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US4425207A Expired / Lapsed US ⏱️ 0.0 years remaining

Dual cure coating compositions

Assignee: UCB SA
•
Filing: 1983-01-17
•
Granted: 1984-01-10
•
Expires: 2003-01-17
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Abstract

Abstract Dual cure coating compositions are prepared by one of the following techniques: aminoplast crosslinking with residual hydroxy present on extended acrylated or UV cure polymers; oxidative crosslinking of backbone drying oil unsaturation following UV cure; or by employing UV chain extension via reaction of pendent allylic group with polymercaptans followed by a melamine heat cure. The coatings are cured by UV exposure followed by heating or air drying.

Inventors

  • 👤 Rudolph H. Boeckeler
  • 👤 James R. Prom

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 21:56
CPC Classifications
C; C09; C09D; C09D161/00; C09D161/20

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 55 words
A coating composition comprising: an epoxy modified polyester extended acrylate resin containing plural beta hydroxy alkyl acrylate groups and drying oil unsaturation; and a photopolymerization initiator for said resin, said initiator being selected from those initiators which decompose upon exposure to U.V. radiation to generate an acid catalyst for the cross-linking reaction of said resin.
Claim 2
Dependent Claim 55 words
A coating composition comprising: an epoxy modified polyester extended acrylate resin containing plural beta hydroxy alkyl acrylate groups and drying oil unsaturation; and a photopolymerization initiator for said resin, said initiator being selected from those initiators which decompose upon exposure to U.V. radiation to generate an acid catalyst for the cross-linking reaction of said resin.
Claim 3
Dependent Claim 19 words
The composition set forth in claim 1 wherein said extender comprises the reaction product of linseed oil fatty acid.
Claim 4
Dependent Claim 32 words
A method for curing the coating composition of claim 1 comprising exposing the composition to ultraviolet radiation and air curing the composition to permit oxidative crosslinking of the backbone drying oil unsaturation.
Claim 5
Dependent Claim 32 words
A method for curing the coating composition of claim 2 comprising exposing the composition to ultraviolet radiation and air curing the composition to permit oxidative crosslinking of the backbone drying oil unsaturation.
Claim 6
Dependent Claim 60 words
A coating composition comprising: a first resin containing pendent allyl groups; a polymercaptan reactive with said allylic groups of said first resin; a polymerization initiator for said reaction between said first resin and said polymerization; an aminoplast resin; and an acid catalyst for the reaction of said aminoplast resin and the reaction product of said polymerization and said first resin.
Claim 7
Dependent Claim 60 words
A coating composition comprising: a first resin containing pendent allyl groups; a polymercaptan reactive with said allylic groups of said first resin; a polymerization initiator for said reaction between said first resin and said polymerization; an aminoplast resin; and an acid catalyst for the reaction of said aminoplast resin and the reaction product of said polymerization and said first resin.
Claim 8
Dependent Claim 23 words
The composition set forth in claim 5 wherein said catalyst consists at least in part of the decomposition product of said polymerization initiator.
Claim 9
Dependent Claim 32 words
A method of curing the composition of claim 5 comprising exposing the composition to ultraviolet radiation and subsequently heating the composition to react the aminoplast resin with the ultraviolet radiation cured material.
Claim 10
Dependent Claim 32 words
A method of curing the composition of claim 6 comprising exposing the composition to ultraviolet radiation and subsequently heating the composition to react the aminoplast resin with the ultraviolet radiation cured material.

References Cited (Backward Citations)

US3882007A Cited
US4154896A Cited
US4377457A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-01-09 1987-07-11 1988-01-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-01-09 1991-07-11 1992-01-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-01-09 1995-07-11 1996-01-10 $7700.00 Window Closed / Lapsed

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