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US4412943A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid detergent composition

Assignee: Kao Corp
•
Filing: 1982-02-10
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Granted: 1983-11-01
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Expires: 2002-02-10
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Abstract

Abstract A liquid detergent composition comprises: (A) 5-25 wt. % of an ammonium alkyl sulfate of the formula (1): R.sub.1 OSO.sub.3 NH.sub.4 (1) wherein R 1 is a straight-chain or branched, saturated hydrocarbon group having 8-18 carbon atoms on the average, (B) 0.05-5 wt. % of an alkylenediaminecarboxylic acid derivative of the formula (2): ##STR1## wherein R 2 is an alkylene group having 2-3 carbon atoms, A, B, C and D may be the same or different and each is ##STR2## or hydrogen, R 3 is C n H 2n (n being 1 or 2), or ##STR3## and Y is hydrogen or a cation, with the proviso that the number of hydrogen atoms contained in A, B, C and D is at most 2, and (C) 0.1 to 5 wt. % of a carboxylic acid, a salt of the carboxylic acid, an amino acid or a salt of the amino acid.

Inventors

  • 👤 Hajime Hirota
  • 👤 Hiroshi Watanabe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:38
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/40; A61K8/44; A61K8/46; A61K8/463; A61Q; A61Q5/00; A61Q5/02; C; C11; C11D; C11D1/00; C11D1/02; C11D1/12; C11D1/14; C11D1/146; C11D3/00; C11D3/16; C11D3/20; C11D3/2075; C11D3/26; C11D3/33

