Polymerizable compositions comprising derivatives of mono-(alkylene ureido alkyl) ureas and bis-(alkylene ureido alkyl) ureas

Claim 2

A composition suitable for use in forming aqueous emulsion polymers comprising a polymerizable mixture of at least one unsaturated monomer polymerizable to form a latex polymer for paint and at least one compound having the formula: ##STR84## where A 1 and A 5 are each independently H, Q 6 H, or ##STR85## A 3 and A 4 are each independently H, Q 1 H, or ##STR86## provided that at least one of A 1 , A 3 , A 4 and A 5 is a group having the moiety ##STR87## R 1 is alkylene having 2 to 3 carbon atoms; R 2 is alkylene having 2 to about 10 carbon atoms; R 3 is H or CH 3 ; R 4 is H or CH 3 and may be the same as or different from R 3 ; Q 1 is (R 5 --O) m where m is zero or an integer from 1 to about 100, and R 5 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms; Q 2 is ##STR88## where A 2 is H, ##STR89## where t is zero or an integer from 1 to 10; Q 3 is (O--R 6 ) n where n is zero or an integer from 1 to about 100 and may be the same as or different from m, and R 6 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 ; Q 6 is (R 9 --O) r where r is zero or an integer from 1 to about 100 and may be the same as or different from m and n and R 9 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 and R 6 ; and Y is CH 2 or ##STR90##

Claim 3

A composition according to claim 1 wherein in said compound A 1 , A 3 , A 4 and A 5 are each independently H or ##STR91## provided that at least one of A 1 , A 3 , A 4 and A 5 is ##STR92##

Claim 4

A composition according to claim 2 wherein in said compound Q 2 is ##STR93##

Claim 5

A composition according to claim 2 wherein in said compound Y is CH 2 .

Claim 6

A composition according to claim 2 wherein in said compound Y is ##STR94##

Claim 7

A composition according to claim 2 wherein in said compound both R 1 and R 2 are ethylene.

Claim 8

A composition suitable for use in forming aqueous emulsion polymers comprising a polymerizable mixture of at least one unsaturated monomer polymerizable to form a latex polymer for paint and at least one compound having the formula: ##STR95## where A is H, Q 4 H or ##STR96## A 1 is H, Q 6 H or ##STR97## A 3 is H, Q 1 H or ##STR98## A 6 is H, Q 8 H or ##STR99## provided that at least one of A, A 1 , A 3 and A 6 is a group having the moiety ##STR100## R 1 is alkylene having 2 to 3 carbon atoms; R 2 is alkylene having 2 to about 10 carbon atoms; R 3 is H or CH 3 ; R 4 is H or CH 3 and may be the same as or different from R 3 ; Q 1 is (R 5 --O) m where m is zero or an integer from 1 to about 100, and R 5 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene,, arylalkylene, and aryloxyalkylene residue having 2 to about 20 carbon atoms; Q 2 is ##STR101## where A 2 is H or ##STR102## where t is zero or an integer from 1 to 10; Q 3 is (O--R 6 ) n where n is zero or an integer from 1 to about 100 and may be the same as or different from m, and R 6 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 ; Q 4 is (R 7 --O) p where p is zero or an integer from 1 to about 100 and may be the same as or different from m and n, and R 7 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 or R 6 ; Q 5 is (O--R 8 ) q where q is zero or an integer from 1 to about 100 and may be the same as or different from m, n and p, and R 8 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 , R 6 and R 7 ; and Q 6 is (R 9 --O) r where r is zero or an integer from 1 to about 100 and may be the same as or different from m, n, p and q, and R 9 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 , R 6 , R 7 and R 8 ; and Q 7 is (O--R 10 ) s where s is zero or an integer from 1 to about 100 and may be the same as or different from m, n, p, q and r, and R 10 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 , R 6 , R 7 , R 8 , and R 9 ; Q 8 is (R 11 --O) w where w is zero or an integer from 1 to about 100 and may be the same as or different from m, n, p, q, r and s, and R 11 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene or aryloxyalkylene residue having 2 to about 20 carbon atoms and may be the same as or different from R 5 , R 6 , R 7 , R 8 , R 9 , and R 10 ; and Y is CH 2 or ##STR103##

Claim 9

A composition suitable for use in forming aqueous emulsion polymers comprising a polymerizable mixture of at least one unsaturated monomer polymerizable to form a latex polymer for paint and at least one compound having the formula: ##STR95## where A is H, Q 4 H or ##STR96## A 1 is H, Q 6 H or ##STR97## A 3 is H, Q 1 H or ##STR98## A 6 is H, Q 8 H or ##STR99## provided that at least one of A, A 1 , A 3 and A 6 is a group having the moiety ##STR100## R 1 is alkylene having 2 to 3 carbon atoms; R 2 is alkylene having 2 to about 10 carbon atoms; R 3 is H or CH 3 ; R 4 is H or CH 3 and may be the same as or different from R 3 ; Q 1 is (R 5 --O) m where m is zero or an integer from 1 to about 100, and R 5 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene,, arylalkylene, and aryloxyalkylene residue having 2 to about 20 carbon atoms; Q 2 is ##STR101## where A 2 is H or ##STR102## where t is zero or an integer from 1 to 10; Q 3 is (O--R 6 ) n where n is zero or an integer from 1 to about 100 and may be the same as or different from m, and R 6 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 ; Q 4 is (R 7 --O) p where p is zero or an integer from 1 to about 100 and may be the same as or different from m and n, and R 7 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 or R 6 ; Q 5 is (O--R 8 ) q where q is zero or an integer from 1 to about 100 and may be the same as or different from m, n and p, and R 8 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 , R 6 and R 7 ; and Q 6 is (R 9 --O) r where r is zero or an integer from 1 to about 100 and may be the same as or different from m, n, p and q, and R 9 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 , R 6 , R 7 and R 8 ; and Q 7 is (O--R 10 ) s where s is zero or an integer from 1 to about 100 and may be the same as or different from m, n, p, q and r, and R 10 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene, or aryloxyalkylene residue having 2 to about 20 carbon atoms, and may be the same as or different from R 5 , R 6 , R 7 , R 8 , and R 9 ; Q 8 is (R 11 --O) w where w is zero or an integer from 1 to about 100 and may be the same as or different from m, n, p, q, r and s, and R 11 is a linear or branched alkylene, alkoxyalkylene, cycloalkylene, cycloalkoxyalkylene, arylalkylene or aryloxyalkylene residue having 2 to about 20 carbon atoms and may be the same as or different from R 5 , R 6 , R 7 , R 8 , R 9 , and R 10 ; and Y is CH 2 or ##STR103##

Claim 10

A composition according to claim 7 wherein in said compound A, A 1 , A 3 and A 6 are each independently H or ##STR104## provided that at least one of A, A 1 , A 3 and A 6 is ##STR105##

Claim 11

A composition according to claim 8 wherein in said compound Q 2 is ##STR106##

Claim 12

A composition according to claim 8 wherein in said compound Y is CH 2 .

Claim 13

A composition according to claim 8 wherein in said compound Y is ##STR107##

Claim 14

A composition according to claim 8 wherein in said compound both R 1 and R 2 are ethylene.

Claim 15

A composition according to claims 1 or 7 which is an aqueous mixture wherein said unsaturated monomer is selected from the group consisting of an ester of acrylic acid, an ester of methacrylic acid, vinyl acetate, vinyl esters of higher carboxylic acids, styrene, vinyl toluene, acrylonitrile, acrylamide, vinyl chloride and mixtures thereof.