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US4404024A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of magnetic powder

Assignee: Kanto Denka Kogyo Co Ltd
•
Filing: 1981-03-24
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Granted: 1983-09-13
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Expires: 2001-03-24
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Abstract

Abstract The magnetic characteristics of magnetic powder consisting mainly of iron are improved by pre-treating the starting material from which the magnetic powder is prepared by reduction, with an aqueous solution and/or suspension of one member selected from the group consisting of cobalt, nickel, manganese and antimony compounds and mixtures thereof.

Inventors

  • 👤 Shintaro Suzuki
  • 👤 Sadao Iizuka
  • 👤 Yoshimi Moriya

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 17:04
CPC Classifications
H; H01; H01F; H01F1/00; H01F1/01; H01F1/03; H01F1/032; H01F1/04; H01F1/06; H01F1/065; B; B22; B22F; B22F1/00; B22F1/17

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 307 words
A process for producing a magnetic powder consisting essentially of acicular iron particles, said particles being doped with at least one metal selected from the group consisting of Co, Mn, Ni, Ti, Bi, Mo, Ag, Cr, Zn, Si and Al and additionally containing an applied metal selected from the group consisting of cobalt, nickel, manganese and antimony and mixtures thereof, said iron particles being suitable for magnetic recording which comprises the steps of (a) treating finely divided starting material in the form of acicular particles selected from the group consisting of (i) a doped iron oxyhydroxide containing a doping component selected from the group consisting of Co, Mn, Ni, Ti, Bi, Mo, Ag, Cr, Zn, Si, Al and mixtures thereof and (ii) a doped iron oxide containing a doping component selected from the group consisting of Co, Mn, Ni, Ti, Bi, Mo, Ag, Cr, Zn, Si, Al and mixtures thereof with an aqueous solution or suspension of an applied metal compound selected from the group consisting of cobalt, nickel, manganese and antimony compounds and mixtures thereof or a mixture of said solution and said suspension so that said applied metal compound is applied on said particles, (b) filtering said treated particles from the liquid medium to form a cake comprising said treated particles and drying said cake and (c) reducing said dry cake in a reducing gas stream at a temperature up to 600° C. to reduce said treated particles of doped iron oxyhydroxide or doped iron oxide containing said applied metal compound whereby the individual particles are not sintered and the initial shape of the micro-particles of the starting material is retained to form magnetic powder consisting essentially of acicular iron particles doped with at least one metal selected from the group consisting of Co, Mn, Ni, Ti, Bi, Mo, Ag, Cr, Zn, Si and Al.
Claim 2
Dependent Claim 307 words
A process for producing a magnetic powder consisting essentially of acicular iron particles, said particles being doped with at least one metal selected from the group consisting of Co, Mn, Ni, Ti, Bi, Mo, Ag, Cr, Zn, Si and Al and additionally containing an applied metal selected from the group consisting of cobalt, nickel, manganese and antimony and mixtures thereof, said iron particles being suitable for magnetic recording which comprises the steps of (a) treating finely divided starting material in the form of acicular particles selected from the group consisting of (i) a doped iron oxyhydroxide containing a doping component selected from the group consisting of Co, Mn, Ni, Ti, Bi, Mo, Ag, Cr, Zn, Si, Al and mixtures thereof and (ii) a doped iron oxide containing a doping component selected from the group consisting of Co, Mn, Ni, Ti, Bi, Mo, Ag, Cr, Zn, Si, Al and mixtures thereof with an aqueous solution or suspension of an applied metal compound selected from the group consisting of cobalt, nickel, manganese and antimony compounds and mixtures thereof or a mixture of said solution and said suspension so that said applied metal compound is applied on said particles, (b) filtering said treated particles from the liquid medium to form a cake comprising said treated particles and drying said cake and (c) reducing said dry cake in a reducing gas stream at a temperature up to 600° C. to reduce said treated particles of doped iron oxyhydroxide or doped iron oxide containing said applied metal compound whereby the individual particles are not sintered and the initial shape of the micro-particles of the starting material is retained to form magnetic powder consisting essentially of acicular iron particles doped with at least one metal selected from the group consisting of Co, Mn, Ni, Ti, Bi, Mo, Ag, Cr, Zn, Si and Al.
Claim 3
Dependent Claim 18 words
A process as claimed in claim 1 in which the starting material is iron oxyhydroxide doped with Co.
Claim 4
Dependent Claim 16 words
A process as claimed in claim 1 in which the starting material is doped with Co.
Claim 5
Dependent Claim 17 words
A process as claimed in claim 1 in which the metal compound is a water soluble salt.
Claim 6
Dependent Claim 17 words
A process as claimed in claim 1 in which the metal compound is a colloid forming compound.
Claim 7
Dependent Claim 17 words
A process as claimed in claim 1 in which the aqueous solution or suspension contains a surfactant.
Claim 8
Dependent Claim 19 words
A process as claimed in claim 6 in which the surfactant is selected from sodium oleate and sodium alginate.
Claim 9
Dependent Claim 29 words
A process as claimed in claim 1 in which the application of metal said applied compound on the starting material is effected by at least one adsorption and absorption.
Claim 10
Dependent Claim 24 words
A process as claimed in claim 1 in which the application of said applied metal compound on the starting material is effected by deposition.
Claim 11
Dependent Claim 16 words
A process as claimed in claim 1 in which the reducing gas consists essentially of hydrogen.
Claim 12
Dependent Claim 26 words
A process as claimed in claim 1 in which the reduction is carried out at a temperature of from about 200° C. to about 600° C.
Claim 13
Dependent Claim 35 words
A process as claimed in claim 1 which comprises a further step of treating the reduced material with a stream comprising an inert gas and a minor proportion of air to stabilize the product powder.
Claim 14
Dependent Claim 23 words
A process as claimed in claim 12 in which during the stabilization the proportion of air in the treatment stream is gradually increased.
Claim 15
Dependent Claim 13 words
A process as claimed in claim 1 wherein said applied metal is cobalt.
Claim 16
Dependent Claim 13 words
A process as claimed in claim 1 wherein said applied metal is nickel.
Claim 17
Dependent Claim 23 words
A process as claimed in claims 1 or 14 or 15 wherein said reduced acicular magnetic powder consisting essentially of iron is stabilized.
Claim 18
Dependent Claim 40 words
A process as claimed in claim 1 or 14 or 15 wherein said applied metal compound applied on said particles is in an amount from about 1% to about 10% by weight based on the iron content of said particles.
Claim 19
Dependent Claim 36 words
A process as claimed in claim 16 wherein said applied metal compound applied on said particles is in an amount from about 1% to about 10% by weight based on the iron content of said particles.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-09-12 1987-03-14 1987-09-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-09-12 1991-03-14 1991-09-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-09-12 1995-03-14 1995-09-13 $7700.00 Window Closed / Lapsed

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