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US4410680A Expired / Lapsed US ⏱️ 0.0 years remaining

Two-phase, heat-curable polyepoxide-unsaturated monomer compositions

Assignee: Shell USA Inc
•
Filing: 1982-11-04
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Granted: 1983-10-18
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Expires: 2002-11-04
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Abstract

Abstract A curable thermosetting resin, especially suitable for RIM applications, comprising a blend of (a) 100 parts by weight of a polyepoxide, particularly a normally liquid polyepoxide and more particularly a glycidyl polyether of a polyhydric phenol, (b) from about 10 to about 200 parts by weight of at least one ethylenically unsaturated monomer, especially an aromatic monomer, and preferably styrene, (c) a curing amount of an aliphatic or cycloaliphatic polyfunctional amine or a polyamide, and (d) an effective amount of an amine-compatible free-radical initiator.

Inventors

  • 👤 Thomas F. Brownscombe
  • 👤 William W. C. Hart

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 10:48
CPC Classifications
C; C08; C08F; C08F283/00; C08F283/10; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/50

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 59 words
A curable thermosetting resin composition comprising a blend of (1) 100 parts by weight of a epoxy compound containing at least one vicinal epoxy group in the molecule, (2) from about 10 to about 200 parts by weight of at least one ethylenically unsaturated aromatic monomer, (3) a curing amount of 4,4'-di(cyclohexylamino)methane and (4) an effective amount of 2,5-dimethyl-2,5-bis(2-ethylhexanoylperoxy)hexane.
Claim 2
Dependent Claim 59 words
A curable thermosetting resin composition comprising a blend of (1) 100 parts by weight of a epoxy compound containing at least one vicinal epoxy group in the molecule, (2) from about 10 to about 200 parts by weight of at least one ethylenically unsaturated aromatic monomer, (3) a curing amount of 4,4'-di(cyclohexylamino)methane and (4) an effective amount of 2,5-dimethyl-2,5-bis(2-ethylhexanoylperoxy)hexane.
Claim 3
Dependent Claim 17 words
The composition of claim 1 wherein the epoxy compound is a glycidyl polyether of a polyhydric phenol.
Claim 4
Dependent Claim 11 words
The composition of claim 2 wherein the polyhydric phenol is 2,2-bis(4-hydroxyphenyl)propane.
Claim 5
Dependent Claim 12 words
The composition of claim 2 wherein the polyhydric phenol is hydrogenated 2,2-bis(4-hydroxyphenyl)propane.
Claim 6
Dependent Claim 13 words
The composition of claim 1 wherein the ethylenically unsaturated aromatic monomer is styrene.
Claim 7
Dependent Claim 20 words
The composition of claim 5 wherein up to about 80% of the styrene is replaced with a compatible unsaturated comonomer.
Claim 8
Dependent Claim 10 words
The composition of claim 6 wherein the comonomer is divinylbenzene.
Claim 9
Dependent Claim 10 words
The composition of claim 6 wherein the comonomer is methylmethacrylate.
Claim 10
Dependent Claim 10 words
The composition of claim 6 wherein the comonomer is methacrylonitrile.

References Cited (Backward Citations)

US2939859A Cited
US3009898A Cited
US3099638A Cited
US3232901A Cited
US3245950A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-17 1987-04-18 1987-10-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-17 1991-04-18 1991-10-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-17 1995-04-18 1995-10-18 $7700.00 Window Closed / Lapsed

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