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US4423349A Expired / Lapsed US ⏱️ 0.0 years remaining

Green fluorescence-emitting material and a fluorescent lamp provided therewith

Assignee: Nichia Denshi Kagaku Co Ltd
•
Filing: 1981-07-01
•
Granted: 1983-12-27
•
Expires: 2001-07-01
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Abstract

Abstract A green light-emitting fluorescent material prepared from terbium-activated lanthanum cerium orthophosphate expressed by the structural formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9 and a fluorescent lamp comprising said green light-emitting fluorescent material used alone or in combination with any other form of fluorescent material.

Inventors

  • 👤 Shigeharu Nakajima
  • 👤 Keiji Ichinomiya
  • 👤 Koichi Okada
  • 👤 Kaname Tsuchikura
  • 👤 Minoru Kashiwagi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 08:55
CPC Classifications
H; H01; H01J; H01J61/00; H01J61/02; H01J61/38; H01J61/42; H01J61/44; C; C09; C09K; C09K11/00; C09K11/08; C09K11/77; C09K11/7766; C09K11/7777

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 27 words
A green light-emitting fluorescent material prepared from terbium activated lanthanum cerium orthophosphate and expressed by formula (I): La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9.
Claim 2
Dependent Claim 27 words
A green light-emitting fluorescent material prepared from terbium activated lanthanum cerium orthophosphate and expressed by formula (I): La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9.
Claim 3
Dependent Claim 36 words
The green light-emitting fluorescent material according to claim 1, wherein the term z given in formula (I) is 0.62 to 0.80; the term y is 0.08 to 0.20; and the term x is 0.12 to 0.30.
Claim 4
Dependent Claim 21 words
The green light-emitting fluorescent material according to claim 1 or 2, which comprises at least one of yttrium, gadolinium and lutecium.
Claim 5
Dependent Claim 79 words
A 3-wavelength type fluorescent lamp which is provided with 16 to 28% of a blue light-emitting fluorescent material 35 to 49% of a green light-emitting fluorescent material 26 to 38% of a red light-emitting fluorescent material wherein said fluorescent lamp is chosen to have a color temperature around 5000° K., and in which the green light-emitting fluorescent material is prepared from terbium-activated lanthanum cerium orthophosphate expressed by the formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9.
Claim 6
Dependent Claim 79 words
A 3-wavelength type fluorescent lamp which is provided with 16 to 28% of a blue light-emitting fluorescent material 35 to 49% of a green light-emitting fluorescent material 26 to 38% of a red light-emitting fluorescent material wherein said fluorescent lamp is chosen to have a color temperature around 5000° K., and in which the green light-emitting fluorescent material is prepared from terbium-activated lanthanum cerium orthophosphate expressed by the formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9.
Claim 7
Dependent Claim 34 words
The fluorescent lamp according to claim 4, wherein the term z given in formula (I) is 0.62 to 0.80; the term y is 0.08 to 0.20; and the term x is 0.12 to 0.30.
Claim 8
Dependent Claim 24 words
The fluorescent lamp according to claim 4 or 5, wherein the green light-emitting fluorescent material contains at least one of yttrium, gadolinium and lutecium.
Claim 9
Dependent Claim 43 words
The fluorescent lamp according to claim 4 or 5, which is further provided with less than 70 parts by weight of the calcium halophosphate fluorescent material based on the total 100 parts by weight of the blue, green and red lights-emitting fluorescent materials.
Claim 10
Dependent Claim 39 words
A fluorescent lamp used with an electronic copying machine, whose inside is coated with a green light-emitting fluorescent material prepared from terbium-activated lanthanum cerium orthophosphate expressed by the formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9.
Claim 11
Dependent Claim 39 words
A fluorescent lamp used with an electronic copying machine, whose inside is coated with a green light-emitting fluorescent material prepared from terbium-activated lanthanum cerium orthophosphate expressed by the formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9.
Claim 12
Dependent Claim 33 words
A green light-emitting fluorescent material of the formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where x+y+z=1 and where z is 0.62 to 0.80, y is 0.08 to 0.20, and x is 0.12 to 0.30.
Claim 13
Dependent Claim 33 words
A green light-emitting fluorescent material of the formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where x+y+z=1 and where z is 0.62 to 0.80, y is 0.08 to 0.20, and x is 0.12 to 0.30.
Claim 14
Dependent Claim 22 words
The fluorescent lamp according to claim 8 or 9, which is further provided with at least one of yttrium, gadolinium and lutecium.
Claim 15
Dependent Claim 60 words
A mercury vapor discharge lamp, which comprises a single or a plurality of bright membranes prepared from a plurality of fluorescent materials, whose color temperature ranges from 2800° to 7000° K., and wherein a green light-emitting fluorescent material is prepared from terbium activated lanthanum cerium orthophosphate expressed by the formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9.
Claim 16
Dependent Claim 60 words
A mercury vapor discharge lamp, which comprises a single or a plurality of bright membranes prepared from a plurality of fluorescent materials, whose color temperature ranges from 2800° to 7000° K., and wherein a green light-emitting fluorescent material is prepared from terbium activated lanthanum cerium orthophosphate expressed by the formula: La.sub.x Tb.sub.y Ce.sub.z PO.sub.4 (I) where: x+y+z=1 0.05<x<0.35 0.05<y<0.3 0.6<z<0.9.

References Cited (Backward Citations)

US4208611A Cited
US4215289A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-26 1987-06-27 1987-12-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-26 1991-06-27 1991-12-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-26 1995-06-27 1995-12-27 $7700.00 Window Closed / Lapsed

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