US4416937A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymer blends and laminates and adhesive films prepared therefrom
Assignee: Dow Chemical Co
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Filing: 1983-03-08
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Granted: 1983-11-22
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Expires: 2003-03-08
Abstract
Abstract Polymer blends are provided which are characterized by good processability on conventional extrusion equipment to provide films having excellent adhesion to various substrates while still exhibiting good non-blocking properties during film manufacture, storage, shipment and use. Such blends comprise, based upon the total blend weight, from 5 to about 90 weight percent of a high melt index adhesive resin; from about 5 to about 90 weight percent of a relatively low melt index adhesive resin; and from about 5 to about 70 weight percent of non-adhesive resin having a melt index of from about 3 to about 10.
Inventors
- 👤 Bruce A. Metzger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 08:25
CPC Classifications
C; C09; C09J; C09J123/00; C09J123/02; C09J123/04; B; B32; B32B; B32B27/00; B32B27/04; C09J7/00; C09J7/10; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/04; Y; Y10; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249953; Y10T428/249982; Y10T428/249985; Y10T442/00; Y10T442/60; Y10T442/647
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
220 words
A consolidated laminar structure comprising at least two dissimilar laminar layers, at least one of said layers being composed essentially of a polymer blend composition comprising, based upon the total weight of said composition, (a) from about 5 to 90 weight percent of a first adhesive resin having a melt index of from about 50 to about 70 and comprising a random copolymer of a major proportion by weight of ethylene and from about 15 to about 25 weight percent, based upon said copolymer, of an ethylenically unsaturated carboxylic acid; (b) from about 5 to about 90 weight percent of a normally solid second adhesive resin having a melt index of from about 3 to about 15 and comprising a random copolymer of a major proportion by weight of ethylene with a minor proportion by weight of an ethylenically unsaturated carboxylic acid, a vinyl ester of an alkanoic acid or a lower alkyl or hydroxyalkyl ester of an ethylenically unsaturated carboxylic acid monomer; and (c) from about 5 to about 70 weight percent of a normally solid non-adhesive resin having a melt index of from about 3 to about 10 and comprising a homopolymer of ethylene or a copolymer of a major proportion by weight of ethylene and a minor proportion by weight of a C 4 -C 12 α-olefin.
Claim 2
Dependent Claim
220 words
A consolidated laminar structure comprising at least two dissimilar laminar layers, at least one of said layers being composed essentially of a polymer blend composition comprising, based upon the total weight of said composition, (a) from about 5 to 90 weight percent of a first adhesive resin having a melt index of from about 50 to about 70 and comprising a random copolymer of a major proportion by weight of ethylene and from about 15 to about 25 weight percent, based upon said copolymer, of an ethylenically unsaturated carboxylic acid; (b) from about 5 to about 90 weight percent of a normally solid second adhesive resin having a melt index of from about 3 to about 15 and comprising a random copolymer of a major proportion by weight of ethylene with a minor proportion by weight of an ethylenically unsaturated carboxylic acid, a vinyl ester of an alkanoic acid or a lower alkyl or hydroxyalkyl ester of an ethylenically unsaturated carboxylic acid monomer; and (c) from about 5 to about 70 weight percent of a normally solid non-adhesive resin having a melt index of from about 3 to about 10 and comprising a homopolymer of ethylene or a copolymer of a major proportion by weight of ethylene and a minor proportion by weight of a C 4 -C 12 α-olefin.
Claim 3
Dependent Claim
193 words
A consolidated laminar structure comprising at least two dissimilar layers in which at least one of said layers is composed essentially of a polymer blend composition comprising, based upon the total weight of said composition, (a) from about 5 to 90 weight percent of a first adhesive resin having a melt index of from about 50 to about 700 and comprising a random copolymer of a major proportion by weight of ethylene and a minor proportion by weight of an ethylenically unsaturated carboxylic acid; (b) from about 5 to about 90 weight percent of a normally solid second adhesive resin having a melt index of from about 3 to about 15 and comprising a random copolymer of a major proportion by weight of ethylene with a minor proportion by weight of an ethylenically unsaturated carboxylic acid; and (c) from about 5 to about 70 weight percent of a normally solid non-adhesive resin having a melt index of from about 3 to about 10 and comprising a homopolymer of ethylene or a copolymer of a major proportion by weight of ethylene and a minor proportion by weight of a C 4 -C 12 α-olefin.
