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US4407882A Expired / Lapsed US ⏱️ 0.0 years remaining

Printing ink compositions and use thereof for the production of textured foamed resin materials

Assignee: BASF Corp
•
Filing: 1981-07-13
•
Granted: 1983-10-04
•
Expires: 2001-07-13
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Abstract

Abstract The invention provides a printing ink composition comprising a pigment or pigment preparation, a thermoplastic resin, water, a water-soluble solvent, and, as inhibitor for preventing the foaming of a foamable material containing a blowing agent, an azole of the formula <IMAGE> wherein A is a benzene or naphthalene radical, X is a nitrogen atom or the <IMAGE> group, wherein R is a hydrogen atom or an alkyl group of 1 to 4 carbon atoms, R1 is an alkyl or alkenyl group, each of 1 to 20 carbon atoms, a hydroxyalkyl group of 2 to 20 carbon atoms, an alkoxyalkyl or cyanoalkyl group, each of 3 to 20 carbon atoms, a cycloalkyl group of 5 to 12 carbon atoms, or a phenalkyl group of 7 to 9 carbon atoms, R2 has the same meaning as R1 and can in addition be hydrogen, or R1 and R2, together with the nitrogen atom to which they are attached, form a heterocyclic ring. The inhibitors employed in the printing ink compositions of this invention have the advantage that they do not require a pH regulator, i.e. they can also be used for printing inks having a pH lower than 8, and have the further advantage that they can be more easily incorporated in printing ink compositions, have a better compatibility with aqueous acrylic resins, a better stability in PVC latices, have less influence on the viscosity and have a lower toxicity than aminotriazoles.

Inventors

  • 👤 Hanspeter Hauser
  • 👤 Peter Eckert

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 06:20
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/03; D; D06; D06N; D06N7/00; D06N7/0005; D06N7/0007; D06N7/0013; D06N7/0015; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24479; Y10T428/24496; Y10T428/24504

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 166 words
A printing ink composition comprising a pigment or pigment preparation, a thermoplastic resin, water, a water-soluble organic solvent and an inhibitor for preventing the foaming of a foamable material containing a blowing agent, said inhibitor being an azole of the formula ##STR7## wherein A is a benzene or naphthalene radical, X is a nitrogen atom or the ##STR8## group, wherein R is a hydrogen atom or an alkyl group of 1 to 4 carbon atoms, R 1 is an alkyl or alkenyl group, each of 1 to 20 carbon atoms, a hydroxyalkyl group of 2 to 20 carbon atoms, an alkoxyalkyl or cyanoalkyl group, each of 3 to 20 carbon atoms, a cycloalkyl group of 5 to 12 carbon atoms, or a phenalkyl group of 7 to 9 carbon atoms, R 2 has the same meaning as R 1 and can in addition be hydrogen, or R 1 and R 2 , together with the nitrogen atom to which they are attached, form a heterocyclic ring.
Claim 2
Dependent Claim 166 words
A printing ink composition comprising a pigment or pigment preparation, a thermoplastic resin, water, a water-soluble organic solvent and an inhibitor for preventing the foaming of a foamable material containing a blowing agent, said inhibitor being an azole of the formula ##STR7## wherein A is a benzene or naphthalene radical, X is a nitrogen atom or the ##STR8## group, wherein R is a hydrogen atom or an alkyl group of 1 to 4 carbon atoms, R 1 is an alkyl or alkenyl group, each of 1 to 20 carbon atoms, a hydroxyalkyl group of 2 to 20 carbon atoms, an alkoxyalkyl or cyanoalkyl group, each of 3 to 20 carbon atoms, a cycloalkyl group of 5 to 12 carbon atoms, or a phenalkyl group of 7 to 9 carbon atoms, R 2 has the same meaning as R 1 and can in addition be hydrogen, or R 1 and R 2 , together with the nitrogen atom to which they are attached, form a heterocyclic ring.
Claim 3
Dependent Claim 64 words
A printing ink composition according to claim 1, which contains an azole of the formula ##STR9## wherein R 3 and R 4 are alkyl radicals of 1 to 6 carbon atoms or hydroxyalkyl radicals of 2 to 6 carbon atoms, Y is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or a phenalkyl group of 7 to 9 carbon atoms.
Claim 4
Dependent Claim 33 words
A printing ink composition according to either of claims 1 or 2, which contains an azole of the formula (2), wherein Y is a methyl group which is in the 5- or 6-position.
Claim 5
Dependent Claim 36 words
A printing ink composition according to claim 1, wherein the thermoplastic resin is a water-soluble, emulsifiable or dispersible acrylic resin, polyvinyl chloride or copolymer of vinylchloride and vinyl acetate, polyvinyl acetate, polyvinyl alcohol or a polyurethane.
Claim 6
Dependent Claim 14 words
a printing ink composition according to claim 1, wherein the principal solvent is water.
Claim 7
Dependent Claim 22 words
A printing ink composition according to claim 1, wherein the water-soluble solvent is an aliphatic alcohol containing 1 to 4 carbon atoms.
Claim 8
Dependent Claim 61 words
A printing ink composition according to claim 1 which contains, based on 100 parts by weight of said composition, 1 to 5 parts by weight of pigment, 2 to 20 parts by weight of azole, 15 to 40 parts by weight of resin, 5 to 25 parts by weight of organic solvent, and 5 to 75 parts by weight of water.
Claim 9
Dependent Claim 28 words
A printing ink composition according to claim 5 which contains, based on 100 parts by weight of said composition, 10 to 25 parts by weight of organic solvent.
Claim 10
Dependent Claim 49 words
A method of embossing a heat-foamable, resinous material, which method comprises applying a printing ink composition according to claim 1 to selected areas of the surface of said heat-foamable material containing a blowing agent, and heating said material to a temperature above the decomposition temperature of the blowing agent.
Claim 11
Dependent Claim 8 words
The structured material obtained according to claim 9.

References Cited (Backward Citations)

US3293108A Cited
US3293094A Cited
US3844814A Cited
US4177155A Cited
US4083907A Cited
US4191581A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-03 1987-04-04 1987-10-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-03 1991-04-04 1991-10-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-03 1995-04-04 1995-10-04 $7700.00 Window Closed / Lapsed

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