US4411884A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Cosmetic agents based on polycationic polymers, and their use in cosmetic compositions
Assignee: L'Oréal SA
•
Filing: 1980-12-17
•
Granted: 1983-10-25
•
Expires: 2000-12-17
Abstract
Abstract A hair shaping cosmetic composition contains in an aqueous, alcoholic or hydoalcoholic carrier a quaternized polymer.
Inventors
- 👤 Bernard Jacquet
- 👤 Gerard Lang
- 👤 Alain Malaval
- 👤 Serge Forestier
- 👤 Do Le Trung
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 03:59
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/84; A61Q; A61Q5/00; A61Q5/02; A61Q5/04; A61Q5/06; A61Q5/08; A61Q5/10; A61K2800/00; A61K2800/40; A61K2800/54; A61K2800/542; A61K2800/5426
Claims Analysis
Total Claims: 43
Claim 1
Independent Claim
455 words
A hair-shaping cosmetic composition comprising a solution in an aqueous, alcoholic or hydroalcoholic carrier of a hair-shaping amount of a quaternized polymer containing units of the formula ##STR34## wherein R 1 , R 2 , R 3 and R 4 each independently represent a hydrocarbon group, or at least one of the pairs R 1 , R 2 and R 3 , R 4 represent together with the nitrogen atom to which it is attached a heterocycle optionally containing an oxygen or sulfur heteroatom; A 1 and A 2 , each independently, represent linear or branched alkylene or arylene, substituted or not, containing up to 20 carbon atoms; X represents a bivalent group of the formula ##STR35## wherein y is equal to 0 or 1, R 5 , R 6 , R 7 , R 8 , R 9 and R 10 represent hydrogen or lower alkyl, X 1 represents alkylene, alkylene including an --S--S-- group, alkenylene, arylene, diaminoalkylene, diaminoarylene, dioxyyalkylene, dioxyarylene or polyoxyalkylene, or X 1 represents a direct covalent bond, X 2 represents diaminoalkylene, dioxylkylene or polyoxyalkylene bivalent group, X 2 ' represents dithioalkylene, X 3 represents alkylene, cycloalkylene, arylene, diaminoalkylene, diaminocycloalkylene or diaminoarylene, A 3 represents --B 1 --Y--B 2 --, wherein B 1 and B 2 represent alkylene or arylene and Y has the same meaning as X above, or Y represents ##STR36## or A 3 represents linear or branched alkylene, substituted by one or more ═O groups, or linear or branched alkylene interrupted by at least one heteroatom selected from oxygen, sulfur or nitrogen, or arylene, or A 3 represents ##STR37## wherein B 3 and B 4 represent arylene and Y 1 represents linear or branched alkylene, or linear or branched alkylene substituted by at least one --OH or ═O group, or Y 1 represents a heteroatom selected from oxygen, sulfur or nitrogen, or A 3 represents (a) --E--O--D) z' O--E-- or (b) --E--O--G--O--E--, wherein z' is a number ranging from 2 to 600, E represents alkylene having 1-4 carbon atoms or --CH 2 --CHOH--CH 2 --, D represents a bivalent hydrocarbon group containing 1-5 carbon atoms, and G represents alkylene, cycloalkylene, arylene or aralkylene, or when X is other than --CO--X 2 --CO--, A 3 represents linear or branched alkylene or hydroxyalkylene, alkenylene or hydroxyalkenylene, cycloalkylene, or cycloalkenylene, containing up to 20 carbon atoms; and z.sup.⊖ represents a halide anion; with the proviso that when X represents --NH--CO--NH, A 3 represents --E--(O--D) z --O--E-- or --B 1 --Y--B 2 , wherein Y has the meaning given for X above except for the value --NH--CO--NH, or A 3 represents --E--O--G--O--E-- wherein E and G have the meanings given above with the proviso that E and G are not simultaneously alkylene.
