US4426365A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for removing nitrogen oxides from gas streams and regenerating spent sorbent
Assignee: Noxso Corp
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Filing: 1981-03-31
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Granted: 1984-01-17
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Expires: 2001-03-31
Abstract
Abstract Novel sorbents comprising (a) an alumina component comprising alumina of the surface area of at least 20 and preferably 100 square meters per gram, and (b) a salt, or mixtures of salts, of an alkali or alkaline earth metal, especially oxides, hydroxides, carbonates, nitrates, acetates or aluminates of sodium and potassium, are outstandingly effective for the removal of nitrogen oxides and sulfur oxides from waste gas streams.
Inventors
- 👤 Jules Magder
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 04:59
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/0404; B; B01; B01D; B01D53/00; B01D53/14; B01D53/1493; B01D53/34; B01D53/46; B01D53/54; B01D53/56; B01D53/92; B01D53/94; B01D53/9404; B01D53/9409; B01D53/9413; B01D53/9422; B01J; B01J20/00; B01J20/02; B01J20/06; B01J20/08; B01D2255/00; B01D2255/20; B01D2255/202; B01D2255/2022; B01D2255/2027; B01D2255/90; B01D2255/92; B01D2255/9207; Y; Y02; Y02C; Y02C20/00; Y02C20/10
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
167 words
A method for the removal of nitrogen oxides from a gas containing them which method comprises contacting said gas at a temperature of 85° C. to about 200° C. with a sorbent, which sorbent comprises (a) an alumina component comprising alumina having a surface area of at least about 20 square meters per gram, and (b) an alkaline component comprising at least one salt of a Group IA the alkali metals or IIA the alkaline earth metals of atomic number not exceeding 56 and thereafter removing nitrogen oxides from said sorbent by a process which comprises: (c) contacting said nitrogen oxide containing sorbent in a regeneration zone where the regenerant gas stream containing at least 0.01 atmosphere partial pressure of hydrogen sulfide at a temperature of about 350 to about 750° C. for a period of time sufficient to recover a substantial portion of the sorbent's capacity for nitrogen oxide sorption; and (d) withdrawing nitrogen oxide formerly contained on said sorbent in a form of elemental nitrogen.
Claim 2
Independent Claim
167 words
A method for the removal of nitrogen oxides from a gas containing them which method comprises contacting said gas at a temperature of 85° C. to about 200° C. with a sorbent, which sorbent comprises (a) an alumina component comprising alumina having a surface area of at least about 20 square meters per gram, and (b) an alkaline component comprising at least one salt of a Group IA the alkali metals or IIA the alkaline earth metals of atomic number not exceeding 56 and thereafter removing nitrogen oxides from said sorbent by a process which comprises: (c) contacting said nitrogen oxide containing sorbent in a regeneration zone where the regenerant gas stream containing at least 0.01 atmosphere partial pressure of hydrogen sulfide at a temperature of about 350 to about 750° C. for a period of time sufficient to recover a substantial portion of the sorbent's capacity for nitrogen oxide sorption; and (d) withdrawing nitrogen oxide formerly contained on said sorbent in a form of elemental nitrogen.
Claim 3
Dependent Claim
21 words
Method as claimed in claim 1, wherein the said surface area of component (a) is at least 100 m 2 /gm.
Claim 4
Dependent Claim
31 words
Method as claimed in claim 1, wherein said contacting is effected with the sorbent in a fixed bed and wherein the contacting time is from about 0.1 to about 10 seconds.
Claim 5
Dependent Claim
18 words
Method as claimed in claim 1, wherein said contacting is effected with the sorbent in a fluid bed.
Claim 6
Dependent Claim
34 words
Method as claimed in claim 1, wherein the weight ratio of alkali or alkaline earth metal atoms in said component (a) to the alumina atoms in said component (b) is from 5:95 to 60:40.
Claim 7
Dependent Claim
14 words
Method as claimed in claim 5, wherein said ratio is from 10:90 to 40:60.
Claim 8
Dependent Claim
25 words
Method as claimed in claim 1, wherein said alumina of said component (a) has a surface area of at least 200 square meters per gram.
Claim 9
Dependent Claim
21 words
Method as claimed in claim 7, wherein said surface area is from about 400 to about 500 square meters per gram.
Claim 10
Dependent Claim
31 words
Method as claimed in claim 1, wherein said salt, of component (b), is an oxide, hydroxide, carbonate, nitrate, acetate, or aluminate, or mixtures thereof, of said Group IA or IIA metal.
Claim 11
Dependent Claim
26 words
Method as claimed in claim 1, wherein the salt of component (b) is incorporated into said sorbent, as a carbonate, nitrate or acetate, or mixtures thereof.
Claim 12
Dependent Claim
33 words
Method as claimed in claim 1, wherein said Group IA or IIA metals are selected from the group consisting of lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium, and barium, or mixtures thereof.
Claim 13
Dependent Claim
15 words
Method as claimed in claim 1, wherein said Group IA metal is sodium or potassium.
Claim 14
Dependent Claim
22 words
Method as claimed in claim 1, in which the sorbent is in the form of a co-precipitate of components (a) and (b).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-16 | 1987-07-18 | 1988-01-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-16 | 1991-07-18 | 1992-01-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-16 | 1995-07-18 | 1996-01-17 | $7700.00 | Window Closed / Lapsed |