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US4411775A Expired / Lapsed US ⏱️ 0.0 years remaining

Demulsification of bitumen emulsions using water soluble epoxy-containing polyethers

Assignee: Texaco Inc
•
Filing: 1981-12-02
•
Granted: 1983-10-25
•
Expires: 2001-12-02
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Abstract

Abstract A process for recovering bitumem from oil-in-water (O/W) emulsions is disclosed wherein water soluble demulsifiers are used. These demulsifiers are water soluble polyethers prepared by the reaction between certain diepoxides and poly(ethyleneoxy) glycols. To resolve the bituminous petroleum emulsions, the process is carried out between 25° and 160° C. wherein the demulsifier of the invention is contacted with the bituminous emulsion.

Inventors

  • 👤 David R. McCoy
  • 👤 Michael Cuscurida
  • 👤 George P. Speranza

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 11:23
CPC Classifications
C; C10; C10G; C10G33/00; C10G33/04; B; B01; B01D; B01D17/00; B01D17/02; B01D17/04; B01D17/047

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 73 words
A process for recovering petroleum from oil-in-water (O/W) bitumen emulsions by demulsifying said emulsions comprising contacting the emulsions at a temperature of from between about 25° and 160° C. with water soluble polyethers prepared from the acid- or base-catalyzed reaction of poly(ethyleneoxy) glycols of the structure HO(CH.sub.2 CH.sub.2 O).sub.n H where n=40 to 250 with 0.5-10 wt.% diepoxides of ≦600 molecular weight of the general structure ##STR2## wherein R' is an aromatic group.
Claim 2
Dependent Claim 73 words
A process for recovering petroleum from oil-in-water (O/W) bitumen emulsions by demulsifying said emulsions comprising contacting the emulsions at a temperature of from between about 25° and 160° C. with water soluble polyethers prepared from the acid- or base-catalyzed reaction of poly(ethyleneoxy) glycols of the structure HO(CH.sub.2 CH.sub.2 O).sub.n H where n=40 to 250 with 0.5-10 wt.% diepoxides of ≦600 molecular weight of the general structure ##STR2## wherein R' is an aromatic group.
Claim 3
Dependent Claim 12 words
A process as in claim 1 where R' also contains ether groups.
Claim 4
Dependent Claim 18 words
A process as in claim 1 or 2 wherein the diepoxide is the diglycidyl ether of Bisphenol A.
Claim 5
Dependent Claim 31 words
A process as in claim 1 wherein the reaction between the poly(ethyleneoxy) glycols and diepoxides takes place at temperatures ranging from 20° to 200° C. in the presence of a catalyst.
Claim 6
Dependent Claim 20 words
A process as in claim 4 wherein the reaction takes place at temperatures ranging from about 60° to 150° C.

References Cited (Backward Citations)

US2996551A Cited
US2792400A Cited
US2882250A Cited
US3585148A Cited
US3738945A Cited
US4281199A Cited
US4321148A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-24 1987-04-25 1987-10-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-24 1991-04-25 1991-10-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-24 1995-04-25 1995-10-25 $7700.00 Window Closed / Lapsed

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