Claim 2
Dependent Claim
455 words
A hair-shaping cosmetic composition comprising a solution in an aqueous, alcoholic or hydroalcoholic carrier of a hair-shaping amount of a quaternized polymer containing units of the formula ##STR34## wherein R 1 , R 2 , R 3 and R 4 each independently represent a hydrocarbon group, or at least one of the pairs R 1 , R 2 and R 3 , R 4 represent together with the nitrogen atom to which it is attached a heterocycle optionally containing an oxygen or sulfur heteroatom; A 1 and A 2 , each independently, represent linear or branched alkylene or arylene, substituted or not, containing up to 20 carbon atoms; X represents a bivalent group of the formula ##STR35## wherein y is equal to 0 or 1, R 5 , R 6 , R 7 , R 8 , R 9 and R 10 represent hydrogen or lower alkyl, X 1 represents alkylene, alkylene including an --S--S-- group, alkenylene, arylene, diaminoalkylene, diaminoarylene, dioxyyalkylene, dioxyarylene or polyoxyalkylene, or X 1 represents a direct covalent bond, X 2 represents diaminoalkylene, dioxylkylene or polyoxyalkylene bivalent group, X 2 ' represents dithioalkylene, X 3 represents alkylene, cycloalkylene, arylene, diaminoalkylene, diaminocycloalkylene or diaminoarylene, A 3 represents --B 1 --Y--B 2 --, wherein B 1 and B 2 represent alkylene or arylene and Y has the same meaning as X above, or Y represents ##STR36## or A 3 represents linear or branched alkylene, substituted by one or more ═O groups, or linear or branched alkylene interrupted by at least one heteroatom selected from oxygen, sulfur or nitrogen, or arylene, or A 3 represents ##STR37## wherein B 3 and B 4 represent arylene and Y 1 represents linear or branched alkylene, or linear or branched alkylene substituted by at least one --OH or ═O group, or Y 1 represents a heteroatom selected from oxygen, sulfur or nitrogen, or A 3 represents (a) --E--O--D) z' O--E-- or (b) --E--O--G--O--E--, wherein z' is a number ranging from 2 to 600, E represents alkylene having 1-4 carbon atoms or --CH 2 --CHOH--CH 2 --, D represents a bivalent hydrocarbon group containing 1-5 carbon atoms, and G represents alkylene, cycloalkylene, arylene or aralkylene, or when X is other than --CO--X 2 --CO--, A 3 represents linear or branched alkylene or hydroxyalkylene, alkenylene or hydroxyalkenylene, cycloalkylene, or cycloalkenylene, containing up to 20 carbon atoms; and z.sup.⊖ represents a halide anion; with the proviso that when X represents --NH--CO--NH, A 3 represents --E--(O--D) z --O--E-- or --B 1 --Y--B 2 , wherein Y has the meaning given for X above except for the value --NH--CO--NH, or A 3 represents --E--O--G--O--E-- wherein E and G have the meanings given above with the proviso that E and G are not simultaneously alkylene.
Claim 3
Dependent Claim
39 words
The hair-shaping cosmetic composition of claim 1 which also includes a reducing agent so as to open the S--S bonds of the hair keratin, said composition constituting a reducing composition for the first stage of a permanent wave operation.
Claim 4
Dependent Claim
39 words
The hair-shaping cosmetic composition of claim 1 which also includes an oxidizing agent so as to reconstitute reduced S--S bonds of the hair keratin, said composition constituting an oxidizing composition for the second stage of a permanent wave operation.
Claim 5
Dependent Claim
23 words
The hair-shaping cosmetic composition of claim 1 which also includes an effective amount of a cosmetic resin, said composition constituting a hair-setting lotion.
Claim 6
Dependent Claim
29 words
The hair-shaping cosmetic composition of claim 4 wherein said carrier is an alcohol or a hydroalcoholic solution and which also includes a propellant, said composition constituting a hair lacquer.
Claim 7
Dependent Claim
18 words
The hair-shaping cosmetic composition of claim 1 which also includes an effective amount of a hair restructuring agent.
Claim 8
Dependent Claim
57 words
The hair-shaping cosmetic composition of claim 1 wherein when A 3 represents linear or branched alkylene, optionally substituted by one or more --OH or ═O groups and interrupted by at least one heteroatom group, said heteroatom group is selected from --O--, --S--, --SO 2 --, --S--S--, or ##STR38## wherein R 11 is alkyl, aryl, cycloalkyl or aralkyl.
