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US4409340A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat-curable coating composition, its use and process for coating substrates

Assignee: Axalta Coating Systems Germany GmbH and Co KG
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Filing: 1982-03-01
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Granted: 1983-10-11
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Expires: 2002-03-01
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Abstract

Abstract The invention relates to a heat-curable coating composition, comprising: (A) a prepolymer with ketoxime-blocked NCO groups, which are linked to the prepolymer via cycloaliphatic and/or aliphatic groups, (B) a diamine cross linker, (C) organic solvents in an amount of 0 to 50 weight percent, based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives. The equivalence ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lies between 1.3:1 and 0.75:1. The invention also relates to processes for its application and its use. The composition has a long shelf life and is advantageously used as an impact resistive coating on metal substrates such as automobile parts.

Inventors

  • 👤 Heinrich Stolzenbach
  • 👤 Rudolf Heitzmann
  • 👤 Siegfried Heinrich

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 23:52
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/74; C08G18/75; C08G18/08; C08G18/10; C08G18/73; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31605

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 116 words
Heat-curable coating composition, consisting essentially of (A) a prepolymer with an average molecular weight of 500 to 15,000, which includes on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR5## in which R represents hydrogen or a methyl group, ##STR6## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1.
Claim 2
Dependent Claim 116 words
Heat-curable coating composition, consisting essentially of (A) a prepolymer with an average molecular weight of 500 to 15,000, which includes on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR5## in which R represents hydrogen or a methyl group, ##STR6## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1.
Claim 3
Dependent Claim 42 words
Coating composition according to claim 1, characterized by the fact that the prepolymer of component (A) is the ketoxime-blocked reaction product of a polyether or a polyester having 2 to 6 hydroxyl groups with an isocyanate containing 2 to 3 isocyanate groups.
Claim 4
Dependent Claim 29 words
Process for coating substrates by applying a heat-curable coating composition and curing, characterized by the fact that the coating is carried out with the coating composition of claim 1.
Claim 5
Dependent Claim 26 words
Process according to claim 3, characterized by the fact that the coating is a protective layer on motor vehicles as protection against the impact of stones.
Claim 6
Dependent Claim 24 words
Process according to claim 4, characterized by the fact that the stone-impact protective layer is a layer of a paint system with several layers.
Claim 7
Dependent Claim 31 words
Process according to claim 5, characterized by the fact that a further known coat of paint is applied to the stone-impact protective layer and cured together with the stone-impact protective layer.
Claim 8
Dependent Claim 19 words
Process of using the coating composition according to claim 1 for the production of protective coatings on motor vehicles.
Claim 9
Dependent Claim 18 words
Process according to claim 7 comprising use of the coating composition for the production of stone-impact protective layers.
Claim 10
Dependent Claim 24 words
Process according to claim 8, characterized by the fact that the stone-impact protective layer is a layer of a paint system with several layers.
Claim 11
Dependent Claim 31 words
Process according to claim 9, characterized by the fact that a further known coat of paint is applied on the stone-impact protective layer and cured together with the stone-impact protective layer.
Claim 12
Dependent Claim 134 words
An impact protective paint comprising a heat-curable coating composition, including (A) a prepolymer with an average molecular weight of 500 to 15,000, which includes on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR7## in which R represents hydrogen or a methyl group, ##STR8## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1, said heat-curable coating composition comprising one layer of a paint system of several layers.
Claim 13
Dependent Claim 134 words
An impact protective paint comprising a heat-curable coating composition, including (A) a prepolymer with an average molecular weight of 500 to 15,000, which includes on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR7## in which R represents hydrogen or a methyl group, ##STR8## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1, said heat-curable coating composition comprising one layer of a paint system of several layers.
Claim 14
Dependent Claim 24 words
Paint according to claim 11, wherein the coating composition layer and a further paint layer are cured by curing together in one processing step.
Claim 15
Dependent Claim 11 words
Paint according to claim 11, wherein the coating composition is cured.
Claim 16
Dependent Claim 144 words
Process for coating a protective layer on motor vehicles as protection against the impact of stones which comprise applying a heat-curable coating composition and curing, characterized by the fact that the coating composition includes: (A) a prepolymer with an average molecular weight of 500 to 15,000, which contains on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR9## in which R represents hydrogen or a methyl group, ##STR10## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1.
Claim 17
Dependent Claim 144 words
Process for coating a protective layer on motor vehicles as protection against the impact of stones which comprise applying a heat-curable coating composition and curing, characterized by the fact that the coating composition includes: (A) a prepolymer with an average molecular weight of 500 to 15,000, which contains on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR9## in which R represents hydrogen or a methyl group, ##STR10## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1.
Claim 18
Dependent Claim 21 words
Process according to claim 14, wherein the stone impact protective layer is a layer of a paint system with several layers.
Claim 19
Dependent Claim 31 words
Process according to claim 15, characterized by the fact that a further known coat of paint is applied to the stone impact layer and cured together with the stone impact layer.
Claim 20
Dependent Claim 130 words
A metal part protected by an impact resistant paint which comprises a heat-cured coating composition, including the cured product of (A) a prepolymer with an average molecular weight of 500 to 15,000, which includes on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR11## in which R represents hydrogen or a methyl group, ##STR12## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1.
Claim 21
Dependent Claim 130 words
A metal part protected by an impact resistant paint which comprises a heat-cured coating composition, including the cured product of (A) a prepolymer with an average molecular weight of 500 to 15,000, which includes on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR11## in which R represents hydrogen or a methyl group, ##STR12## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1.
Claim 22
Dependent Claim 25 words
The protected metal part of claim 17, wherein the coating composition and a further paint layer are cured by curing together in one processing step.
Claim 23
Dependent Claim 117 words
An essentially non-aqueous heat-curable coating composition, comprising (A) a prepolymer with an average molecular weight of 500 to 15,000, which contains on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR13## in which R represents hydrogen or a methyl group, ##STR14## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1.
Claim 24
Dependent Claim 117 words
An essentially non-aqueous heat-curable coating composition, comprising (A) a prepolymer with an average molecular weight of 500 to 15,000, which contains on the average 2 to 6 ketoxime-blocked NCO groups, which are linked via cycloaliphatic and/or aliphatic groups to the prepolymer, (B) a cross linker from the group of amines having the formula ##STR13## in which R represents hydrogen or a methyl group, ##STR14## (C) organic solvents in an amount of 0 to 50 weight percent based on the total weight of the coating composition, (D) optionally pigments, fillers, blowing agents and other known additives, the equivalent ratio of blocked NCO groups of component (A) to NH 2 groups of component (B) lying between 1.3:1 and 0.75:1.

References Cited (Backward Citations)

US4299868A Cited
US4248756A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-10 1987-04-11 1987-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-10 1991-04-11 1991-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-10 1995-04-11 1995-10-11 $7700.00 Window Closed / Lapsed

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