US4413052A
Expired / Lapsed
US
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Photopolymerization process employing compounds containing acryloyl group and anthryl group
Assignee: Novartis Corp
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Filing: 1982-03-25
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Granted: 1983-11-01
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Expires: 2002-03-25
Abstract
Abstract In a three stage process, a layer of a liquid composition containing a compound (A) having in the same molecule both at least one (meth)acryloyl group and at least one anthryl group is exposed to actinic radiation so that the layer solidifies due to photopolymerization of (A) through the (meth)acryloyl group(s), remaining, however, further photocrosslinkable. When desired, the solidified layer is exposed, as through a negative, to a substantially greater amount of actinic radiation, the parts so further exposed becoming more highly photocrosslinked through the anthryl group(s) and hence insoluble. An image is produced which can be developed by means of suitable solvents. Examples of (A) include 3-(acryloyloxy)-2-hydroxypropyl anthracene-9-carboxylate and its methacryloyl homologue.
Inventors
- 👤 George E. Green
- 👤 Ewald Losert
- 👤 John G. Paul
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 14:25
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/20; G03F7/2022
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
182 words
A process for production of an image which comprises (1) exposing to actinic radiation a layer, supported on a carrier, of a liquid composition containing a photoinitiator and a compound (A) having in the same molecule both at least one group of formula ##STR32## and at least one group of formula ##STR33## where R denotes a hydrogen atom or a methyl group, R 1 denotes a chlorine or bromine atom, a methyl group, or a nitro group, and m is zero, 1, or 2, such that the layer solidifies and becomes essentially nontacky due to photopolymerisation of (A) through the group or groups of formula III but remains substantially photocrosslinkable, and subsequently, (2) exposing the layer so solidified through an image-bearing transparency consisting of substantially opaque and substantially transparent parts to a substantially greater amount of actinic radiation such that the further exposed part or parts of the photopolymerised layer undergo photocrosslinking through the group or groups of formula IV, and (3) developing the image by dissolving in a solvent the part or parts of the layer which have not become photocrosslinked.
Claim 2
Dependent Claim
182 words
A process for production of an image which comprises (1) exposing to actinic radiation a layer, supported on a carrier, of a liquid composition containing a photoinitiator and a compound (A) having in the same molecule both at least one group of formula ##STR32## and at least one group of formula ##STR33## where R denotes a hydrogen atom or a methyl group, R 1 denotes a chlorine or bromine atom, a methyl group, or a nitro group, and m is zero, 1, or 2, such that the layer solidifies and becomes essentially nontacky due to photopolymerisation of (A) through the group or groups of formula III but remains substantially photocrosslinkable, and subsequently, (2) exposing the layer so solidified through an image-bearing transparency consisting of substantially opaque and substantially transparent parts to a substantially greater amount of actinic radiation such that the further exposed part or parts of the photopolymerised layer undergo photocrosslinking through the group or groups of formula IV, and (3) developing the image by dissolving in a solvent the part or parts of the layer which have not become photocrosslinked.
Claim 3
Dependent Claim
19 words
The process of claim 1 in which (A) contains, per average molecule, up to four groups of formula III.
Claim 4
Dependent Claim
19 words
The process of claim 1 in which (A) contains, per average molecule, up to four groups of formula IV.
Claim 5
Dependent Claim
23 words
The process of claim 1 in which a group of formula III is directly attached to an atom of carbon, oxygen, or nitrogen.
Claim 6
Dependent Claim
23 words
The process of claim 1 in which a group of formula IV is directly attached to an atom of carbon, oxygen, or nitrogen.
Claim 7
Dependent Claim
89 words
The process of claim 1 in which (A) is of the formula ##STR34## where a and b are each independently an integer of at least 1, R 3 denotes a group of formula --COO--, --O--, --R 2 O--, --NH--, or --SO 3 --, where R 2 represents an alkylene or alkylidene group of 1 to 4 carbon atoms, and R 4 denotes the residue, after removal of (a+b) glycidyl groups directly attached to atoms of oxygen, nitrogen, or sulfur, of a compound containing at least (a+b) such glycidyl groups.
Claim 8
Dependent Claim
14 words
The process of claim 1 in which (A) is of the formula ##STR35## where
Claim 9
Dependent Claim
23 words
a and b are each independently an integer of at least 1, R 5 denotes a group of formula --COO-- or --NHCOO--, and
Claim 10
Dependent Claim
23 words
a and b are each independently an integer of at least 1, R 5 denotes a group of formula --COO-- or --NHCOO--, and
Claim 11
Dependent Claim
22 words
R 6 denotes the residue, after removal of (a+b) alcoholic hydroxyl groups, of a compound containing at least (a+b) such hydroxyl groups.
Claim 12
Dependent Claim
22 words
R 6 denotes the residue, after removal of (a+b) alcoholic hydroxyl groups, of a compound containing at least (a+b) such hydroxyl groups.
Claim 13
Dependent Claim
39 words
The process of claim 1 in which (A) is an esteracetal containing in the molecule at least one group of formula ##STR36## and at least one group of the formula ##STR37## where p denotes zero, 1, 2, or 3.
Claim 14
Dependent Claim
56 words
The process of claim 1 in which (A) is an amide of formula ##STR38## or a urea-amide of formula ##STR39## where a and b are each independently an integer of at least 1, and R 7 denotes the residue, after removal of (a+b) primary amino groups, of a compound containing at least (a+b) such amino groups.
Claim 15
Dependent Claim
14 words
The process of claim 1 in which (A) is of the general formula ##STR40##
Claim 16
Dependent Claim
29 words
The process of claim 1 in which (A) is of the general formula ##STR41## where R 2 represents an alkylene or alkylidene group of 1 to 4 carbon atoms.
Claim 17
Dependent Claim
15 words
The process of claim 1 in which (A) is an ester of the formula ##STR42##
Claim 18
Dependent Claim
21 words
The process of claim 1 in which at least one group of formula IV is a 1-anthryl, 2-anthryl, or 9-anthryl group.
Claim 19
Dependent Claim
16 words
The process of claim 1 in which (A) is 3-(acryloyloxy)-2-hydroxypropyl anthracene-9-carboxylate, 3-(methacryloyloxy)-2-hydroxypropyl anthracene-9-carboxylate, or 9-anthrylmethyl acrylate.
Claim 20
Dependent Claim
55 words
The process of claim 1 in which the composition further contains a photopolymerisable compound (B) having in the same molecule at least one group of formula III but none of formula IV and also at least one free sulfonic, phosphonic, or carboxylic acid group, and the solvent employed is an aqueous solution of a base.
Claim 21
Dependent Claim
53 words
The process of claim 1 in which the composition further contains a photopolymerisable compound (B) having in the molecule at least one group of formula III but none of formula IV and also at least one primary, secondary, or tertiary amino group, and the solvent employed is an aqueous solution of an acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-31 | 1987-05-02 | 1987-11-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-31 | 1991-05-02 | 1991-11-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-31 | 1995-05-02 | 1995-11-01 | $7700.00 | Window Closed / Lapsed |