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US4432833A Expired / Lapsed US ⏱️ 0.0 years remaining

Pulp containing hydrophilic debonder and process for its application

Assignee: Kimberly Clark Worldwide Inc
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Filing: 1982-02-25
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Granted: 1984-02-21
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Expires: 2002-02-25
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Abstract

Abstract The invention provides a cellulosic pulp having reduced interfiber bonding and therefore reduced physical strength while maintaining excellent hydrophilic properties. The pulp is produced by treating the cellulosic fibers with a hydrophilic debonder having the general formula: <IMAGE> wherein: R1=methyl, ethyl, propyl, hydrogen or hydroxyethyl, R2=methyl, ethyl, propyl or [ethylene oxide]n where N=1 to 50, R3=aliphatic chain of at least 4 carbon atoms, R4=[ethylene oxide]n or [propylene oxide]n with N=1 to 50, X-Cl, I, Br, SO4-, PO4--, CH3CO2.

Inventors

  • 👤 John A. Breese

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 06:04
CPC Classifications
A; A61; A61L; A61L15/00; A61L15/16; A61L15/20; D; D21; D21C; D21C9/00; D21C9/001; D21C9/002; D21C9/005

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 100 words
A wood pulp consisting essentially of a hydrophilic debonder having the general formula: ##STR5## wherein: R 1 =methyl, ethyl, propyl, hydrogen or hydroxyethyl, R 2 =methyl, ethyl, propyl or (ethylene oxide) n where n=1 to 50, R 3 =aliphatic chain of at least 4 carbon items, R 4 =(ethylene oxide) n or (propylene oxide) n with n=1 to 50, X=Cl, I, Br, SO 4 , PO 4 , CH 3 CO 2 said debonder present at the level of 0.1% to 5.0% by weight of the dry cellulosic material in an amount sufficient to increase the water and/or urine absorbency.
Claim 2
Dependent Claim 100 words
A wood pulp consisting essentially of a hydrophilic debonder having the general formula: ##STR5## wherein: R 1 =methyl, ethyl, propyl, hydrogen or hydroxyethyl, R 2 =methyl, ethyl, propyl or (ethylene oxide) n where n=1 to 50, R 3 =aliphatic chain of at least 4 carbon items, R 4 =(ethylene oxide) n or (propylene oxide) n with n=1 to 50, X=Cl, I, Br, SO 4 , PO 4 , CH 3 CO 2 said debonder present at the level of 0.1% to 5.0% by weight of the dry cellulosic material in an amount sufficient to increase the water and/or urine absorbency.
Claim 3
Dependent Claim 144 words
A process for treating cellulose pulp fibers to reduce interfiber bonding while preserving the hydrophilicity of the pulp comprising adding to a cellulose pulp fiber slurry prior to or during the formation of the slurry into a web a debonder consisting essentially of quaternary ammonium compound having the formula: ##STR6## wherein: R 1 =methyl, ethyl, propylene, hydrogen or hydroxyethyl, R 2 =methyl, ethyl, propyl or (ethylene oxide) n where n=1 to 50, R 3 =aliphatic chain of at least 4 carbon atoms, R 4 =(ethylene oxide) n or (propylene oxide) n with n=1 to 50, X=Cl, I, Br, SO 4 , PO 4 , CH 3 CO 2 and forming and drying said web, said quaternary ammonium compound added at a level of 0.1% to 5.0% by weight of the dry cellulosic material in an amount sufficient to increase the water and/or urine absorbency.
Claim 4
Dependent Claim 144 words
A process for treating cellulose pulp fibers to reduce interfiber bonding while preserving the hydrophilicity of the pulp comprising adding to a cellulose pulp fiber slurry prior to or during the formation of the slurry into a web a debonder consisting essentially of quaternary ammonium compound having the formula: ##STR6## wherein: R 1 =methyl, ethyl, propylene, hydrogen or hydroxyethyl, R 2 =methyl, ethyl, propyl or (ethylene oxide) n where n=1 to 50, R 3 =aliphatic chain of at least 4 carbon atoms, R 4 =(ethylene oxide) n or (propylene oxide) n with n=1 to 50, X=Cl, I, Br, SO 4 , PO 4 , CH 3 CO 2 and forming and drying said web, said quaternary ammonium compound added at a level of 0.1% to 5.0% by weight of the dry cellulosic material in an amount sufficient to increase the water and/or urine absorbency.