Claim 9
Dependent Claim
59 words
The hair-shaping cosmetic composition of claim 1 wherein A 3 is --CH 2 --C 6 H 4 --CH 2 --, --CH 2 --C 6 H 4 --C 6 H 4 --CH 2 , --CH 2 --C 6 H 4 --O--C 6 H 4 --CH 2 -- or --CH 2 --O--G--O--CH 2 -- wherein G is defined in claim 1.
Claim 10
Dependent Claim
76 words
The hair-shaping cosmetic composition of claim 1 wherein when A 3 represents --B 3 --Y 1 --B 4 --, A 3 represents --C 6 H 4 --SO 2 --C 6 H 4 --, --C 6 H 4 --CH 2 --C 6 H 4 --, --C 6 H 4 --C(CH 3 ) 2 --C 6 H 4 --, --C 6 H 4 --CO--C 6 H 4 --, or --C 6 H 4 --CHOH--C 6 H 4 --.
Claim 11
Dependent Claim
39 words
The hair-shaping cosmetic composition of claim 1 wherein when wherein D represents --E--O--D) z O--E--, A 3 represents --(CH 2 ) 2 --, --CH 2 --CH(CH 3 )-- or --(CH 2 ) 4 -- and z' ranges from 2-18.
Claim 12
Dependent Claim
17 words
The hair-shaping cosmetic composition of claim 1 wherein Z.sup.⊖ represents a halide, sulfate, acetate or paratoluenesufonate anion.
Claim 13
Dependent Claim
25 words
The hair-shaping cosmetic composition of claim 1 wherein R 1 , R 2 , R 3 and R 4 represent alkyl having 1-8 carbon atoms.
Claim 14
Dependent Claim
22 words
The hair-shaping cosmetic composition of claim 1 wherein X represents ##STR39## wherein R 9 and R 10 are defined in claim 1.
Claim 15
Dependent Claim
16 words
The hair-shaping cosmetic composition of claim 1 wherein X represents --NH--SO 2 --NH--, --CO--NH-- or --NH--CO--alkylene--S--S--alkylene--CO--NH--.
Claim 16
Dependent Claim
25 words
The hair-shaping cosmetic composition of claim 1 wherein X represents --O--CO--NH--X 3 '--NH--CO--O-- wherein X 3 ' represents linear or branched alkylene, cycloalkylene or arylene.
Claim 17
Dependent Claim
11 words
The hair-shaping cosmetic composition of claim 1 wherein X represents --CO--NH--alkylene--NH--CO--.
Claim 18
Dependent Claim
11 words
The hair-shaping cosmetic composition of claim 1 wherein X represents --NH--CO--NH--.
Claim 19
Dependent Claim
19 words
The hair-shaping cosmetic composition of claim 1 wherein said quaternized polymer has a molecular weight between 1,000 and 50,000.
Claim 20
Dependent Claim
26 words
The hair-shaping cosmetic composition of claim 1 wherein said quaternized polymer is present in an amount between 0.1 and 10 percent by weight of said composition.
Claim 21
Dependent Claim
26 words
The hair-shaping cosmetic composition of claim 19 wherein said quaternized polymer is present in an amount between 0.25 and 5 percent by weight of said composition.
Claim 22
Dependent Claim
46 words
The hair-shaping cosmetic composition of claim 1 wherein the carrier is water or a hydroalcoholic solution, said quaternized polymer being present in an amount ranging from 0.1 to 10 percent by weight of said composition and said composition having a pH ranging from 5 to 8.
Claim 23
Dependent Claim
18 words
The hair-shaping cosmetic composition of claim 19 which also includes a soap or fatty alcohol and an emulsifier.
Claim 24
Dependent Claim
12 words
The hair-shaping cosmetic composition of claim 22 which also includes a thickener.
Claim 25
Dependent Claim
67 words
The hair-shaping cosmetic composition of claim 1 which also includes an effective amount of a reducing agent for the S--S bonds of hair keratin and where in said quaternized polymer R 1 ═R 2 ═R 3 ═R 4 ═methyl, A 1 ═A 2 ═(CH 2 ) 3 , X=--NH--CO--CO--NH--, A 3 =--CH 2 CH 2 --O--CH 2 CH 2 --OCH 2 --CH 2 -- and Z.sup.⊖ =Cl.sup.⊖.
