← Back to Patent Explorer
US4405722A Expired / Lapsed US ⏱️ 0.0 years remaining

Sealing glass compositions

Assignee: Iwaki Glass Co Ltd
•
Filing: 1980-01-02
•
Granted: 1983-09-20
•
Expires: 2000-01-02
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A sealing glass composition containing refractory filler of lower coefficient of thermal expansion for use in sealing alumina package for electronic components is disclosed. The composition consists essentially of low melting glass powder and cordierite powder in proportion of 2-30% by weight of the total composition, and optionally, β-eucryptite, β-spodumen, lead titanate or zircon in a proportion, respectively, not exceeding 15% by weight of the total composition. The low melting glass has a composition of 77.0-86.0 wt. % of PbO, 6.0-15.0 wt. % of B 2 O 3 , 0.5-6.9 wt. % of ZnO, 0.1-3.0 wt. % of SiO 2 , 0-3.0% of Al 2 O 3 0-2.0% of alkali earth metal oxide, 0-1.5% of SnO 2 and 0-1.0% of alkali metal oxide.

Inventors

  • 👤 Yoshinori Kokubu
  • 👤 Jiro Chiba
  • 👤 Nobuyoshi Ichimura
  • 👤 Takashi Iwai
  • 👤 Toshiyasu Kawaguchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 05:47
CPC Classifications
H; H10; H10W; H10W76/00; H10W76/60; C; C03; C03C; C03C14/00; C03C14/004; C03C8/00; C03C8/24; C03C8/245; C03C2214/00; C03C2214/04

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 206 words
In a sealing glass composition, used for sealing an alumina package containing a semiconductor integrated circuit, consisting essentially of low melting glass powder and refractory filler powder of low coefficient of thermal expansion, the improvement wherein said low melting glass has a composition consisting essentially of by weight %: ______________________________________ PbO 77.0-86.0 B.sub.2 O.sub.3 6.0-15.0 ZnO 0.5-6.9 SiO.sub.2 0.1-3.0 Al.sub.2 O.sub.3 0-3.0 MgO, CaO, BaO, SrO 0-2.0 SnO.sub.2 0-1.5 Li.sub.2 O, Na.sub.2 O, K.sub.2 O 0-1.0 ______________________________________ wherein said refractory filler is cordierite in a proportion of 2-30% by weight of the total composition and optionally, β-eucryptite, β-spodumene, lead titanate or zircon in a proportion, respectively, not exceeding 15% by weight of the total composition wherein said sealing glass composition can achieve a matched seal to a material having a thermal expansion coefficient of 65-70×10 -7 ° C. -1 (25°-400° C.) at a non-devitrified state by a heat-treatment at a temperature between 400° C. and 430° C. within a period of 10 minutes and wherein the weight loss of the composition, heat-treated at 400° to 430° C. for 10 minutes, is less than 100 mg/cm 2 when dipped in 5 wt. % nitric acid or 20 wt. % acetic acid for 10 minutes at 25° C.
Claim 2
Dependent Claim 206 words
In a sealing glass composition, used for sealing an alumina package containing a semiconductor integrated circuit, consisting essentially of low melting glass powder and refractory filler powder of low coefficient of thermal expansion, the improvement wherein said low melting glass has a composition consisting essentially of by weight %: ______________________________________ PbO 77.0-86.0 B.sub.2 O.sub.3 6.0-15.0 ZnO 0.5-6.9 SiO.sub.2 0.1-3.0 Al.sub.2 O.sub.3 0-3.0 MgO, CaO, BaO, SrO 0-2.0 SnO.sub.2 0-1.5 Li.sub.2 O, Na.sub.2 O, K.sub.2 O 0-1.0 ______________________________________ wherein said refractory filler is cordierite in a proportion of 2-30% by weight of the total composition and optionally, β-eucryptite, β-spodumene, lead titanate or zircon in a proportion, respectively, not exceeding 15% by weight of the total composition wherein said sealing glass composition can achieve a matched seal to a material having a thermal expansion coefficient of 65-70×10 -7 ° C. -1 (25°-400° C.) at a non-devitrified state by a heat-treatment at a temperature between 400° C. and 430° C. within a period of 10 minutes and wherein the weight loss of the composition, heat-treated at 400° to 430° C. for 10 minutes, is less than 100 mg/cm 2 when dipped in 5 wt. % nitric acid or 20 wt. % acetic acid for 10 minutes at 25° C.
Claim 3
Dependent Claim 28 words
The sealing glass composition claimed in claim 1, wherein said composition consists essentially of 75-97% by weight of said low melting glass and 3-25% by weight of cordierite.
Claim 4
Dependent Claim 56 words
The sealing glass composition claimed in claim 1, wherein said low melting glass has a composition consisting essentially of by weight %: ______________________________________ PbO 80.0-85.0% B.sub.2 O.sub.3 7.0-13.0% ZnO 2.5- 6.5% SiO.sub.2 0.5- 2.5% Al.sub.2 O.sub.3 0- 3.0% MgO, CaO, BaO, SrO 0- 2.0% SnO.sub.2 0 1.5% Li.sub.2 O, K.sub.2 O, Na.sub.2 O 0- 1.0% ______________________________________
Claim 5
Dependent Claim 53 words
The sealing glass composition claimed in claim 1, wherein said composition has a composition essentially of by weight of: ______________________________________ PbO 83.5-85.5% B.sub.2 O.sub.3 10.0-14.0% ZnO 1.5- 3.0% SiO.sub.2 0.35- 0.5% Al.sub.2 O.sub.3 0- 3.0% MgO, CaO, BaO, SrO 0- 2.0% SnO.sub.2 0- 1.5% Li.sub.2 O, Na.sub.2 O, K.sub.2 O 0- 1.0% ______________________________________
Claim 6
Dependent Claim 30 words
The sealing glass composition claimed in claim 1, wherein the coefficient of thermal expansion is 55-72×10 -7 ° C. -1 after heat-treatment at 400° to 430° C. for 10 minutes.
Claim 7
Dependent Claim 30 words
The sealing glass composition claimed in claim 1, wherein the diameter of the flow button is at least 17 cm after heat-treatment at 400° to 430° C. for 10 minutes.
Claim 8
Dependent Claim 31 words
The sealing glass composition claimed in claim 1, wherein the volume resistivity is at least 10 10 ohm-cm at 150° C., after heat-treatment at 400° to 430° C. for 10 minutes.
Claim 9
Dependent Claim 33 words
The sealing glass composition claimed in claim 1, wherein the dielectric constant is less than 20 in a frequency of 1 MHz at 20° C., after heat-treatment at 400°-430° C. for 10 minutes.
Claim 10
Dependent Claim 34 words
The sealing glass composition claimed in claim 1, wherein the transformation point of the glass composition is 285° to 315° C. and the softening point of the glass composition is 335° to 360° C.

References Cited (Backward Citations)

US3951669A Cited
US4133690A Cited
US4006028A Cited
US4115132A Cited
US4186023A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-09-19 1987-03-21 1987-09-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-09-19 1991-03-21 1991-09-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-09-19 1995-03-21 1995-09-20 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag