US4404408A
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Complexed compounds, processes for their manufacture and their use
Assignee: BASF Corp
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Filing: 1977-09-07
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Granted: 1983-09-13
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Expires: 1997-09-07
Abstract
Abstract Metal or metalloid salts, ansolvo-acids and proton-acids can be so complexed with 1,2,3-triols, glycerol ethers or glycerol thioethers containing at least 6 C atoms in the molecule that they are in the form of compositions which are soluble in organic solvents, especially non-polar, aprotic solvents, such as hydrocarbons. These stable compositions display an outstanding anti-static action and, because of their spectrum of properties, are especially suitable for imparting anti-static characteristics to polymers, lubricants, fuels and also solvents based on hydrocarbons.
Inventors
- 👤 Hermann O. Wirth
- 👤 Hans-Helmut Friedrich
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 17:28
CPC Classifications
C; C07; C07C; C07C43/00; C07C43/02; C07C43/03; C07C43/04; C07C43/13; C07C43/135; C07C53/00; C07C53/08; C07C53/10; C08; C08K; C08K5/00; C08K5/0008; C08K5/0075; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/30
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
244 words
A complexed compound of the formula M.sub.n.sup.m.X.sub.m.sup.n.qZ in which M is a proton or a m-valent cation selected from the group consisting of Li + , Na + , K + , Be ++ , Mg ++ , Ca ++ , Ba ++ , Al +++ , Ce +++ , Ti +4 , ZrO ++ , Th +4 , Nb +5 , Cr +++ , Mo +5 , Mn ++ , Fe ++ , Fe +++ , Co ++ , Ni ++ , Cu ++ , Ag + , Zn ++ , Cd ++ , B +++ , Si +4 , Sn ++ , Sn +4 , Pb ++ , Sb +++ , Sb +5 , In +++ , Bi +++ , Hg ++ and Y +3 , X is a n-valent anion selected from the group consisting of hydroxyl, fluoride, chloride, bromide, iodide, thiocyanate, perchlorate, sulfide, thiosulfate, sulfate, acetate, nitrate, hydrogen phosphite, borate, carbonate, sulfite, silicate, hydrogen phosphate, titanate, phosphate, metadisilicate, metasilicate, metatrisilicate, hypophosphinite, metatitanate, methoxy, dihydrogen phosphite, metaborate, zirconate, oxide, metaphosphite, phosphite, trithiocarbonate, methylsulfonate, trifluoromethylsulfonate, octoxycarbonylmethylmercaptide, 2-(octoxycarbonyl)ethylmercaptide and β-carboxyethylmercaptide; m is an integer from 1 to 5, n is an integer from 1 to 4, Z is a chelate-forming compound of the formula R.sup.3 --L--(CH.sub.2 CHOHCH.sub.2 O).sub.x --H where R 3 is alkyl of 3 to 18 carbon atoms, ##STR184## L is O or S, x is an integer from 1 to 3, and q is an integer from 1 to 12.
Claim 2
Dependent Claim
244 words
A complexed compound of the formula M.sub.n.sup.m.X.sub.m.sup.n.qZ in which M is a proton or a m-valent cation selected from the group consisting of Li + , Na + , K + , Be ++ , Mg ++ , Ca ++ , Ba ++ , Al +++ , Ce +++ , Ti +4 , ZrO ++ , Th +4 , Nb +5 , Cr +++ , Mo +5 , Mn ++ , Fe ++ , Fe +++ , Co ++ , Ni ++ , Cu ++ , Ag + , Zn ++ , Cd ++ , B +++ , Si +4 , Sn ++ , Sn +4 , Pb ++ , Sb +++ , Sb +5 , In +++ , Bi +++ , Hg ++ and Y +3 , X is a n-valent anion selected from the group consisting of hydroxyl, fluoride, chloride, bromide, iodide, thiocyanate, perchlorate, sulfide, thiosulfate, sulfate, acetate, nitrate, hydrogen phosphite, borate, carbonate, sulfite, silicate, hydrogen phosphate, titanate, phosphate, metadisilicate, metasilicate, metatrisilicate, hypophosphinite, metatitanate, methoxy, dihydrogen phosphite, metaborate, zirconate, oxide, metaphosphite, phosphite, trithiocarbonate, methylsulfonate, trifluoromethylsulfonate, octoxycarbonylmethylmercaptide, 2-(octoxycarbonyl)ethylmercaptide and β-carboxyethylmercaptide; m is an integer from 1 to 5, n is an integer from 1 to 4, Z is a chelate-forming compound of the formula R.sup.3 --L--(CH.sub.2 CHOHCH.sub.2 O).sub.x --H where R 3 is alkyl of 3 to 18 carbon atoms, ##STR184## L is O or S, x is an integer from 1 to 3, and q is an integer from 1 to 12.