Claim 26
Dependent Claim
14 words
The hair-shaping cosmetic composition of claim 24 wherein said reducing agent is thioglycolic acid.
Claim 27
Dependent Claim
23 words
A process for shaping the hair comprising applying thereto an effective amount of the composition of claim 1 and thereafter shaping the hair.
Claim 28
Dependent Claim
73 words
A process for shaping the hair comprising applying thereto an effective amount of the composition of claim 2, permitting said composition to remain in contact with the hair for a period of about 5 to 20 minutes so as to reduce the S--S bonds of the hair keratin, rinsing the hair and thereafter applying to the hair an oxidizing composition in an amount effective to reform the S--S bonds of the hair keratin.
Claim 29
Dependent Claim
106 words
A hair-shaping cosmetic composition comprising a solution in an aqueous, alcoholic or hydroalcoholic carrier of 0.01 to 15 percent by weight of a quaternized polymer containing units of the formula ##STR40## wherein R 1 , R 2 , R 3 and R 4 each independently represent CH 3 , C 2 H 5 , C 4 H 9 or C 8 H 17 , A 1 and A 2 each independently represent ##STR41## A 3 represents ##STR42## Z.sup.⊖ represents Cl or Br, with the proviso that when X represents --NH--CO--NH--, A 3 represents ##STR43## said quaternized polymer having a molecular weight ranging from 1,000 to 50,000.
Claim 30
Dependent Claim
106 words
A hair-shaping cosmetic composition comprising a solution in an aqueous, alcoholic or hydroalcoholic carrier of 0.01 to 15 percent by weight of a quaternized polymer containing units of the formula ##STR40## wherein R 1 , R 2 , R 3 and R 4 each independently represent CH 3 , C 2 H 5 , C 4 H 9 or C 8 H 17 , A 1 and A 2 each independently represent ##STR41## A 3 represents ##STR42## Z.sup.⊖ represents Cl or Br, with the proviso that when X represents --NH--CO--NH--, A 3 represents ##STR43## said quaternized polymer having a molecular weight ranging from 1,000 to 50,000.
Claim 31
Dependent Claim
43 words
The hair-shaping cosmetic composition of claim 28 wherein said quaternized polymer is in an aqueous or hydroalcoholic solution and is present in an amount ranging from 0.1 to 10 percent by weight thereof, said composition having a pH ranging from 5 to 8.
Claim 32
Dependent Claim
45 words
The hair-shaping cosmetic composition of claim 28 which also includes from 3 to 50 weight percent of at least one of a cationic, nonionic, anionic or amphoteric detergent and said quaternized polymer is present in an amount ranging from 0.1 to 5 weight percent thereof.
Claim 33
Dependent Claim
63 words
The hair-shaping cosmetic composition of claim 28 which also includes from 0.1 to 5 weight percent of a cosmetic resin selected from polyvinylpyrrolidone, copolymer of polyvinylpyrrolidone and vinyl acetate or copolymer of crotonic acid and vinyl acetate, said quaternized polymer being present in an amount ranging from 0.1 to 5 weight percent and said composition having a pH ranging from 4.5 to 7.5.
Claim 34
Dependent Claim
84 words
The hair-shaping cosmetic composition of claim 28 wherein said quaternized polymer is in an alcoholic or hydroalcoholic solution, said composition also containing a cosmetic resin selected from polyvinylpyrrolidone, copolymer of polyvinylpyrrolidone and vinyl acetate or copolymer of crotonic acid and vinylacetate, said cosmetic resin being prresent in an amount ranging from 0.5 to 5 weight percent and said quaternized polymer being present in an amount ranging from 0.1 to 5 weight percent, said composition being packaged in an aerosol container together with a propellant.
Claim 35
Dependent Claim
52 words
The hair-shaping cosmetic composition of claim 28 which also includes a methylol derivative, as a hair restructuring agent, present in an amount ranging from 0.1 to 10 percent by weight of said composition, said quaternized polymer being present in an amount ranging from 0.25 to 5 percent by weight of said composition.
Claim 36
Dependent Claim
55 words
The hair-shaping cosmetic composition of claim 28 for use in the first stage of a permanent wave operation to open the S-S bonds of the hair keratin which includes a mercaptan, as a reducing agent, present in an amount sufficient to reduce said S-S bonds, said composition having a pH ranging from 7 to 10.
