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US4423135A Expired / Lapsed US ⏱️ 0.0 years remaining

Preparation of photosensitive block copolymer elements

Assignee: EIDP Inc
•
Filing: 1982-08-16
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Granted: 1983-12-27
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Expires: 2002-08-16
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Abstract

Abstract Photosensitive elements comprising a layer of a solvent-soluble, thermoplastic, elastomeric, block copolymer, a nongaseous ethylenically unsaturated compound, and an addition polymerization initiator activatable by actinic light interposed between a support and cover sheet, a flexible polymeric film, e.g., polyamide, being interposed between the cover sheet and the surface of the layer. The elements are useful in preparing printing plates, particularly flexographic printing plates, and other relief images.

Inventors

  • 👤 Gwendyline Y. Y. T. Chen
  • 👤 James F. Brennan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 00:59
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; G03F7/033; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 172 words
A process for forming a solvent-soluble, photosensitive elastomeric element comprising applying to a sheet support a layer of a photosensitive, elastomeric composition to a dry thickness of from about 0.005 to about 0.25 inch, said composition comprising (1) at least 30% by weight of at least one solvent-soluble, thermoplastic, elastomeric block copolymer containing at least two thermoplastic, nonelastomeric polymer blocks having a glass transition temperature above 25° C. and an average molecular weight of 2000-100,000, and between said thermoplastic, nonelastomeric polymer blocks an elastomeric polymer block having a glass transition temperature below 10° C. and an average molecular weight of about 25,000 to 1,000,000, (2) at least 1% by weight of an addition-polymerizable ethylenically unsaturated compound containing at least one terminal ethylenical group, and (3) a polymerization-effective amount of polymerization initiator activatable by actinic radiation; laminating onto said layer a combination of (a) a strippable flexible cover sheet having coated thereon (b) a solvent-soluble, flexible, polymeric film, so that the surface of said film is contiguous to the surface of said layer.
Claim 2
Dependent Claim 172 words
A process for forming a solvent-soluble, photosensitive elastomeric element comprising applying to a sheet support a layer of a photosensitive, elastomeric composition to a dry thickness of from about 0.005 to about 0.25 inch, said composition comprising (1) at least 30% by weight of at least one solvent-soluble, thermoplastic, elastomeric block copolymer containing at least two thermoplastic, nonelastomeric polymer blocks having a glass transition temperature above 25° C. and an average molecular weight of 2000-100,000, and between said thermoplastic, nonelastomeric polymer blocks an elastomeric polymer block having a glass transition temperature below 10° C. and an average molecular weight of about 25,000 to 1,000,000, (2) at least 1% by weight of an addition-polymerizable ethylenically unsaturated compound containing at least one terminal ethylenical group, and (3) a polymerization-effective amount of polymerization initiator activatable by actinic radiation; laminating onto said layer a combination of (a) a strippable flexible cover sheet having coated thereon (b) a solvent-soluble, flexible, polymeric film, so that the surface of said film is contiguous to the surface of said layer.
Claim 3
Dependent Claim 23 words
A process according to claim 1 wherein the photosensitive, elastomeric composition is applied to the sheet support by extruding at an elevated temperature.
Claim 4
Dependent Claim 19 words
A process according to claim 1 wherein the photosensitive, elastomeric composition is applied to the sheet support by calendering.
Claim 5
Dependent Claim 16 words
A process according to claim 3 wherein the photosensitive, elastomeric composition is calendered between two sheets.

References Cited (Backward Citations)

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US3024180A Cited
US3060026A Cited
US3144331A Cited
US3241973A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-12-26 1987-06-27 1987-12-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-12-26 1991-06-27 1991-12-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-12-26 1995-06-27 1995-12-27 $7700.00 Window Closed / Lapsed

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