US4424336A
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Meat-curable mixture, which are stable on storage, of epoxide resin, 3-aminocrotonic acid derivatives and maleimide compound
Assignee: Novartis Corp
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Filing: 1982-09-16
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Granted: 1984-01-03
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Expires: 2002-09-16
Abstract
Abstract Heat-curable mixtures of one or more epoxide compounds, which, on average, have more than one epoxide group in the molecule, and one or more β-aminocrotonic acid derivatives, such as β-aminocrotononitrile, β-aminocrotonamide or β-aminocrotonic acid esters, and also, if desired, a polyamine or polycarboxylic acid anhydride or a malenimide. The novel curable mixtures are distinguished by outstanding stability on storage, can be processed easily and give moulded materials with good mechanical properties.
Inventors
- 👤 Theobald Haug
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 03:03
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/50; C08G59/52; C08G59/4007; C08G59/4014; C08G59/54
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
203 words
A heat-curable mixture which is stable on storage, which contains (a) an epoxide compound with, on average, more than one epoxide group in the molecule, (b) a β-amino-crotonic acid derivative of the formulae I to X ##STR37## in which R 1 and R 2 independently of one another are each a hydrogen atom, alkyl having 1 to 6 C atoms, cycloalkyl having 5 or 6 C atoms or aryl having 6 to 10 C atoms, Y is a n-valent organic radical having 2 to 30 C atoms, R is an aromatic or aliphatic radical having not more than 30 C atoms, E, together with the two N atoms, is a heterocyclic, five-membered or six-membered ring and n is a number from 1 to 3, and (c) a maleimide of the formula XIII ##STR38## in which A is a x-valent organic radical having 2 to 30 C atoms, Z is vinylene or methylvinylene and x is a number from 1 to 3; the curable mixture containing 2 to 8 epoxide equivalents per 1 equivalent of β-aminocrotonic acid derivative, containing the grouping ##STR39## and a maximum of 70% of imide group equivalents, based on the sum of equivalents of β-aminocrotonic acid derivative and imide group.
Claim 2
Dependent Claim
203 words
A heat-curable mixture which is stable on storage, which contains (a) an epoxide compound with, on average, more than one epoxide group in the molecule, (b) a β-amino-crotonic acid derivative of the formulae I to X ##STR37## in which R 1 and R 2 independently of one another are each a hydrogen atom, alkyl having 1 to 6 C atoms, cycloalkyl having 5 or 6 C atoms or aryl having 6 to 10 C atoms, Y is a n-valent organic radical having 2 to 30 C atoms, R is an aromatic or aliphatic radical having not more than 30 C atoms, E, together with the two N atoms, is a heterocyclic, five-membered or six-membered ring and n is a number from 1 to 3, and (c) a maleimide of the formula XIII ##STR38## in which A is a x-valent organic radical having 2 to 30 C atoms, Z is vinylene or methylvinylene and x is a number from 1 to 3; the curable mixture containing 2 to 8 epoxide equivalents per 1 equivalent of β-aminocrotonic acid derivative, containing the grouping ##STR39## and a maximum of 70% of imide group equivalents, based on the sum of equivalents of β-aminocrotonic acid derivative and imide group.
Claim 3
Dependent Claim
103 words
A mixture according to claim 1, which contains a glycidyl ether or a N-glycidyl compound as the epoxide compound and a β-aminocrotonic acid derivative of the formula I, III, IV, V, VI, VII, VIII, IX or X, in which R 1 is a hydrogen atom and R 2 is an alkyl having 1 to 6 C atoms, Y is alkylene having 2 to 10 C atoms, m- or p-phenylene or a divalent radical of the formulae ##STR40## R is an aliphatic radical having not more than 10 C atoms, the grouping ##STR41## is the radical of the formula ##STR42## and n is 2.
Claim 4
Dependent Claim
48 words
A mixture according to claim 1, which contains a diglycidyl ether of dihydric phenols as the epoxide compound and a β-aminocrotonic acid derivative of the formula I, IV, V or VI, in which R 1 , R 2 , Y and n are as defined in claim 2.
Claim 5
Dependent Claim
41 words
A mixture according to claim 1, which contains a diglycidyl ether of dihydric phenols as the epoxide compound and a β-aminocrotonic acid derivative of the formula VI in which R 1 , Y and n are as defined in claim 2.
Claim 6
Dependent Claim
12 words
The mixture according to claim 1, wherein A is an aliphatic radical.
Claim 7
Dependent Claim
24 words
The mixture according to claim 1, wherein A is a radical of the formulae. ##STR43## Z is vinylene and x is 2 or 3.
References Cited (Backward Citations)
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