Mixed nitrate salt heat transfer medium and process for providing the same

Claim 2

A process for preparing particles of a non-friable, eutectic mixture of sodium nitrate and potassium nitrate for use as a heat transfer and thermal storage medium for solar power stations comprising steps of: (a) preparing a fluid mixture of between about 70% and about 30% by weight sodium nitrate and about 30% and about 70% by weight potassium nitrate, wherein said fluid mixture has a combined level of sulfates, oxides, carbonates and chlorides of no more than about 0.7% by weight and with the chloride being no more than about 0.2% by weight; (b) granulating said fluid mixture by a process selected from the group consisting of shock chilling and spray graining to form substantially homogeneous particles of said mixture; and (c) recovering a salt product comprised of particles having a predetermined mesh size.

Claim 3

The process of claim 1 wherein said fluid mixture is formed by: (a) admixing granular NaNO 3 and granular KNO 3 to produce a dry blended substantially homogeneous salt mix; and (b) heating said salt mix while agitating it until it fuses to form a molten mass.

Claim 4

The process of claim 2 wherein said salt mix is heated to a temperature in the range of from about 220° C. to about 300° C.

Claim 5

The process of claim 3 wherein said salt mix is heated to a temperature in the range of from about 220° C. to about 245° C.

Claim 6

The process of claim 2 wherein said particles are formed by a shock chilling process which comprises: (a) pouring said molten mass onto a chilled surface to form a solid, amorphous homogeneous sheet; and (b) breaking up said sheet to form said particles.

Claim 7

The process of claim 5 wherein said solid sheet is between about 0.20" and about 1.25" thick.

Claim 8

The process of claim 5 wherein said solid sheet is between about 0.25" and about 0.75" thick.

Claim 9

The process of claim 1 wherein said fluid mixture is an aqueous solution of sodium nitrate and potassium nitrate.

Claim 10

The process of claim 8 wherein said aqueous solution has a total salt concentration of between about 60% and about 75% by weight.

Claim 11

The process of claim 8 wherein said aqueous solution is at a temperature of between about 95° C. and about 120° C.

Claim 12

The process of claim 8 wherein said granulation step is carried out by spray graining in a process which comprises: (a) spraying said aqueous solution into a drying chamber and contacting said sprayed solution with a heated gas flowing through said chamber to form a dried fine particulate product, said fine particulate product being fluidized by said flowing gas; and (b) agglomerating said fluidized fine particulate product by contacting it with additional aqueous solution which is being sprayed into said drying chamber for a time sufficient to form agglomerated particles of a predetermined mesh size.

Claim 13

The process of claim 10 wherein said heated gas is at a temperature of between about 160° C. and about 200° C.

Claim 14

The process of claim 5 or claim 11 wherein said recovery step comprises screening said agglomerated particles to separate out salt particles having an acceptable size range from those which are oversized or undersized.

Claim 15

The process of claim 13 wherein said acceptable salt particles are in the range of between about -5 mesh to about +30 mesh.

Claim 16

The process of claim 13 wherein oversized particles of said mix are crushed and rescreened.

Claim 17

The process of claim 13 wherein undersized particles of said mix are recycled to form a part of the feedstock for said fluid mixture.

Claim 18

The process of claim 13 wherein said salt particles are comprised of between about 65% and about 55% by weight sodium nitrate and about 35% to about 45% by weight potassium nitrate.

Claim 19

A process for making non-friable, dried salt particles for use as a heat transfer medium for solar power stations, said salt particles being a eutectic mixture of between about 70% and about 30% by weight sodium nitrate and between about 30% and about 70% by weight potassium nitrate, said particles being further characterized by having a maximum combined chloride, sulfate, oxide and carbonate content of about 0.7% by weight with the maximum chloride content being about 0.2%, said salt particles having been produced by a method comprising the steps of: (a) admixing granular NaNO 3 and granular KNO 3 to produce a dry blended substantially homogeneous salt mix; (b) heating said salt mix to a temperature in the range of about 220° C. to about 300° C. while agitating it until it fuses to form a molten mass; (c) pouring said molten mass onto a chilled surface at a rate sufficient to form a solid, amorphous homogeneous sheet of between about 0.20" and about 1.25" thick; (d) breaking up said sheet to form said particles; and (e) classifying said particles to recover a final product.

