Abstract A method for synthesizing amorphous silicon nitride, wherein silicon halide and ammonia are reacted in a reaction vessel at a high temperature in the absence of oxygen to thereby synthesize powder of amorphous silicon nitride, then the powder is separated from a gas containing therein gaseous ammonia halide which has been produced simultaneously with said amorphous silicon nitride by use of a collecting means, comprises directly mixing, in advance of the separation, cool gas containing therein neither oxygen nor moisture into said gas to cool down said powder and gas so that both substances may be put in said collecting means without deposition of ammonium halide to the inner wall of the reaction vessel, and other component parts.
A two stage method for synthesizing amorphous silicon nitride, comprising reacting in the first stage silicon halide and ammonia in a reaction vessel for about 0.1 to 3 seconds at a temperature range of about 400° C. to 1600° C. in a molar ratio of ammonia to silicon halide of about 0.1 to 5 in the absence of oxygen to produce amorphous silicon nitride, and then separating in the second stage silicon nitride with ammonia halide which was produced in the first stage simultaneously with said amorphous silicon nitride, using a separating device wherein cool gas at a temperature of 150° C. or below containing therein neither oxygen nor moisture is introduced resulting in the collection of solid amorphous silicon nitride and condensed ammonium chloride without adhering into the separating device and other component parts thereof in any substantial amount.
Claim 2
Dependent Claim
140 words
A two stage method for synthesizing amorphous silicon nitride, comprising reacting in the first stage silicon halide and ammonia in a reaction vessel for about 0.1 to 3 seconds at a temperature range of about 400° C. to 1600° C. in a molar ratio of ammonia to silicon halide of about 0.1 to 5 in the absence of oxygen to produce amorphous silicon nitride, and then separating in the second stage silicon nitride with ammonia halide which was produced in the first stage simultaneously with said amorphous silicon nitride, using a separating device wherein cool gas at a temperature of 150° C. or below containing therein neither oxygen nor moisture is introduced resulting in the collection of solid amorphous silicon nitride and condensed ammonium chloride without adhering into the separating device and other component parts thereof in any substantial amount.
Claim 3
Dependent Claim
20 words
The method as set forth in claim 1, wherein said cool gas is further cooled by a heat-exchanger for recycling.