Claim 5
Dependent Claim 29 words
The process according to claim 2 wherein the quaternary ammonium compound applied to the fibers is from about 0.05% to 5.0% based on the dry weight of the cellulose.
Claim 6
Dependent Claim 26 words
The process according to claim 2 in which the quaternary ammonium compound is added by spraying a solution thereof on the web and drying the web.
Claim 7
Dependent Claim 26 words
The process according to claim 2 wherein the quaternary ammonium compound is added to the slurry of cellulosic pulp fibers and the pulp is subsequently dried.
Claim 8
Dependent Claim 15 words
A process according to claim 2 in which the web is fiberized into cellulose fluff.
Claim 9
Dependent Claim 25 words
A process according to claim 2 in which the quaternary ammonium compound is added during formation of the cellulose pulp fiber slurry into a web.
Claim 10
Dependent Claim 10 words
An absorbent fluff containing the hydrophilic debonder of claim 1.
Claim 11
Dependent Claim 109 words
A diaper containing an absorbent fluff with a hydrophilic debonder said debonder consisting essentially of a compound having the general formula: ##STR7## wherein: R 1 =methyl, ethyl, propyl, hydrogen or hydroxyethyl, R 2 =methyl, ethyl, propyl or (ethylene oxide) n where n=1 to 50, R 3 =aliphatic chain of at least 4 carbon atoms, R 4 =(ethylene oxide) n or (propylene oxide) n with n=1 to 50, X=Cl, I, Br, SO 4 , PO 4 , CH 3 CO 2 said debonder being present at the level of 0.1% to 5.0% by weight of the dry cellulosic material in an amount sufficient to increase the water and/or urine absorbency.
Claim 12
Dependent Claim 109 words
A diaper containing an absorbent fluff with a hydrophilic debonder said debonder consisting essentially of a compound having the general formula: ##STR7## wherein: R 1 =methyl, ethyl, propyl, hydrogen or hydroxyethyl, R 2 =methyl, ethyl, propyl or (ethylene oxide) n where n=1 to 50, R 3 =aliphatic chain of at least 4 carbon atoms, R 4 =(ethylene oxide) n or (propylene oxide) n with n=1 to 50, X=Cl, I, Br, SO 4 , PO 4 , CH 3 CO 2 said debonder being present at the level of 0.1% to 5.0% by weight of the dry cellulosic material in an amount sufficient to increase the water and/or urine absorbency.
Claim 13
Dependent Claim 106 words
An absorbent cellulosic based sheet stock with a hydrophilic debonder said debonder consisting essentially of the general formula: ##STR8## wherein: R 1 =methyl, ethyl, propyl, hydrogen or hydroxyethyl, R 2 =methyl, ethyl, propyl or (ethylene oxide) n where n=1 to 50, R 3 =aliphatic chain of at least 4 carbon atoms, R 4 =(ethylene oxide) n or (propylene oxide) n with n=1 to 50, X=Cl, I, Br, So 4 , PO 4 , CH 3 CO 2 said debonder being present at the level of 0.1% to 5.0% by weight of the dry cellulosic material in an amount sufficient to increase the water and/or urine absorbency.
Claim 14
Dependent Claim 106 words
An absorbent cellulosic based sheet stock with a hydrophilic debonder said debonder consisting essentially of the general formula: ##STR8## wherein: R 1 =methyl, ethyl, propyl, hydrogen or hydroxyethyl, R 2 =methyl, ethyl, propyl or (ethylene oxide) n where n=1 to 50, R 3 =aliphatic chain of at least 4 carbon atoms, R 4 =(ethylene oxide) n or (propylene oxide) n with n=1 to 50, X=Cl, I, Br, So 4 , PO 4 , CH 3 CO 2 said debonder being present at the level of 0.1% to 5.0% by weight of the dry cellulosic material in an amount sufficient to increase the water and/or urine absorbency.

References Cited (Backward Citations)

US3554863A Cited
US4144122A Cited
US4303471A Cited
US4351699A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-02-20 1987-08-22 1988-02-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-02-20 1991-08-22 1992-02-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-02-20 1995-08-22 1996-02-21 $7700.00 Window Closed / Lapsed

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