Inhibiting polymerization of vinyl aromatic monomers

Claim 2

A composition comprised of (a) a vinyl aromatic compound containing an amount effective to inhibit polymerization of said vinyl aromatic compound of a mixture of (1) about 10 to 90 parts by weight of at least one N,N-dialkylhydroxylamine wherein the alkyl groups are the same or different and each alkyl group has 2 to 10 carbon atoms, and (2) about 90 to 10 parts by weight of at least one tertiary-alkylcatechol having 4 to 20 carbon atoms.

Claim 3

The composition of claim 1 wherein the total concentration of said mixture of N,N-dialkylhydroxylamine and tertiary-alkylcatechol in said composition is 0.5 to 1000 ppm, based on the total weight of vinyl aromatic compound.

Claim 4

The composition of claim 1 wherein the vinyl aromatic compound is styrene or alkyl substituted styrene, each alkyl group in (1) has 2 to 6 carbon atoms, the tertiary alkyl group in (2) has 4 to 8 carbon atoms and the relative concentrations of the compounds in (1) and (2) are 25 to 75 parts by weight and 75 to 25 parts by weight respectively and the total concentration of said mixture of N,N-dialkylhydroxylamine and tertiary-alkylcatechol is said composition is 5 to 500 ppm, based on the total weight of vinyl aromatic compound.

Claim 5

The composition of claim 3 wherein the vinyl aromatic compound is styrene, the compound in (1) is N,N-diethylhydroxylamine and the compound in (2) is tertiary butylcatechol.

Claim 6

In a method of inhibiting polymerization of a vinyl aromatic compound comprising adding to the vinyl aromatic compound an amount of an polymerization inhibiting agent effective to substantially reduce the rate of polymerization, the improvement comprising using as the agent a combination of: (a) about 10 to 90 parts of at least one N,N-dialkylhydroxylamine wherein the alkyl groups are the same or different and each alkyl group has 2 to 10 carbon atoms, and (b) about 90 to 10 parts of at least one tertiary alkylcatechol having 4 to 20 alkyl carbon atoms per 100 total parts by weight of the compounds in 8a) and (b).

Claim 7

In a method of inhibiting polymerization of a vinyl aromatic compound comprising adding to the vinyl aromatic compound an amount of an polymerization inhibiting agent effective to substantially reduce the rate of polymerization, the improvement comprising using as the agent a combination of: (a) about 10 to 90 parts of at least one N,N-dialkylhydroxylamine wherein the alkyl groups are the same or different and each alkyl group has 2 to 10 carbon atoms, and (b) about 90 to 10 parts of at least one tertiary alkylcatechol having 4 to 20 alkyl carbon atoms per 100 total parts by weight of the compounds in 8a) and (b).

Claim 8

The improved method of claim 5 wherein said agent is added to the vinyl aromatic compound in a concentration of about 0.5 to 1000 ppm based on the weight of said vinyl aromatic compound.

Claim 9

The improved method of claim 5 wherein each alkyl group of the compound in (a) has 2 to 6 carbon atoms, the tertiary alkyl group of the compound in (b) has 4 to 8 carbon atoms and said agent is added to the vinyl aromatic monomer in a concentration of about 5 to 500 ppm, based on the weight of said vinyl aromatic compound.

Claim 10

The improved method of claim 7 wherein the compound in (a) is N,N-diethythyhydroxylamine and the compound in (b) is tertiary-butylcatechol.

Claim 11

The improved method of claim 5, 6, 7 or 8 wherein the compounds in (a) and (b) are present in amounts of about 25 to 75 parts and 75 to 25 parts by weight, respectively.