US4427805A
Expired / Lapsed
US
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Thermosetting resinous binder compositions, their preparation and use as coating materials
Assignee: Shell USA Inc
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Filing: 1982-09-07
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Granted: 1984-01-24
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Expires: 2002-09-07
Abstract
Abstract Thermosetting binder composition for coating, comprising: (I) (1) A non-acidic resinous compound, saturated, molecular weight at least 900, alcoholic hydroxyl content at least 0.2 eq./100 g; (2) as cross-linking agent a non-acidic polyester of a polycarboxylic acid, having more than one beta-hydroxyl ester group per molecule, at least one of components (1) and (2) having an alcoholic hydroxyl functionality of more than 2, and (II) as curing catalyst a transesterification-promoting metal compound which is insoluble in liquid hydrocarbons. <??>The compositions can be used in solvent-based lacquers and paints, in coating powders, aqueous powder suspensions, in aqueous coating compositions for cathodic electrodeposition; for aqueous compositions component (I) (1) is preferably an epoxy resin/amine adduct.
Inventors
- 👤 Petrus G. Kooijmans
- 👤 Werner T. Raudenbusch
- 👤 Adrianus M. C. Van Steenis
- 👤 Wolfgang Kunze
- 👤 Josepha M. E. Seelen-Kruijssen
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 16:09
CPC Classifications
C; C09; C09D; C09D167/00; C09D129/00; C09D129/02; C09D129/06; C09D129/08; C09D163/00; C09D201/00; C09D201/02; C09D201/06; C09D5/00; C09D5/44; C09D5/4488; C09D5/4496; Y; Y10; Y10S; Y10S524/00; Y10S524/901; Y10S524/902; Y10S524/904; Y10S525/00; Y10S525/93; Y10S525/934
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
166 words
An aqueous paint composition suitable for cathodic electrodeposition comprising a binder comprising (1) a non-acidic resinous compound having the formula: A--B--C--B).sub.m A wherein m is a number from 0 to 2, A is a group which is linked to B through a tertiary amino function and being derived from an amine having one secondary amino group, B is a group ##STR7## wherein n is a number from 0 to 4, R is a hydrocarbon radical of a dihydric phenol, and C is a group which is linked to B through two tertiary amino functions and being derived from an amine containing at least two secondary amino groups or a primary mono-amino groups, (2) a non-acidic polyester prepared by reacting a polycarboxylic acid or anhydride thereof with at least one hydroxyl-containing compound selected from the groups consisting of glycols, glycol mono-ethers and polyols, and (3) a polyvalent metal compound, said binder having from about 20% to about 100% of the amino groups neutralized with a carboxylic acid.
Claim 2
Dependent Claim
166 words
An aqueous paint composition suitable for cathodic electrodeposition comprising a binder comprising (1) a non-acidic resinous compound having the formula: A--B--C--B).sub.m A wherein m is a number from 0 to 2, A is a group which is linked to B through a tertiary amino function and being derived from an amine having one secondary amino group, B is a group ##STR7## wherein n is a number from 0 to 4, R is a hydrocarbon radical of a dihydric phenol, and C is a group which is linked to B through two tertiary amino functions and being derived from an amine containing at least two secondary amino groups or a primary mono-amino groups, (2) a non-acidic polyester prepared by reacting a polycarboxylic acid or anhydride thereof with at least one hydroxyl-containing compound selected from the groups consisting of glycols, glycol mono-ethers and polyols, and (3) a polyvalent metal compound, said binder having from about 20% to about 100% of the amino groups neutralized with a carboxylic acid.
Claim 3
Dependent Claim
22 words
The aqueous paint composition of claim 1, wherein the binder comprises from about 2 to about 20% by weight of the composition.
Claim 4
Dependent Claim
11 words
The composition of claim 1, wherein A is a dialkanolamino group.
Claim 5
Dependent Claim
21 words
The composition of claim 1, wherein the non-acidic polyester is prepared from a polycarboxylic acid or anhydride thereof with a monoepoxide.
Claim 6
Dependent Claim
12 words
The composition of claim 4, wherein polycarboxylic acid anhydride is trimellitic anhydride.
Claim 7
Dependent Claim
21 words
The composition of claim 1, wherein the polyvalent metal compound is a transesterification-promoting metal compound which is insoluble in liquid hydrocarbons.
Claim 8
Dependent Claim
12 words
The composition of claim 1, wherein the carboxylic acid is lactic acid.
Claim 9
Dependent Claim
28 words
The composition of claim 1, wherein the non-acid resinous compound is a polymeric glycidyl or glyceryl polyether of 2,2-bis(4-hydroxyphenyl)propane having a molecular weight (Mn) of more than 1400.
References Cited (Backward Citations)
US3956245A
Cited
US4148772A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-23 | 1987-07-25 | 1988-01-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-23 | 1991-07-25 | 1992-01-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-23 | 1995-07-25 | 1996-01-24 | $7700.00 | Window Closed / Lapsed |