Claim 37
Dependent Claim
16 words
The hair-shaping cosmetic composition of claim 28 wherein said reducing agent is thioglycerol or thioglycolic acid.
Claim 38
Dependent Claim
33 words
The hair-shaping cosmetic composition of claim 35 wherein said reducing agent is thioglycolic acid present in an amount ranging from 1 to 11 percent by weight based on the weight of said composition.
Claim 39
Dependent Claim
64 words
The hair-shaping cosmetic composition of claim 28 for use in the second stage of a permanent wave operation to reconstitute reduced S-S bonds of the hair keratin which includes, as an oxidant, hydrogen peroxide or a persalt present in an amount sufficient to reconstitute said reduced S-S bonds, and said polymer is present in an amount ranging from 0.1 to 10 percent by weight.
Claim 40
Dependent Claim
434 words
A hair-shaping cosmetic composition comprising a solution in an aqueous, alcoholic or hydroalcoholic carrier of a hair-shaping amount of a quaternized polymer containing units of the formula ##STR44## wherein R 1 , R 2 , R 3 and R 4 each independently represent a hydrocarbon group, or at least one of the pairs R 1 , R 2 and R 3 , R 4 represents together with the nitrogen atom to which it is attached a heterocycle optionally containing an oxygen or sulfur heteroatom; A 1 and A 2 , each independently, represent linear or branched alkylene or arylene, substituted or not, containing up to 20 carbon atoms; X represents a bivalent group of the formula ##STR45## wherein y is equal to 0 or 1, R 5 , R 6 , R 7 , R 8 , R 9 and R 10 represent hydrogen or lower alkyl, X 1 represents alkylene, alkylene including an --S--S-- group, alkenylene, arylene, diaminoalkylene, diaminoarylene, dioxyalkylene, dioxyarylene or polyoxyalkylene, or X 1 represents a direct covalent bond, X 2 represents diaminoalkylene, dioxyalkylene or polyoxyalkylene bivalent group, X' 2 represents dithioalkylene, X 3 represents alkylene, cycloalkylene, arylene, diaminoalkylene, diaminocycloalkylene or diaminoarylene, A 3 represents --B 1 --Y--B 2 --, wherein B 1 and B 2 represent alkylene or arylene and Y has the same meaning as X above, or Y represents ##STR46## or A 3 represents linear or branched alkylene, substituted by one or more ═O groups, or linear or branched alkylene interrupted by at least one heteroatom selected from oxygen, sulfur or nitrogen, or arylene, or A 3 represents --B 3 --Y 1 --B 4 wherein B 3 and B 4 represent arylene and Y 1 represents linear or branched alkylene, or linear or branched alkylene substituted by at least one --OH or ═O group, or Y 1 represents a heteroatom selected from oxygen, sulfur or nitrogen, or A 3 represents (a) --E--O--D) z' O--E-- or (b) --E--O--G--O--E--, wherein z' is a number ranging from 2 to 600, E represents alkylene having 1-4 carbon atoms or --CH 2 --CHOH--CH 2 --, D represents a bivalent hydrocarbon group containing 1-5 carbon atoms, and G represents alkylene, cycloalkylene, arylene or aralkylene, or when X is other than --CO--X 2 --CO--, A 3 represents linear or branched alkylene or hydroxyalkylene, alkenylene or hydroxyalkenylene, cycloalkylene, or cycloalkenylene, containing up to 20 carbon atoms; and Z.sup.⊖ represents a halide anion; with the proviso that when X represents --NH--CO--NH--, A 3 represents --E--(O--D) z' --O--E-- or --B 1 --Y--B 2 , wherein Y has the meaning given for X above except for the value --NH--CO--NH--.
