US4408022A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Blend of polyalkylene terephthalate and wholly aromatic polyester and process for producing the same
Assignee: Celanese Corp
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Filing: 1981-12-15
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Granted: 1983-10-04
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Expires: 2001-12-15
Abstract
Abstract A process is provided for forming a novel polymer blend which exhibits an anisotropic melt phase wherein there is chemical interaction between previously formed polymeric blend components to yield a product which is capable of forming shaped articles having highly satisfactory mechanical properties. The process comprises intimately mixing together approximately 50 to 75 percent by weight of polyalkylene terephthalate and 25 to 50 percent by weight of a melt processable polyester which is capable of forming an anisotropic melt phase. A post-polymerization subsequently is conducted in the solid phase in a non-oxidizing atmosphere at a temperature within the range of approximately 250 DEG to 300 DEG C. for a period of time in the range approximately 8 to 72 hours to yield the desired chemical interaction between the previously formed polymeric blend components.
Inventors
- 👤 David E. Cincotta
- 👤 Frank M. Berardinelli
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 02:35
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08G; C08G63/00; C08G63/78; C08G63/80
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
140 words
A process for producing a polymer blend which exibits an anisotropic melt phase and is capable of forming shaped articles having satisfactory mechanical properties, said process comprising the steps of: (a) intimately mixing together approximately 50 to 75 percent by weight of a previously formed polyalkylene terephthalate and approximately 25 to 50 percent by weight of a previously formed melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend, and (b) subsequently subjecting the blend thus formed to post-polymerization, said post-polymerization being conducted in the solid phase in a non-oxidizing atmosphere at a temperature within the range of approximately 250° C. to 300° C. and for a period of time within the range of approximately 8 to 72 hours so as to cause chemical interaction between said previously formed polymeric blend components.
Claim 2
Dependent Claim
140 words
A process for producing a polymer blend which exibits an anisotropic melt phase and is capable of forming shaped articles having satisfactory mechanical properties, said process comprising the steps of: (a) intimately mixing together approximately 50 to 75 percent by weight of a previously formed polyalkylene terephthalate and approximately 25 to 50 percent by weight of a previously formed melt processable wholly aromatic polyester which is capable of forming an anisotropic melt phase apart from the blend, and (b) subsequently subjecting the blend thus formed to post-polymerization, said post-polymerization being conducted in the solid phase in a non-oxidizing atmosphere at a temperature within the range of approximately 250° C. to 300° C. and for a period of time within the range of approximately 8 to 72 hours so as to cause chemical interaction between said previously formed polymeric blend components.
Claim 3
Dependent Claim
40 words
The process of claim 1 wherein said post-polymerization is conducted in the solid phase in a non-oxidizing atmosphere at a temperature within the range of approximately 265° C. to 280° C. for a period of time of approximately 20 hours.
Claim 4
Dependent Claim
123 words
The process of claim 1 wherein said melt processable wholly aromatic polyester is capable of forming an anisotropic melt phase at a temperature below approximately 350° C. apart from said blend and consists essentially of the recurring moieties I and II which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: ##STR6## with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, and mixtures of the foregoing, and wherein said wholly aromatic polyester comprises approximately 10 to 90 mole percent of moiety I and approximately 10 to 90 mole percent of moiety II.
Claim 5
Dependent Claim
73 words
The process of claim 1 wherein said melt processable wholly aromatic polyester is capable of forming an anisotropic melt phase at a temperature below approximately 325° C. apart from said blend and consists essentially of the recurring moieties I, II, and III wherein: ##STR7## wherein said wholly aromatic polyester comprises approximately 30 to 70 mole percent of moiety I, and wherein each of said moieties of said polyester is free of ring substitution.
Claim 6
Dependent Claim
179 words
The process of claim 1 wherein said melt processable wholly aromatic polyester is capable of forming an anisotropic melt phase at a temperature below approximately 400° C. apart from said blend and consists essentially of the recurring moieties I, II, and III which may include substitution of at least some of the hydrogen atoms present upon an aromatic ring wherein: I is ##STR8## II is a dioxyaryl moiety of the formula ##STR9## where Ar is a divalent radical comprising at least one aromatic ring, and III is a dicarboxyaryl moiety of the formula ##STR10## where Ar' is a divalent radical comprising at least one aromatic ring, with said optional substitution if present being selected from the group consisting of an alkyl group of 1 to 4 carbon atoms, an alkoxy group of 1 to 4 carbon atoms, halogen, a phenyl group, and mixtures of the foregoing, and wherein said polyester comprises approximately 10 to 90 mole percent of moiety I, approximately 5 to 45 mole percent of moiety II, and approximately 5 to 45 mole percent of moiety III.
Claim 7
Dependent Claim
19 words
The process of claim 1 wherein the alkylene units of said polyalkylene terephthalate contain 2 to 4 carbon atoms.
Claim 8
Dependent Claim
21 words
The process of claim 6 wherein said polyalkylene terephthalate is selected from the group consisting of polybutylene terephthalate and polyethylene terephthalate.
Claim 9
Dependent Claim
21 words
The process of claim 1 wherein said polyalkylene terephthalate and said wholly aromatic polyester are intimately mixed together by melt extrusion.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-10-03 | 1987-04-04 | 1987-10-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-10-03 | 1991-04-04 | 1991-10-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-10-03 | 1995-04-04 | 1995-10-04 | $7700.00 | Window Closed / Lapsed |