US4431630A
Expired / Lapsed
US
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Dentifrice composition
Assignee: Colgate Palmolive Co
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Filing: 1982-04-29
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Granted: 1984-02-14
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Expires: 2002-04-29
Abstract
Abstract A dentifrice composition containing a water-soluble monofluorophosphate and a calcium salt polishing agent, principally dicalcium phosphate, and a surface active agent containing an anionic phosphate mono- and di- ester mixture. An alkali metal fluoride may be present in minor amount to the monofluorophosphate. The phosphate ester mixture improves retention of soluble fluoride.
Inventors
- 👤 Anthony J. Morton
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 08:04
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/19; A61K8/24; A61K8/30; A61K8/55; A61K8/556; A61Q; A61Q11/00; C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0838; C08G18/0842; C08G18/0861; C08G18/0871; C08G18/0876; C08G18/28; C08G18/30; C08G18/32; C08G18/3271; C08G18/3278; C08G18/40; C08G18/409; C08J; C08J9/00; C08J9/0061; C08J2375/00; C08J2375/04; C08J2475/00
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
231 words
A toothpaste dentifrice composition consisting essentially of a non-toxic amount of about 0.05-7.6% by weight of a water-soluble monofluorophosphate, an alkali metal fluoride present in amount to provide up to about 35% by weight of the fluorine, the remainder being provided by the said monofluorophosphate, about 20-75% by weight of a polishing material consisting essentially of a calcium salt member selected from the group consisting of dicalcium phosphate as the single calcium salt polishing material and calcium salt polishing material of at least half by weight of dicalcium phosphate with a member selected from the group consisting of calcium carbonate, calcium pyrophosphate, tricalcium phosphate and calcium polymetaphosphate and about 0.05-5% by weight of a water-soluble surface active material consisting essentially of a non-cationic surface active agent, said non-cationic surface active agent containing an anionic phosphate ester mixture in an amount of at least about 0.1% by weight of the said dentifrice, the said anionic phosphate ester mixture being a mixture of an anionic phosphate monoester of the formula: ##STR3## and anionic phosphate diester of the formula: ##STR4## wherein R represents an alkyl group of 10-20 carbon atoms, n is an integer from 1 to 6 and M represents a member selected from the group consisting of hydrogen atom of an alkali metal cation or an ammonium group, wherein said anionic phosphate mixture improves the retention of soluble fluorine in said dentifrice.
Claim 2
Dependent Claim
231 words
A toothpaste dentifrice composition consisting essentially of a non-toxic amount of about 0.05-7.6% by weight of a water-soluble monofluorophosphate, an alkali metal fluoride present in amount to provide up to about 35% by weight of the fluorine, the remainder being provided by the said monofluorophosphate, about 20-75% by weight of a polishing material consisting essentially of a calcium salt member selected from the group consisting of dicalcium phosphate as the single calcium salt polishing material and calcium salt polishing material of at least half by weight of dicalcium phosphate with a member selected from the group consisting of calcium carbonate, calcium pyrophosphate, tricalcium phosphate and calcium polymetaphosphate and about 0.05-5% by weight of a water-soluble surface active material consisting essentially of a non-cationic surface active agent, said non-cationic surface active agent containing an anionic phosphate ester mixture in an amount of at least about 0.1% by weight of the said dentifrice, the said anionic phosphate ester mixture being a mixture of an anionic phosphate monoester of the formula: ##STR3## and anionic phosphate diester of the formula: ##STR4## wherein R represents an alkyl group of 10-20 carbon atoms, n is an integer from 1 to 6 and M represents a member selected from the group consisting of hydrogen atom of an alkali metal cation or an ammonium group, wherein said anionic phosphate mixture improves the retention of soluble fluorine in said dentifrice.
Claim 3
Dependent Claim
22 words
The dentifrice composition as claimed in claim 1 wherein the said dicalcium phosphate is present in amount of about 40-60% by weight.
Claim 4
Dependent Claim
17 words
The dentifrice composition as claimed in claim 1 in which the said water-soluble monofluorophosphate is sodium monfluorophosphate.
Claim 5
Dependent Claim
28 words
The dentifrice composition as claimed in claim 1 in which the said alkali metal fluoride is present in amount to provide about 30-35% by weight of the fluorine.
Claim 6
Dependent Claim
17 words
The dentifrice composition as claimed in claim 3 in which the alkali metal fluoride is sodium fluoride.
Claim 7
Dependent Claim
25 words
The dentifrice composition as claimed in claim 1 in which the said dicalcium phosphate is the only polishing agent present in the said polishing material.
Claim 8
Dependent Claim
22 words
The dentifrice composition as claimed in claim 1 in which the alkyl groups in the anionic phosphate ester contain 16-18 carbon atoms.
References Cited (Backward Citations)
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US4238476A
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US4264580A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-02-13 | 1987-08-15 | 1988-02-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-02-13 | 1991-08-15 | 1992-02-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-02-13 | 1995-08-15 | 1996-02-14 | $7700.00 | Window Closed / Lapsed |