Claim 4
Dependent Claim
193 words
A consolidated laminar structure comprising at least two dissimilar layers in which at least one of said layers is composed essentially of a polymer blend composition comprising, based upon the total weight of said composition, (a) from about 5 to 90 weight percent of a first adhesive resin having a melt index of from about 50 to about 700 and comprising a random copolymer of a major proportion by weight of ethylene and a minor proportion by weight of an ethylenically unsaturated carboxylic acid; (b) from about 5 to about 90 weight percent of a normally solid second adhesive resin having a melt index of from about 3 to about 15 and comprising a random copolymer of a major proportion by weight of ethylene with a minor proportion by weight of an ethylenically unsaturated carboxylic acid; and (c) from about 5 to about 70 weight percent of a normally solid non-adhesive resin having a melt index of from about 3 to about 10 and comprising a homopolymer of ethylene or a copolymer of a major proportion by weight of ethylene and a minor proportion by weight of a C 4 -C 12 α-olefin.
Claim 5
Dependent Claim
31 words
The consolidated laminar structure of claim 1 or 2 wherein one of the laminar layers is a synthetic polymer foam and one of the laminar layers is a non-woven fabric material.
Claim 6
Dependent Claim
19 words
The consolidated laminar structure of claim 1 or 2 in the form of a multiple layered thermoplastic polymer film.
Claim 7
Dependent Claim
30 words
The consolidated laminar structure of claim 1 or 2 wherein at least a portion of the carboxylic acid groups of the first adhesive resin are in neutralized metallic salt form.
Claim 8
Dependent Claim
18 words
The consolidated laminar structure of claim 1 or 2 wherein the second adhesive resin is an ionomer resin.
Claim 9
Dependent Claim
25 words
The consolidated laminar structure of claim 1 or 2 wherein the first adhesive resin has a melt index of from about 200 to about 400.
Claim 10
Dependent Claim
27 words
The consolidated laminar structure of claim 1 or 2 wherein the first adhesive resin constitutes from about 15 to about 75 weight percent of the polymer blend.
Claim 11
Dependent Claim
27 words
The consolidated laminar structure of claim 1 or 2 wherein the first adhesive resin constitutes from about 20 to about 60 weight percent of the polymer blend.
Claim 12
Dependent Claim
25 words
The consolidated laminar structure of claim 9 wherein the second adhesive resin constitutes from about 10 to about 70 weight percent of the polymer blend.
Claim 13
Dependent Claim
23 words
The consolidated laminar structure of claim 10 wherein the non-adhesive resin constitutes from about 10 to about 60 weight percent of said blend.
Claim 14
Dependent Claim
44 words
The consolidated laminar structure of claim 1 or 2 wherein the second adhesive resin is a random ethylene copolymer having from about 2 to about 12 weight percent, based upon the weight of said copolymer, of an ethylenically unsaturated carboxylic acid monomer copolymerized therein.
Claim 15
Dependent Claim
38 words
The consolidated laminar structure of claim 12 wherein the non-adhesive resin is a low density polyethylene having a density of from about 0.910 to about 0.930 and a melting point of from about 100° to about 120° C.
Claim 16
Dependent Claim
31 words
The consolidated laminar structure of claim 2 wherein the first adhesive resin comprises, in polymerized form, from about 15 to about 25 weight percent of the ethylenically unsaturated carboxylic acid monomer.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-11-21 | 1987-05-23 | 1987-11-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-11-21 | 1991-05-23 | 1991-11-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-11-21 | 1995-05-23 | 1995-11-22 | $7700.00 | Window Closed / Lapsed |