also contains significant quantities of the elements selected from the group sodium and potassium.

Claim 6

Process as claimed in claim 4 wherein said potassium is also removed from said waste solution.

Claim 7

Process for the decontamination of a nuclear waste solution containing cesium, strontium and residual amounts of soluble plutonium which comprises simultaneously contacting said waste solution containing said values with a solution of sodium tetraphenylboron in sufficient quantity to precipitate said cesium and with sufficient insoluble sodium titanate to sorb said strontium and said soluble plutonium from said waste solution to thereby form an insoluble slurry containing said cesium, strontium and plutonium, filtering said solution to separate said insoluble slurry and to provide a waste solution substantially decontaminated of said cesium, strontium and plutonium.

Claim 8

Process for the decontamination of a nuclear waste solution containing cesium, strontium and residual amounts of soluble plutonium which comprises simultaneously contacting said waste solution containing said values with a solution of sodium tetraphenylboron in sufficient quantity to precipitate said cesium and with sufficient insoluble sodium titanate to sorb said strontium and said soluble plutonium from said waste solution to thereby form an insoluble slurry containing said cesium, strontium and plutonium, filtering said solution to separate said insoluble slurry and to provide a waste solution substantially decontaminated of said cesium, strontium and plutonium.

Claim 9

Process for the decontamination of a nuclear waste solution having cesium, plutonium and strontium values which comprises contacting said waste solution with sufficient sodium tetraphenylboron and sufficient insoluble sodium titanate to remove said cesium, plutonium and strontium values from said solution and recovering said solution which has been substantially decontaminated of cesium, plutonium and strontium.

Claim 10

Process for the decontamination of a nuclear waste solution having cesium, plutonium and strontium values which comprises contacting said waste solution with sufficient sodium tetraphenylboron and sufficient insoluble sodium titanate to remove said cesium, plutonium and strontium values from said solution and recovering said solution which has been substantially decontaminated of cesium, plutonium and strontium.

Claim 11

Process as claimed in claim 1 wherein said solution contains up to 8.0 M of sodium ion.

Claim 12

Process as claimed in claim 7 wherein said contacting step is conducted for at least one quarter hour.

Claim 13

Process as claimed in claim 7 wherein an excess of the sodium tetraphenyl boron is used.

Claim 14

Process as claimed in claim 7 wherein said nuclear waste solution also contains potassium values and enough of said sodium tetraphenyl boron to also remove said potassium values.

Claim 15

Process as claimed in claim 7 wherein said nuclear waste is a nuclear waste supernate having hazardous levels of cesium, plutonium and strontium.

Claim 16

Process for the removal of cesium, plutonium and strontium values from a nuclear waste solution contaminated with said values which comprises simultaneously contacting said waste solution with sufficient sodium tetraphenylboron to precipitate said cesium and sufficient insoluble sodium titanate to sorb said plutonium and strontium, respectively, from said waste solution and filtering said waste solution to separate said solution which has been substantially decontaminated of cesium, plutonium and strontium.

Claim 17

Process for the removal of cesium, plutonium and strontium values from a nuclear waste solution contaminated with said values which comprises simultaneously contacting said waste solution with sufficient sodium tetraphenylboron to precipitate said cesium and sufficient insoluble sodium titanate to sorb said plutonium and strontium, respectively, from said waste solution and filtering said waste solution to separate said solution which has been substantially decontaminated of cesium, plutonium and strontium.

Claim 18

Process as claimed in claim 13 wherein said filtration is achieved by cross-flow filtration means.

Claim 19

Process as claimed in claim 13 wherein a stream of wash water, approximately equal to the filtrate withdrawal rate from the filter, is continuously added to said wash solution during said filtration.

Claim 20

Process as claimed in claim 13 wherein said solution contains up to 8.0 M of sodium ion.

Claim 21

Process as claimed in claim 13 wherein said contacting step is conducted for at least one quarter hour.

Claim 22

Process as claimed in claim 13 wherein an excess of the sodium tetraphenyl boron is used.

Claim 23

Process as claimed in claim 18 wherein an excess of at least 0.0005 M of sodium tetraphenyl boron is used.

Claim 24

Process as claimed in claim 13 wherein said nuclear waste solution also contains potassium values and enough of said sodium tetraphenyl boron to also remove said potassium values.

Claim 25

Process as claimed in claim 13 wherein said nuclear waste is a nuclear waste supernate hazardous levels of cesium, plutonium and strontium.