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US4424272A Expired / Lapsed US ⏱️ 0.0 years remaining

Temporary polymeric mordants and elements containing same

Assignee: Polaroid Corp
•
Filing: 1981-08-03
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Granted: 1984-01-03
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Expires: 2001-08-03
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Abstract

Abstract Polymeric mordants which are capable of converting to non-mordanting species in an alkaline environment are described. The mordants can be used in photographic elements to temporarily mordant a photographically useful dye material, such as a light-filter or anti-halation dye or a diffusion transfer image dye-providing material, and then release the dye material during processing of the element with an alkaline processing composition.

Inventors

  • 👤 Lloyd D. Taylor

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:35
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/42; G03C8/52; G03C8/56; G03C1/00; G03C1/76; G03C1/825; G03C1/835; Y; Y10; Y10S; Y10S430/00; Y10S430/142; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31935

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 91 words
A sheet-like element comprising a support carrying a mordant layer comprising a polymeric mordant of the formula ##STR24## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion.
Claim 2
Dependent Claim 91 words
A sheet-like element comprising a support carrying a mordant layer comprising a polymeric mordant of the formula ##STR24## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion.
Claim 3
Dependent Claim 18 words
An element of claim 1 further comprising an organic dye capable of being mordanted by said polymeric mordant.
Claim 4
Dependent Claim 15 words
An element of claim 2 wherein said organic dye is contained in said mordant layer.
Claim 5
Dependent Claim 37 words
An element of claim 2 wherein said organic dye is contained in a separate layer associated with said mordant layer such that said organic dye, in an alkaline environment, is able to migrate into said mordant layer.
Claim 6
Dependent Claim 80 words
An element of claim 1 wherein said polymer comprises recurring units of the formula ##STR25## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; X - is an anion; and alkylene is a straight or branched alkylene group.
Claim 7
Dependent Claim 16 words
An element of claim 5 wherein said alkylene group comprises from 1 to 8 carbon atoms.
Claim 8
Dependent Claim 120 words
An element of claim 1 wherein said polymer comprises recurring units of the formula ##STR26## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; X - is an anion; alkylene is a straight or branched alkylene group; and each of R 4 and R 5 is independently hydrogen, lower alkyl, substituted lower alkyl, alkaryl, aralkyl, cycloalkyl, or R 4 and R 5 together with the carbon atom to which they are bonded constitute a carbocyclic or heterocyclic ring.
Claim 9
Dependent Claim 16 words
An element of claim 7 wherein said alkylene group comprises from 1 to 8 carbon atoms.
Claim 10
Dependent Claim 111 words
A photosensitive element comprising a support carrying a photosensitive silver halide emulsion layer; a mordant layer comprising a polymeric mordant comprising recurring units of the formula ##STR27## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion; and an organic dye capable of being mordanted by said polymer.
Claim 11
Dependent Claim 111 words
A photosensitive element comprising a support carrying a photosensitive silver halide emulsion layer; a mordant layer comprising a polymeric mordant comprising recurring units of the formula ##STR27## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion; and an organic dye capable of being mordanted by said polymer.
Claim 12
Dependent Claim 15 words
An element of claim 9 wherein said organic dye is contained in said mordant layer.
Claim 13
Dependent Claim 28 words
An element of claim 10 wherein said organic dye is an anti-halation dye and said mordant layer is positioned between said support and said silver halide emulsion layer.
Claim 14
Dependent Claim 36 words
An element of claim 10 wherein said support is transparent, said organic dye is an anti-halation dye, and said mordant layer is positioned on that side of said transparent support opposite said silver halide emulsion layer.
Claim 15
Dependent Claim 21 words
An element of claim 10 wherein said organic dye is a light-filter dye and said mordant layer is an overcoat layer.
Claim 16
Dependent Claim 43 words
An element of claim 10 wherein said organic dye is a light-filter dye and said mordant layer is positioned between two silver halide emulsion layers of said element, each of said silver halide emulsions being sensitive to different regions of the visible spectrum.
Claim 17
Dependent Claim 130 words
A photosensitive element adapted for use in photographic color diffusion transfer processes comprising a support carrying a silver halide emulsion having associated therewith a diffusion transfer process image dye-providing material and a mordant layer comprising a polymeric mordant comprising recurring units of the formula ##STR28## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion; said image dye-providing material being capable of being mordanted by said polymer.
Claim 18
Dependent Claim 130 words
A photosensitive element adapted for use in photographic color diffusion transfer processes comprising a support carrying a silver halide emulsion having associated therewith a diffusion transfer process image dye-providing material and a mordant layer comprising a polymeric mordant comprising recurring units of the formula ##STR28## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion; said image dye-providing material being capable of being mordanted by said polymer.
Claim 19
Dependent Claim 31 words
An element of claim 15 wherein said silver halide emulsion is contained in a layer associated with said mordant layer and said image dye-providing material is contained in said mordant layer.
Claim 20
Dependent Claim 27 words
An element of claim 15 wherein said mordant layer is positioned between a layer containing said silver halide emulsion and a layer containing said image dye-providing material.
Claim 21
Dependent Claim 14 words
An element of claim 15 wherein said image dye-providing material is a dye developer.
Claim 22
Dependent Claim 13 words
An element of claim 15 wherein said mordant layer is an overcoat layer.

References Cited (Backward Citations)

US3425833A Cited
US3425834A Cited
US3438779A Cited
US3444138A Cited
US3455693A Cited
US3575993A Cited
US4229515A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-01-02 1987-07-04 1988-01-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-01-02 1991-07-04 1992-01-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-01-02 1995-07-04 1996-01-03 $7700.00 Window Closed / Lapsed

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