Claim 41
Dependent Claim
434 words
A hair-shaping cosmetic composition comprising a solution in an aqueous, alcoholic or hydroalcoholic carrier of a hair-shaping amount of a quaternized polymer containing units of the formula ##STR44## wherein R 1 , R 2 , R 3 and R 4 each independently represent a hydrocarbon group, or at least one of the pairs R 1 , R 2 and R 3 , R 4 represents together with the nitrogen atom to which it is attached a heterocycle optionally containing an oxygen or sulfur heteroatom; A 1 and A 2 , each independently, represent linear or branched alkylene or arylene, substituted or not, containing up to 20 carbon atoms; X represents a bivalent group of the formula ##STR45## wherein y is equal to 0 or 1, R 5 , R 6 , R 7 , R 8 , R 9 and R 10 represent hydrogen or lower alkyl, X 1 represents alkylene, alkylene including an --S--S-- group, alkenylene, arylene, diaminoalkylene, diaminoarylene, dioxyalkylene, dioxyarylene or polyoxyalkylene, or X 1 represents a direct covalent bond, X 2 represents diaminoalkylene, dioxyalkylene or polyoxyalkylene bivalent group, X' 2 represents dithioalkylene, X 3 represents alkylene, cycloalkylene, arylene, diaminoalkylene, diaminocycloalkylene or diaminoarylene, A 3 represents --B 1 --Y--B 2 --, wherein B 1 and B 2 represent alkylene or arylene and Y has the same meaning as X above, or Y represents ##STR46## or A 3 represents linear or branched alkylene, substituted by one or more ═O groups, or linear or branched alkylene interrupted by at least one heteroatom selected from oxygen, sulfur or nitrogen, or arylene, or A 3 represents --B 3 --Y 1 --B 4 wherein B 3 and B 4 represent arylene and Y 1 represents linear or branched alkylene, or linear or branched alkylene substituted by at least one --OH or ═O group, or Y 1 represents a heteroatom selected from oxygen, sulfur or nitrogen, or A 3 represents (a) --E--O--D) z' O--E-- or (b) --E--O--G--O--E--, wherein z' is a number ranging from 2 to 600, E represents alkylene having 1-4 carbon atoms or --CH 2 --CHOH--CH 2 --, D represents a bivalent hydrocarbon group containing 1-5 carbon atoms, and G represents alkylene, cycloalkylene, arylene or aralkylene, or when X is other than --CO--X 2 --CO--, A 3 represents linear or branched alkylene or hydroxyalkylene, alkenylene or hydroxyalkenylene, cycloalkylene, or cycloalkenylene, containing up to 20 carbon atoms; and Z.sup.⊖ represents a halide anion; with the proviso that when X represents --NH--CO--NH--, A 3 represents --E--(O--D) z' --O--E-- or --B 1 --Y--B 2 , wherein Y has the meaning given for X above except for the value --NH--CO--NH--.
Claim 42
Dependent Claim
429 words
A hair-shaping cosmetic composition comprising a solution in an aqueous, alcoholic or hydroalcoholic carrier of a hair-shaping amount of a quaternized polymer containing units of the formula ##STR47## wherein R 1 , R 2 , R 3 and R 4 each independently represent a hydrocarbon group, or at least one of the pairs R 1 , R 2 and R 3 , R 4 represents together with the nitrogen atom to which it is attached a heterocycle optionally containing an oxygen or sulfur heteroatom; A 1 and A 2 , each independently, represent linear or branched alkylene or arylene, substituted or not, containing up to 20 carbon atoms; X represents a bivalent group of the formula ##STR48## wherein y is equal to 0 or 1, R 5 , R 6 , R 7 , R 8 , R 9 and R 10 represent hydrogen or lower alkyl, X 1 represents alkylene, alkylene including an --S--S-- group, alkenylene, arylene, diaminoalkylene, diaminoarylene, dioxyalkylene, dioxyarylene or polyoxyalkylene, or X 1 represent a direct covalent bond, X 2 represents diaminoalkylene, dioxyalkylene or polyoxyalkylene bivalent group, X' 2 represents dithioalkylene, X 3 represents alkylene, cycloalkylene, arylene, diaminoalkylene, diaminocycloalkylene or diaminoarylene, A 3 represents --B 1 --Y--B 2 --, wherein B 1 and B 2 represent alkylene or arylene and Y has the same meaning as X above, or Y represents ##STR49## or A 3 represents linear or branched alkylene, substituted by one or more ═O groups, or linear or branched alkylene interrupted by at least one heteroatom selected from oxygen, sulfur or nitrogen, or arylene, or A 3 represents --B 3 --Y 1 --B 4 wherein B 3 and B 4 represent arylene and Y 1 represents linear or branched alkylene, or linear or branched alkylene substituted by at least one --OH or ═O group, or Y 1 represents a heteroatom selected from oxygen, sulfur or nitrogen, or A 3 represents (a) --E--O--D) z' O--E-- or (b) --E--O--G--O--E--, wherein z' is a number ranging from 2 to 600, E represents alkylene having 1-4 carbon atoms or --CH 2 --CHOH--CH 2 --, D represents a bivalent hydrocarbon group containing 1-5 carbon atoms, and G represents alkylene, cycloalkylene, arylene or aralkylene, or when X; is other than --CO--X 2 --CO--,A 3 represents linear or branched alkylene or hydroxyalkylene, alkenylene or hydroxyalkenylene, cycloalkylene, or cycloalkenylene, containing up to 20 carbon atoms; and Z.sup.⊖ represents a halide anion; with the proviso that when X represents --NH--CO--NH--, A 3 represents --B 1 --Y--B 2 , wherein Y has the meaning given for X above except for the value --NH--CO--NH--.