Claim 20

A process for making non-friable, dried salt particles for use as a heat transfer medium for solar power stations, said salt particles being a eutectic mixture of between about 70% and about 30% by weight sodium nitrate and between about 30% and about 70% by weight potassium nitrate, said particles being further characterized by having a maximum combined chloride, sulfate, oxide and carbonate content of about 0.7% by weight with the maximum chloride content being about 0.2%, said salt particles having been produced by a method comprising the steps of: (a) admixing granular NaNO 3 and granular KNO 3 to produce a dry blended substantially homogeneous salt mix; (b) heating said salt mix to a temperature in the range of about 220° C. to about 300° C. while agitating it until it fuses to form a molten mass; (c) pouring said molten mass onto a chilled surface at a rate sufficient to form a solid, amorphous homogeneous sheet of between about 0.20" and about 1.25" thick; (d) breaking up said sheet to form said particles; and (e) classifying said particles to recover a final product.

Claim 21

A process for making non-friable, dried salt particles for use as a heat transfer medium for solar power stations, said salt particles being a eutectic mixture of between about 70% and about 30% by weight sodium nitrate and between about 30% and about 70% by weight potassium nitrate, said particles being further characterized by having a maximum combined chloride, sulfate, oxide and carbonate content of about 0.7% by weight with the maximum chloride content being about 0.2%, said salt particles having been produced by a method comprising the steps of: (a) forming an aqueous solution of sodium nitrate and potassium nitrate, said solution having a total salt content of between about 60% and about 75% combined salt by weight at a temperature of between about 95° C. and about 120° C.; (b) spraying said aqueous solution into a drying chamber and contacting said sprayed solution with a heated gas flowing through said chamber to form a dried fine particulate product, said fine particulate product being fluidized by said flowing gas; (c) agglomerating said fluidized fine particulate product by contacting it with additional aqueous solution which is being sprayed into said drying chamber for a time sufficient to form said particles; and (d) classifying said particles to recover a final product.

Claim 22

A process for making non-friable, dried salt particles for use as a heat transfer medium for solar power stations, said salt particles being a eutectic mixture of between about 70% and about 30% by weight sodium nitrate and between about 30% and about 70% by weight potassium nitrate, said particles being further characterized by having a maximum combined chloride, sulfate, oxide and carbonate content of about 0.7% by weight with the maximum chloride content being about 0.2%, said salt particles having been produced by a method comprising the steps of: (a) forming an aqueous solution of sodium nitrate and potassium nitrate, said solution having a total salt content of between about 60% and about 75% combined salt by weight at a temperature of between about 95° C. and about 120° C.; (b) spraying said aqueous solution into a drying chamber and contacting said sprayed solution with a heated gas flowing through said chamber to form a dried fine particulate product, said fine particulate product being fluidized by said flowing gas; (c) agglomerating said fluidized fine particulate product by contacting it with additional aqueous solution which is being sprayed into said drying chamber for a time sufficient to form said particles; and (d) classifying said particles to recover a final product.

Claim 23

The process of claim 18 or 19 wherein said acceptable salt particles are in the range of between about -5 mesh to about +30 mesh.

Claim 24

The process of claim 20 wherein oversized particles of said mix in size are crushed and reclassified.

Claim 25

The process of claim 20 wherein undersized particles of said mix are recycled to form a part of the feedstock for said fluid mixture.

Claim 26

Non-friable, dried salt particles for use as a heat transfer medium for solar power stations, said salt particles being a eutectic mixture of between about 70% and about 30% by weight sodium nitrate and between about 30% and about 70% by weight potassium nitrate, said particles being further characterized by having a maximum combined chloride, sulfate, oxide and carbonate content of about 0.7% by weight with the maximum chloride content being about 0.2%.

Claim 27

Non-friable, dried salt particles for use as a heat transfer medium for solar power stations, said salt particles being a eutectic mixture of between about 70% and about 30% by weight sodium nitrate and between about 30% and about 70% by weight potassium nitrate, said particles being further characterized by having a maximum combined chloride, sulfate, oxide and carbonate content of about 0.7% by weight with the maximum chloride content being about 0.2%.

Claim 28

The salt product of claim 23 wherein said salt particles are comprised of between about 65% and about 55% by weight sodium nitrate and about 35% to about 45% by weight potassium nitrate.

Claim 29

The salt product of claim 23 wherein said acceptable salt particles are in the range of between about -5 mesh to about +30 mesh.