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US4404389A Expired / Lapsed US ⏱️ 0.0 years remaining

Thiazole containing coumarin compounds

Assignee: BASF SE
•
Filing: 1982-07-29
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Granted: 1983-09-13
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Expires: 2002-07-29
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Abstract

Abstract Compounds of the general formula I ##STR1## where B 2 and B 2 independently of one another are hydrogen, C 1 -C 6 -alkyl which may or may not be interrupted by oxygen or sulfur and is unsubstituted by hydroxyl, C 1 -C 4 -alkoxy, C 1 -C 4 -alkylmercapto, cyano, phenylmercapto (which is unsubstituted by chorine or methyl), unsubstituted or substituted carbamoyl or a carboxylic acid ester group, benzyl or phenylethyl which are unsubstituted or substituted in the ring by chlorine, bromine, methyl, ethyl, methoxy or ethoxy, phenyl which is unsubstituted or substituted by chlorine, bromine, hydroxyl, methoxy, ethoxy, methyl, C 1 -C 4 -alkylmercapto, C 1 -C 4 -alkanoylamino or amino, unsubstituted or substituted carbamoyl or a carboxylic acid ester group, B 2 may in addition be cyano, C 2 -C 4 -alkanoyl, benzoyl which is unsubstituted or substituted by chlorine, methyl, methoxy or ethoxy, C 1 -C 6 -alkylsulfonyl, or phenylsulfonyl, which is unsubstituted or substituted by chlorine, bromine, methyl, methoxy, ethoxy, amino, C 1 -C 4 -alkanoylamino, C 1 -C 4 -alkylsulfonyl or benzoylamino, B 1 and B 2 together may also be a saturated 5-membered or 6-membered ring which may or may not contain oxygen or sulfur, X is oxygen or imino and the ring A may be substituted. Such compounds are outstandingly suitable for dyeing synthetic fibers and plastics.

Inventors

  • 👤 Christos Vamvakaris
  • 👤 Manfred Patsch
  • 👤 Wolfgang Mach

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 19:14
CPC Classifications
D; D06; D06P; D06P1/00; D06P1/90; D06P1/908; C; C09; C09B; C09B57/00; C09B57/02; D06P3/00; D06P3/58; D06P3/60; D06P3/6033; D06P3/6041; D06P5/00; D06P5/003; D06P5/004; D06P5/006

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 297 words
A compound of the formula: ##STR70## wherein B 1 and B 2 independently of one another are hydrogen; C 1 -C 6 alkyl; C 1 -C 6 alkoxy optionally interrupted by oxygen or sulfur; hydroxy; alkylmercapto; C 6 H 5 SCH 2 -- or C 6 H 5 SC 2 H 4 -- optionallly substituted in the phenyl ring by chloro, bromo, hydroxy or alkoxy; COOCH 3 , COOC 2 H 5 , COOC 3 H 7 , COOC 4 H 9 , COOC 5 H 11 , COOC 6 H 13 , COOC 8 H 17 , COOCH 2 --CH═CH 2 , COOC 2 H 4 OCH 3 , COOC 2 H 4 OC 2 H 5 , COOC 2 H 4 OC 4 H 9 , COOC 2 H 4 OC 2 H 4 OCH 3 , COOC 2 H 4 OC 2 H 4 OC 4 H 9 , COOCH 2 CH 2 CH 2 OCH 3 , COOCH 2 CH 2 CH 2 OC 3 H 7 , COO(CH 2 ) 3 OC 2 H 4 OC 6 H 5 , COO(CH 2 ) 3 OCH 2 C 6 H 5 , COOC 2 H 4 SC 2 H 5 OR COOC 2 H 4 SC 6 H 5 ; carbamoyl or substituted carbamoyl; B 2 in addition is cyano, C 2 -C 4 alkanoyl, benzoyl, C 1 -C 4 alkylsulfonyl or phenylsulfonyl; R 1 is hydrogen, C 1 -C 4 alkyl, hydroxy, C 1 -C 4 alkoxy, C-acyloxy, chloro, bromo, amino or substituted amino; R 2 is hydrogen; C 1 -C 4 alkyl, hydroxy, C 1 -C 4 alkoxy or C-acyloxy; R 3 is hydrogen, chloro or bromo; R 1 and R 2 together are --CH═CH--CH═CH-- and X is NH or O.
Claim 2
Dependent Claim 297 words
A compound of the formula: ##STR70## wherein B 1 and B 2 independently of one another are hydrogen; C 1 -C 6 alkyl; C 1 -C 6 alkoxy optionally interrupted by oxygen or sulfur; hydroxy; alkylmercapto; C 6 H 5 SCH 2 -- or C 6 H 5 SC 2 H 4 -- optionallly substituted in the phenyl ring by chloro, bromo, hydroxy or alkoxy; COOCH 3 , COOC 2 H 5 , COOC 3 H 7 , COOC 4 H 9 , COOC 5 H 11 , COOC 6 H 13 , COOC 8 H 17 , COOCH 2 --CH═CH 2 , COOC 2 H 4 OCH 3 , COOC 2 H 4 OC 2 H 5 , COOC 2 H 4 OC 4 H 9 , COOC 2 H 4 OC 2 H 4 OCH 3 , COOC 2 H 4 OC 2 H 4 OC 4 H 9 , COOCH 2 CH 2 CH 2 OCH 3 , COOCH 2 CH 2 CH 2 OC 3 H 7 , COO(CH 2 ) 3 OC 2 H 4 OC 6 H 5 , COO(CH 2 ) 3 OCH 2 C 6 H 5 , COOC 2 H 4 SC 2 H 5 OR COOC 2 H 4 SC 6 H 5 ; carbamoyl or substituted carbamoyl; B 2 in addition is cyano, C 2 -C 4 alkanoyl, benzoyl, C 1 -C 4 alkylsulfonyl or phenylsulfonyl; R 1 is hydrogen, C 1 -C 4 alkyl, hydroxy, C 1 -C 4 alkoxy, C-acyloxy, chloro, bromo, amino or substituted amino; R 2 is hydrogen; C 1 -C 4 alkyl, hydroxy, C 1 -C 4 alkoxy or C-acyloxy; R 3 is hydrogen, chloro or bromo; R 1 and R 2 together are --CH═CH--CH═CH-- and X is NH or O.
Claim 3
Dependent Claim 11 words
The coumarin derivative of claim 1, which has the formula: ##STR71##

References Cited (Backward Citations)

US3539583A Cited
DE2126811A1 Cited
US4055568A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-09-12 1987-03-14 1987-09-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-09-12 1991-03-14 1991-09-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-09-12 1995-03-14 1995-09-13 $7700.00 Window Closed / Lapsed

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