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 288 words
A liquid detergent composition which consists essentially of: (A) from 5 to 25 wt. % of an ammonium alkyl sulfate having the formula R.sub.1 OSO.sub.3 NH.sub.4 wherein R 1 is alkyl having from 8 to 18 carbon atoms on the average, (B) from 0.05 to 5 wt. % of one or a mixture of two or more alkylenediaminecarboxylic acid derivatives having the formula ##STR7## wherein R 2 is alkylene having 2 or 3 carbon atoms; A, B, C and D, which are the same or different, each is ##STR8## or hydrogen, in which R 3 is --C n H 2n -- or ##STR9## n is 1 or 2 and Y is hydrogen or a cation, with the proviso that from 0 to 2 of the groups, A, B, C and D are hydrogen and the remainder are ##STR10## (C) from 0.1 to 5 wt. % of one or a mixture of two or more compounds selected from the group consisting of carboxylic acids selected from the group consisting of lower fatty acids having from 1 to 8 carbon atoms, dicarboxylic acids having the formula HOOC--CH 2 -- n COOH wherein n is an integer of from 0 to 5, glycolic acid, lactic acid, hydroacrylic acid, α-hydroxybutyric acid, β-hydroxybutyric acid, glyceric acid, tartronic acid, malic acid, tartaric acid, citric acid, maleic acid, fumaric acid, mesaconic acid and citraconic acid, and amino acids selected from the group consisting of glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophane, sarcosine, β-alanine, γ-aminobutyric acid, ε-aminocaproic acid, glutamic acid, aspartic acid, cysteic acid, homocysteic acid, lysine, ornithine, arginine, serine, homoserine, tyrosine, threonine, proline, hydroxyproline, cystine, cysteine and methionine, and salts of said carboxylic acids and said amino acids, and (D) the balance is essentially water.
Claim 2
Dependent Claim 288 words
A liquid detergent composition which consists essentially of: (A) from 5 to 25 wt. % of an ammonium alkyl sulfate having the formula R.sub.1 OSO.sub.3 NH.sub.4 wherein R 1 is alkyl having from 8 to 18 carbon atoms on the average, (B) from 0.05 to 5 wt. % of one or a mixture of two or more alkylenediaminecarboxylic acid derivatives having the formula ##STR7## wherein R 2 is alkylene having 2 or 3 carbon atoms; A, B, C and D, which are the same or different, each is ##STR8## or hydrogen, in which R 3 is --C n H 2n -- or ##STR9## n is 1 or 2 and Y is hydrogen or a cation, with the proviso that from 0 to 2 of the groups, A, B, C and D are hydrogen and the remainder are ##STR10## (C) from 0.1 to 5 wt. % of one or a mixture of two or more compounds selected from the group consisting of carboxylic acids selected from the group consisting of lower fatty acids having from 1 to 8 carbon atoms, dicarboxylic acids having the formula HOOC--CH 2 -- n COOH wherein n is an integer of from 0 to 5, glycolic acid, lactic acid, hydroacrylic acid, α-hydroxybutyric acid, β-hydroxybutyric acid, glyceric acid, tartronic acid, malic acid, tartaric acid, citric acid, maleic acid, fumaric acid, mesaconic acid and citraconic acid, and amino acids selected from the group consisting of glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophane, sarcosine, β-alanine, γ-aminobutyric acid, ε-aminocaproic acid, glutamic acid, aspartic acid, cysteic acid, homocysteic acid, lysine, ornithine, arginine, serine, homoserine, tyrosine, threonine, proline, hydroxyproline, cystine, cysteine and methionine, and salts of said carboxylic acids and said amino acids, and (D) the balance is essentially water.
Claim 3
Dependent Claim 19 words
A composition as claimed in claim 1 in which R 1 is alkyl having 10 to 14 carbon atoms.
Claim 4
Dependent Claim 30 words
A composition as claimed in claim 2 in which said alkylenediaminecarboxylic acid derivative is selected from the group consisting of ethylenediaminetetraacetate salts, ethylenediamine-N,N'-diacetate salts, ethylenediamine di(O-hydroxyphenylacetate) salts and ethylenediamine-N,N'-dipropionate salts.
Claim 5
Dependent Claim 23 words
A composition as claimed in claim 3 in which the amount of said alkylenediaminecarboxylic acid derivative is from 0.2 to 3 wt. %.
Claim 6
Dependent Claim 82 words
A liquid detergent composition as claimed in claim 1 wherein the component (C) is selected from the group consisting of lower fatty acids having from 1 to 8 carbon atoms, dicarboxylic acids having the formula HOOC--CH 2 -- n COOH wherein n is an integer of from 0 to 5, glycolic acid, lactic acid, hydroacrylic acid, α-hydroxybutyric acid, β-hydroxybutyric acid, glyceric acid, tartronic acid, malic acid, tartaric acid, citric acid, maleic acid, fumaric acid, mesaconic acid and citraconic acid, and salts thereof.
Claim 7
Dependent Claim 57 words
A liquid detergent composition as claimed in claim 1 wherein the component (C) is selected from the group consisting of glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophane, sarcosine, β-alanine, γ-aminobutyric acid, ε-aminocaproic acid, glutamic acid, aspartic acid, cysteic acid, homocysteic acid, lysine, ornithine, arginine, serine, homoserine, tyrosine, threonine, proline, hydroxyproline, cystine, cysteine and methionine, and salts thereof.
Claim 8
Dependent Claim 34 words
A composition as claimed in claim 3 in which (C) is an amino acid selected from the group consisting of glycine, alanine, valine, leucine, isoleucine, phenylalanine, tryptophane, sarcosine, β-alanine, γ-aminobutyric acid and ε-aminocaproic acid.
Claim 9
Dependent Claim 22 words
A composition as claimed in claim 4, in which the amount of said amino acid is from 0.2 to 3 wt. %.
Claim 10
Dependent Claim 51 words
A composition as claimed in claim 3 wherein component (C) is selected from the group consisting of malonic acid, succinic acid, lactic acid, tartaric acid, citric acid, alkali metal salts of said acids, alkaline earth metal salts of said acids, ammonium salts of said acids and alkanolamine salts of said acids.

References Cited (Backward Citations)

US3859337A Cited
US3893955A Cited
US4003857A Cited
US4092273A Cited
US4321156A Cited
US4259204A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-31 1987-05-02 1987-11-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-31 1991-05-02 1991-11-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-31 1995-05-02 1995-11-01 $7700.00 Window Closed / Lapsed

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