Claim 3
Dependent Claim
166 words
A complexed compound of the formula M.sub.n.sup.m.X.sub.m.sup.n qZ in which M is a proton or a m-valent cation selected from the group consisting of Li + , Na + , K + , Mg ++ , Ca ++ , Ba ++ , Fe ++ , Fe +++ , Co ++ , Ni ++ , Cu ++ , Zn ++ , B +++ , Sn ++ and Sn +4 , X is a n-valent anion selected from the group consisting of hydroxyl, fluoride, chloride, bromide, iodide, sulfate, acetate, nitrate, hydrogen phosphite, borate, carbonate, sulfite, silicate, hydrogen phosphate, phosphate, hypophosphinite, dihydrogen phosphite, phosphite, trithiocarbonate and methylsulfonate, m is an integer from 1 to 4, n is an integer from 1 to 4, Z is a chelate-forming compound of the formula R.sup.3 --L--(CH.sub.2 CHOHCH.sub.2 O).sub.x --H where R 3 is alkyl of 8 to 18 carbon atoms, L is O or S, x is an integer from 1 to 2, and q is an integer from 1 to 12.
Claim 4
Dependent Claim
166 words
A complexed compound of the formula M.sub.n.sup.m.X.sub.m.sup.n qZ in which M is a proton or a m-valent cation selected from the group consisting of Li + , Na + , K + , Mg ++ , Ca ++ , Ba ++ , Fe ++ , Fe +++ , Co ++ , Ni ++ , Cu ++ , Zn ++ , B +++ , Sn ++ and Sn +4 , X is a n-valent anion selected from the group consisting of hydroxyl, fluoride, chloride, bromide, iodide, sulfate, acetate, nitrate, hydrogen phosphite, borate, carbonate, sulfite, silicate, hydrogen phosphate, phosphate, hypophosphinite, dihydrogen phosphite, phosphite, trithiocarbonate and methylsulfonate, m is an integer from 1 to 4, n is an integer from 1 to 4, Z is a chelate-forming compound of the formula R.sup.3 --L--(CH.sub.2 CHOHCH.sub.2 O).sub.x --H where R 3 is alkyl of 8 to 18 carbon atoms, L is O or S, x is an integer from 1 to 2, and q is an integer from 1 to 12.
Claim 5
Dependent Claim
16 words
A compound according to claim 1, of the composition I, which corresponds to the formula ##STR185##
Claim 6
Dependent Claim
16 words
A compound according to claim 1, of the composition I, which corresponds to the formula ##STR186##
Claim 7
Dependent Claim
20 words
A compound according to claim 1, of the composition I, which corresponds to the formula BaSO.sub.4.4i--C.sub.8 H.sub.17 --O--CH.sub.2 --CHOH--CH.sub.2 OH.
Claim 8
Dependent Claim
20 words
A compound according to claim 1, of the composition I, which corresponds to the formula BF.sub.3.2i--C.sub.13 H.sub.27 --OCH.sub.2 --CHOH--CH.sub.2 OH.
References Cited (Backward Citations)
US4089881A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-09-12 | 1987-03-14 | 1987-09-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-09-12 | 1991-03-14 | 1991-09-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-09-12 | 1995-03-14 | 1995-09-13 | $7700.00 | Window Closed / Lapsed |