US4424272A
Expired / Lapsed
US
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Temporary polymeric mordants and elements containing same
Assignee: Polaroid Corp
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Filing: 1981-08-03
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Granted: 1984-01-03
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Expires: 2001-08-03
Abstract
Abstract Polymeric mordants which are capable of converting to non-mordanting species in an alkaline environment are described. The mordants can be used in photographic elements to temporarily mordant a photographically useful dye material, such as a light-filter or anti-halation dye or a diffusion transfer image dye-providing material, and then release the dye material during processing of the element with an alkaline processing composition.
Inventors
- 👤 Lloyd D. Taylor
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 03:35
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/42; G03C8/52; G03C8/56; G03C1/00; G03C1/76; G03C1/825; G03C1/835; Y; Y10; Y10S; Y10S430/00; Y10S430/142; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31935
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
91 words
A sheet-like element comprising a support carrying a mordant layer comprising a polymeric mordant of the formula ##STR24## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion.
Claim 2
Dependent Claim
91 words
A sheet-like element comprising a support carrying a mordant layer comprising a polymeric mordant of the formula ##STR24## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion.
Claim 3
Dependent Claim
18 words
An element of claim 1 further comprising an organic dye capable of being mordanted by said polymeric mordant.
Claim 4
Dependent Claim
15 words
An element of claim 2 wherein said organic dye is contained in said mordant layer.
Claim 5
Dependent Claim
37 words
An element of claim 2 wherein said organic dye is contained in a separate layer associated with said mordant layer such that said organic dye, in an alkaline environment, is able to migrate into said mordant layer.
Claim 6
Dependent Claim
80 words
An element of claim 1 wherein said polymer comprises recurring units of the formula ##STR25## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; X - is an anion; and alkylene is a straight or branched alkylene group.
Claim 7
Dependent Claim
16 words
An element of claim 5 wherein said alkylene group comprises from 1 to 8 carbon atoms.
Claim 8
Dependent Claim
120 words
An element of claim 1 wherein said polymer comprises recurring units of the formula ##STR26## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; X - is an anion; alkylene is a straight or branched alkylene group; and each of R 4 and R 5 is independently hydrogen, lower alkyl, substituted lower alkyl, alkaryl, aralkyl, cycloalkyl, or R 4 and R 5 together with the carbon atom to which they are bonded constitute a carbocyclic or heterocyclic ring.
Claim 9
Dependent Claim
16 words
An element of claim 7 wherein said alkylene group comprises from 1 to 8 carbon atoms.
Claim 10
Dependent Claim
111 words
A photosensitive element comprising a support carrying a photosensitive silver halide emulsion layer; a mordant layer comprising a polymeric mordant comprising recurring units of the formula ##STR27## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion; and an organic dye capable of being mordanted by said polymer.
Claim 11
Dependent Claim
111 words
A photosensitive element comprising a support carrying a photosensitive silver halide emulsion layer; a mordant layer comprising a polymeric mordant comprising recurring units of the formula ##STR27## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion; and an organic dye capable of being mordanted by said polymer.
Claim 12
Dependent Claim
15 words
An element of claim 9 wherein said organic dye is contained in said mordant layer.
Claim 13
Dependent Claim
28 words
An element of claim 10 wherein said organic dye is an anti-halation dye and said mordant layer is positioned between said support and said silver halide emulsion layer.
Claim 14
Dependent Claim
36 words
An element of claim 10 wherein said support is transparent, said organic dye is an anti-halation dye, and said mordant layer is positioned on that side of said transparent support opposite said silver halide emulsion layer.
Claim 15
Dependent Claim
21 words
An element of claim 10 wherein said organic dye is a light-filter dye and said mordant layer is an overcoat layer.
Claim 16
Dependent Claim
43 words
An element of claim 10 wherein said organic dye is a light-filter dye and said mordant layer is positioned between two silver halide emulsion layers of said element, each of said silver halide emulsions being sensitive to different regions of the visible spectrum.
Claim 17
Dependent Claim
130 words
A photosensitive element adapted for use in photographic color diffusion transfer processes comprising a support carrying a silver halide emulsion having associated therewith a diffusion transfer process image dye-providing material and a mordant layer comprising a polymeric mordant comprising recurring units of the formula ##STR28## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion; said image dye-providing material being capable of being mordanted by said polymer.
Claim 18
Dependent Claim
130 words
A photosensitive element adapted for use in photographic color diffusion transfer processes comprising a support carrying a silver halide emulsion having associated therewith a diffusion transfer process image dye-providing material and a mordant layer comprising a polymeric mordant comprising recurring units of the formula ##STR28## wherein R is hydrogen or lower alkyl; each of R 1 and R 2 is independently lower alkyl, cycloalkyl, substituted lower alkyl, aralkyl, or R 1 and R 2 taken together represent the atoms necessary to complete a saturated N-containing ring; L is a divalent linking group; A represents the atoms necessary to complete an arylene nucleus; R 3 is lower alkyl, aryl, aralkyl, alkoxy, or aryloxy; and X - is an anion; said image dye-providing material being capable of being mordanted by said polymer.
Claim 19
Dependent Claim
31 words
An element of claim 15 wherein said silver halide emulsion is contained in a layer associated with said mordant layer and said image dye-providing material is contained in said mordant layer.
Claim 20
Dependent Claim
27 words
An element of claim 15 wherein said mordant layer is positioned between a layer containing said silver halide emulsion and a layer containing said image dye-providing material.
Claim 21
Dependent Claim
14 words
An element of claim 15 wherein said image dye-providing material is a dye developer.
Claim 22
Dependent Claim
13 words
An element of claim 15 wherein said mordant layer is an overcoat layer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-02 | 1987-07-04 | 1988-01-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-02 | 1991-07-04 | 1992-01-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-02 | 1995-07-04 | 1996-01-03 | $7700.00 | Window Closed / Lapsed |