US4409199A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Removal of H2 S and COS
Assignee: Shell USA Inc
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Filing: 1981-12-14
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Granted: 1983-10-11
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Expires: 2001-12-14
Abstract
Abstract A process for the removal of H 2 S and COS from gas streams containing high concentrations of H 2 S is described, the process being characterized by close integration of absorption and reaction techniques. In particular, the bulk of the H 2 S is first absorbed from the gas stream, the balance being removed by oxidation after treatment of the stream to hydrolyze the COS.
Inventors
- 👤 George C. Blytas
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 01:22
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/14; B01D53/1493; B01D53/1456; B01D53/1468; C; C01; C01B; C01B17/00; C01B17/16; C01B17/165; C01B17/167
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
205 words
A process for the removal of H 2 S and COS from a sour gaseous stream containing H 2 S and COS comprising: a. contacting the sour gaseous stream in an absorption zone with an aqueous absorbent under conditions to absorb the bulk of the H 2 S, and producing a product gas stream containing a reduced H 2 S concentration and COS, and a loaded absorbent mixture; b. contacting the product gas stream containing COS with a catalyst for the hydrolysis of COS, in the presence of water, and under conditions to react COS and water, and producing a gas stream containing CO 2 and H 2 S; c. removing H 2 S from the gas stream by contacting the gas stream in a first contact zone with an aqueous oxidizing reactant solution which comprises an effective amount of an oxidizing reactant, at a temperature below the melting point of sulfur, and producing a purified gaseous stream and a reactant solution containing sulfur and reduced reactant; d. concomitantly removing loaded absorbent mixture from the absorption zone, and regenerating the loaded absorbent to produce an acid gas stream comprising H 2 S, and a regenerated absorbent; e. and returning regenerated absorbent to the absorption zone.
Claim 2
Dependent Claim
205 words
A process for the removal of H 2 S and COS from a sour gaseous stream containing H 2 S and COS comprising: a. contacting the sour gaseous stream in an absorption zone with an aqueous absorbent under conditions to absorb the bulk of the H 2 S, and producing a product gas stream containing a reduced H 2 S concentration and COS, and a loaded absorbent mixture; b. contacting the product gas stream containing COS with a catalyst for the hydrolysis of COS, in the presence of water, and under conditions to react COS and water, and producing a gas stream containing CO 2 and H 2 S; c. removing H 2 S from the gas stream by contacting the gas stream in a first contact zone with an aqueous oxidizing reactant solution which comprises an effective amount of an oxidizing reactant, at a temperature below the melting point of sulfur, and producing a purified gaseous stream and a reactant solution containing sulfur and reduced reactant; d. concomitantly removing loaded absorbent mixture from the absorption zone, and regenerating the loaded absorbent to produce an acid gas stream comprising H 2 S, and a regenerated absorbent; e. and returning regenerated absorbent to the absorption zone.
Claim 3
Dependent Claim
41 words
The process of claim 1 wherein sulfur is removed from the reactant solution containing sulfur and reduced reactant, the reactant solution is regenerated in a regeneration zone, and regenerated reactant solution containing regenerated reactant is returned to the first contact zone.
Claim 4
Dependent Claim
50 words
The process of claim 1 wherein the reactant solution containing sulfur and reduced reactant is regenerated in a regeneration zone producing a regenerated reactant solution containing sulfur and regenerated reactant, sulfur is removed from said regenerated reactant solution, and the regenerated reactant solution is returned to the first contact zone.
Claim 5
Dependent Claim
91 words
The process of claim 2 wherein the acid gas stream from step (d) is oxidized in an oxidation zone to produce sulfur and offgases, the offgases from the oxidation zone are reduced to produce an offgas-containing H 2 S, and the offgas-containing H 2 S is contacted in a second contact zone with an aqueous oxidizing reactant solution which comprises an effective amount of an oxidizing reactant, at a temperature below the melting point of sulfur, and producing a purified offgas and a second reactant solution containing sulfur and reduced reactant.
Claim 6
Dependent Claim
58 words
The process of claim 4 wherein second reactant containing solution is combined with the reactant solution containing sulfur and reduced reactant produced in step (c), producing a combined stream containing sulfur and reduced reactant, sulfur is removed, the combined stream is regenerated producing a regenerated reactant solution, and regenerated reactant solution is returned to the second contact zone.
Claim 7
Dependent Claim
91 words
The process of claim 3 wherein the acid gas stream from step (d) is oxidized in an oxidation zone to produce sulfur and offgases, the offgases from the oxidation zone are reduced to produce an offgas-containing H 2 S, and the offgas-containing H 2 S is contacted in a second contact zone with an aqueous oxidizing reactant solution which comprises an effective amount of an oxidizing reactant, at a temperature below the melting point of sulfur, and producing a purified offgas and a second reactant solution containing sulfur and reduced reactant.
Claim 8
Dependent Claim
35 words
The process of claim 6 wherein the second reactant solution containing sulfur and reduced reactant is regenerated in the regeneration zone sulfur is removed, and regenerated reactant solution is returned to the second contact zone.
Claim 9
Dependent Claim
117 words
The process of claim 5 wherein the oxidizing reactant comprises an iron chelate of an oxidizing acid having the formula: (X).sub.3-n --N--(Y).sub.n wherein n is a whole number from 1 to 3; Y is an acetic acid or propionic acid group; X is 2-hydroxyethyl, 2-hydroxypropyl, or an alkyl group having from one to four carbon atoms; or ##STR3## wherein: from two to four of the groups Y are selected from acetic and propionic acid groups; from zero to two of the groups Y are selected from 2-hydroxyethyl, 2-hydroxypropyl, and ##STR4## R is ethylene, propylene or isopropylene or alternatively cyclohexane or benzene where the two hydrogen atoms replaced by nitrogen are in the 1,2 position, and mixtures thereof.
Claim 10
Dependent Claim
13 words
The process of claim 8 wherein the aqueous absorbent comprises an aqueous alkanolamine.
Claim 11
Dependent Claim
16 words
The process of claim 9 wherein the iron chelate is the Fe(II) chelate of nitrilotriacetic acid.
Claim 12
Dependent Claim
115 words
The process of claim 7 wherein the oxidizing reactant comprises an oxidizing iron chelate of an acid having the formula: (X).sub.3-n --N--(Y).sub.n wherein n is a whole number from 1 to 3; Y is an acetic acid or propionic acid group; X is 2-hydroxyethyl, 2-hydroxypropyl, or an alkyl group having from one to four carbon atoms; or from two to four of the groups Y are selected from acetic and propionic acid groups; from zero to two of the groups Y are selected from 2-hydroxyethyl, 2-hydroxypropyl, and ##STR5## R is ethylene, propylene or isopropylene or alternatively cyclohexane or benzene where the two hydrogen atoms replaced by nitrogen are in the 1,2 position, and mixtures thereof.
Claim 13
Dependent Claim
13 words
The process of claim 11 wherein the aqueous absorbent comprises an aqueous alkanolamine.
Claim 14
Dependent Claim
16 words
The process of claim 12 wherein the iron chelate is the Fe(III) chelate of nitrilotriacetic acid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-10 | 1987-04-11 | 1987-10-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-10 | 1991-04-11 | 1991-10-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-10 | 1995-04-11 | 1995-10-11 | $7700.00 | Window Closed / Lapsed |