Claim 43
Dependent Claim
429 words
A hair-shaping cosmetic composition comprising a solution in an aqueous, alcoholic or hydroalcoholic carrier of a hair-shaping amount of a quaternized polymer containing units of the formula ##STR47## wherein R 1 , R 2 , R 3 and R 4 each independently represent a hydrocarbon group, or at least one of the pairs R 1 , R 2 and R 3 , R 4 represents together with the nitrogen atom to which it is attached a heterocycle optionally containing an oxygen or sulfur heteroatom; A 1 and A 2 , each independently, represent linear or branched alkylene or arylene, substituted or not, containing up to 20 carbon atoms; X represents a bivalent group of the formula ##STR48## wherein y is equal to 0 or 1, R 5 , R 6 , R 7 , R 8 , R 9 and R 10 represent hydrogen or lower alkyl, X 1 represents alkylene, alkylene including an --S--S-- group, alkenylene, arylene, diaminoalkylene, diaminoarylene, dioxyalkylene, dioxyarylene or polyoxyalkylene, or X 1 represent a direct covalent bond, X 2 represents diaminoalkylene, dioxyalkylene or polyoxyalkylene bivalent group, X' 2 represents dithioalkylene, X 3 represents alkylene, cycloalkylene, arylene, diaminoalkylene, diaminocycloalkylene or diaminoarylene, A 3 represents --B 1 --Y--B 2 --, wherein B 1 and B 2 represent alkylene or arylene and Y has the same meaning as X above, or Y represents ##STR49## or A 3 represents linear or branched alkylene, substituted by one or more ═O groups, or linear or branched alkylene interrupted by at least one heteroatom selected from oxygen, sulfur or nitrogen, or arylene, or A 3 represents --B 3 --Y 1 --B 4 wherein B 3 and B 4 represent arylene and Y 1 represents linear or branched alkylene, or linear or branched alkylene substituted by at least one --OH or ═O group, or Y 1 represents a heteroatom selected from oxygen, sulfur or nitrogen, or A 3 represents (a) --E--O--D) z' O--E-- or (b) --E--O--G--O--E--, wherein z' is a number ranging from 2 to 600, E represents alkylene having 1-4 carbon atoms or --CH 2 --CHOH--CH 2 --, D represents a bivalent hydrocarbon group containing 1-5 carbon atoms, and G represents alkylene, cycloalkylene, arylene or aralkylene, or when X; is other than --CO--X 2 --CO--,A 3 represents linear or branched alkylene or hydroxyalkylene, alkenylene or hydroxyalkenylene, cycloalkylene, or cycloalkenylene, containing up to 20 carbon atoms; and Z.sup.⊖ represents a halide anion; with the proviso that when X represents --NH--CO--NH--, A 3 represents --B 1 --Y--B 2 , wherein Y has the meaning given for X above except for the value --NH--CO--NH--.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-24 | 1987-04-25 | 1987-10-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-24 | 1991-04-25 | 1991-10-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-24 | 1995-04-25 | 1995-10-25 | $7700.00 | Window Closed / Lapsed |