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US4409039A Expired / Lapsed US ⏱️ 0.0 years remaining

High stability printing liquid, intended more particularly for printing by ink jet

Assignee: Hotchkiss Brandt Sogeme HBS SA
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Filing: 1981-03-18
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Granted: 1983-10-11
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Expires: 2001-03-18
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Abstract

Abstract The invention relates to a high stability printing liquid, intended more particularly for printing by ink jet. The ink is in the state of a micro-emulsion formed by a dispersing phase containing a group of inter-compatible constituents and a dispersed phase containing a second group of inter-compatible constituents, the constituents of the first and second groups being incompatible with one another. These two phases are separated by an interfacial liquid containing surfactant molecules in such a way that the dispersed phase is in the form of globules of 500 to 1000 Angstrom. The invention is more particularly applicable to printing by ink jet.

Inventors

  • 👤 Jean P. Lepesant
  • 👤 Georges Tantot

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 15:20
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 70 words
A printing liquid useful in jet ink printing processes which require inks which are macroscopically homogeneous and stable over long periods of time, comprising: a liquid having the structure of a microemulsion comprising a dispersing phase and a dispersed phase, said phases being separated from one another by an interfacial film which isolates the constituents of the two phases in such a way that any danger of flocculation is avoided.
Claim 2
Dependent Claim 70 words
A printing liquid useful in jet ink printing processes which require inks which are macroscopically homogeneous and stable over long periods of time, comprising: a liquid having the structure of a microemulsion comprising a dispersing phase and a dispersed phase, said phases being separated from one another by an interfacial film which isolates the constituents of the two phases in such a way that any danger of flocculation is avoided.
Claim 3
Dependent Claim 24 words
The printing liquid according to claim 1, wherein the dispersed phase is in the form of globules of dimensions between 500 and 1000 Angstrom.
Claim 4
Dependent Claim 46 words
The printing liquid according to claim 1 or 2, wherein the dispersing phase is constituted by a first group of inter-compatible components and the dispersed phase is constituted by a second group of inter-compatible components, whilst the first and second group of constituents are not inter-compatible.
Claim 5
Dependent Claim 17 words
The printing liquid according to claim 1, wherein the interfacial film contains anionic or cationic surfactant molecules.
Claim 6
Dependent Claim 15 words
The printing liquid according to claim 1, wherein the interfacial film contains nonionic surfactant molecules.
Claim 7
Dependent Claim 18 words
The printing liquid according to claim 3, wherein the first group of inter-compatible constituents contains a polar solvent.
Claim 8
Dependent Claim 13 words
The printing liquid according to claim 6, wherein this polar solvent is water.
Claim 9
Dependent Claim 35 words
The printing liquid according to claim 3, wherein the second group of constituents comprises a volatile organic solvent which is incompatible with the polar solvent and a dye which is soluble in said organic solvent.
Claim 10
Dependent Claim 15 words
The printing liquid according to claims 7 or 8, wherein the electrolyte is dimethylammonium chloride.
Claim 11
Dependent Claim 16 words
The printing liquid according to claim 8, wherein the electrolyte is a sodium or ammonium acetate.
Claim 12
Dependent Claim 17 words
The printing liquid according to claim 8, wherein the volatile organic solvent is a light aliphatic ketone.
Claim 13
Dependent Claim 14 words
The printing liquid according to claim 11, wherein this ketone is methyl ethyl ketone.
Claim 14
Dependent Claim 14 words
The printing liquid according to claim 11, wherein this ketone is methyl isobutyl ketone.
Claim 15
Dependent Claim 12 words
The printing liquid according to claim 11, wherein this ketone is cyclohexanone.
Claim 16
Dependent Claim 16 words
The printing liquid according to claim 8, wherein the dye is a chrome complex azo dye.
Claim 17
Dependent Claim 17 words
The printing liquid according to claim 4, wherein the interfacial film is constituted by sodium dodecyl sulphate.
Claim 18
Dependent Claim 16 words
The printing liquid according to claim 5, wherein the interfacial film is an ethoxylated nonyl phenol.
Claim 19
Dependent Claim 14 words
The printing liquid according to claim 4, which has a macroscopically high electrical conductivity.
Claim 20
Dependent Claim 16 words
The printing liquid according to claim 6 or 7, wherein said ink further comprises an electrolyte.
Claim 21
Dependent Claim 40 words
The printing liquid according to claim 7, wherein said liquid nominally contains a weight proportion of 45% water, 5.8% sodium dodecylsulfate, 35.4% methylethylketone and 13.8% of a black dye, whereby said proportions can vary by 10% from the nominal values.
Claim 22
Dependent Claim 42 words
The printing liquid according to claim 7, wherein said liquid nominally contains a weight proportion of 43.5% water, 39.3% methylethylketone, 5.8% sodium dodecylsulfate, 1.0% dimethylammonium chloride and 10.4% black dye, said proportions being able to vary by 10% from their nominal values.
Claim 23
Dependent Claim 38 words
The printing liquid according to claim 7, wherein said liquid nominally contains a weight proportion of 63.1% water, 25.4% methylisobutylketone, 6.3% ethoxylated nonyl phenol and 5.2% black dye, said proportions being variable by 10% from the nominal values.
Claim 24
Dependent Claim 38 words
The printing liquid according to claim 7, wherein said liquid nominally contains a weight proportion of 46% water, 30.2% methylisobutylketone, 13.2% ethoxylated nonyl phenol and 0.6% black dye, said proportions being variable by 10% from their nominal values.
Claim 25
Dependent Claim 91 words
A printing liquid useful in jet ink printing processes which require inks which are macroscopically homogeneous and stable over long periods of time, comprising: a liquid having the structure of a micro-emulsion comprising an aqueous dispersing phase containing water in an amount of 43.5% to 63.1% and optionally and electrolyte and a dispersed phase containing a dye and an organic solvent, said phases being separated from one another by an interfacial film which isolates the constituents of the two phases in such a way that any danger of flocculation is avoided.
Claim 26
Dependent Claim 91 words
A printing liquid useful in jet ink printing processes which require inks which are macroscopically homogeneous and stable over long periods of time, comprising: a liquid having the structure of a micro-emulsion comprising an aqueous dispersing phase containing water in an amount of 43.5% to 63.1% and optionally and electrolyte and a dispersed phase containing a dye and an organic solvent, said phases being separated from one another by an interfacial film which isolates the constituents of the two phases in such a way that any danger of flocculation is avoided.

References Cited (Backward Citations)

DE466207C Cited
GB1097461A Cited
US4165399A Cited
US4155767A Cited
US4256493A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-10 1987-04-11 1987-10-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-10 1991-04-11 1991-10-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-10 1995-04-11 1995-10-11 $7700.00 Window Closed / Lapsed

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