US4431787A
Expired / Lapsed
US
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Anaerobic adhesives
Assignee: SAF-T-LOK CHEMICAL Corp 5024 CHASE AVE DOWNERS GROVE IL 60515
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Filing: 1981-05-20
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Granted: 1984-02-14
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Expires: 2001-05-20
Abstract
Abstract Polymerizable acrylic monomers, and anaerobic adhesives which contain such monomers, wherein the acrylic monomers contain internal chain unsaturation in addition to terminal acrylic unsaturation.
Inventors
- 👤 Gerhardt P. Werber
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 23:30
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/34; C08F20/36; C08F20/26; C08F20/28; C09; C09J; C09J4/00
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
176 words
An anaerobic adhesive composition, comprising: an acrylic monomer having the general formula: ##STR14## wherein R" is a member selected from the group consisting of hydrogen, chlorine, methyl and ethyl radicals; R 2 is an unsaturated divalent alkyl or substituted alkyl group of from 2-4 carbon atoms, or an unsaturated divalent carbocyclic aliphatic ring of from 4-9 carbon atoms; R is ##STR15## where p is an integer of from 0 to 2, q is an integer of from 1 to 3, R 1 is a member selected from the group consisting of hydrogen, methyl, ethyl, chloromethyl, methylol, phenyl, methoxyphenyl, methoxybutyl, methoxyallyl and ##STR16## radicals where R" is as previously defined, and X is a member selected from the group consisting of --O--, --NH-- and --NR'-- where R' is a benzyl radical or an alkyl group of from 1-4 carbon atoms; and Y is hydrogen, a metal, an amine ion, an ammonium ion, a guanidinium ion, or a short length carbon chain; said acrylic monomer being in combination with a metal activatable polymerization catalyst and a polymerization inhibitor.
Claim 2
Dependent Claim
176 words
An anaerobic adhesive composition, comprising: an acrylic monomer having the general formula: ##STR14## wherein R" is a member selected from the group consisting of hydrogen, chlorine, methyl and ethyl radicals; R 2 is an unsaturated divalent alkyl or substituted alkyl group of from 2-4 carbon atoms, or an unsaturated divalent carbocyclic aliphatic ring of from 4-9 carbon atoms; R is ##STR15## where p is an integer of from 0 to 2, q is an integer of from 1 to 3, R 1 is a member selected from the group consisting of hydrogen, methyl, ethyl, chloromethyl, methylol, phenyl, methoxyphenyl, methoxybutyl, methoxyallyl and ##STR16## radicals where R" is as previously defined, and X is a member selected from the group consisting of --O--, --NH-- and --NR'-- where R' is a benzyl radical or an alkyl group of from 1-4 carbon atoms; and Y is hydrogen, a metal, an amine ion, an ammonium ion, a guanidinium ion, or a short length carbon chain; said acrylic monomer being in combination with a metal activatable polymerization catalyst and a polymerization inhibitor.
Claim 3
Dependent Claim
23 words
The anaerobic adhesive composition of claim 1 wherein R" is methyl, R 2 is --HC═CH-- and R is --CH 2 CH 2 O--.
Claim 4
Dependent Claim
41 words
The anaerobic adhesive composition of claim 1 wherein said catalyst is an organic hydroperoxide catalyst, and said inhibitor is a quinone inhibitor, in further combination with a promoter selected from the group consisting of organic amines, imides, sulfimides, and mixtures thereof.
Claim 5
Dependent Claim
15 words
The anaerobic adhesive composition of claim 1, blended with one or more polymerizable acrylic monomers.
Claim 6
Dependent Claim
83 words
The anaerobic adhesive composition of claim 1, blended with one or more polymerizable acrylic monomers selected from the group consisting of hydroxyethyl methacrylate, hydroxypropyl methacrylate, trimethylolpropane trimethacrylate, dibromopropyl methacrylate, diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, dimethylaminoethyl methacrylate, tetraethylene glycol dimethacrylate, dipropylene glycol dimethacrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, polyethylene glycol dimethacrylate, di-(pentamethylene glycol) dimethyacrylate, n-butyl methacrylate, trimethylolpropane triacrylate, tetraethylene glycol diacrylate, isobutyl methacrylate, tetraethylene glycol di-(chloroacrylate), diglycerol diacrylate, diglycerol tetramethacrylate, butylene glycol dimethacrylate, ethylene glycol dimethacrylate, neopentyl glycol diacrylate, and tetrahydrofurural methacrylate.
Claim 7
Dependent Claim
11 words
The anaerobic adhesive composition of claim 1, wherein q is 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-02-13 | 1987-08-15 | 1988-02-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-02-13 | 1991-08-15 | 1992-02-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-02-13 | 1995-08-15 | 1996-02-14 | $7700.00 | Window Closed / Lapsed |