US4402930A
Expired / Lapsed
US
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Sulfur recovery process
Assignee: Shell USA Inc
•
Filing: 1982-03-01
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Granted: 1983-09-06
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Expires: 2002-03-01
Abstract
Abstract A cyclic process for the removal of hydrogen sulfide, and carbon dioxide, from a variety of gas streams is disclosed. The gas stream containing the sour gas is contacted with reactant solution containing specified reactant materials and a minor amount of a monoalcohol (C n H 2n+1 OH, where n is 4 through 18) crystal modifier. The hydrogen sulfide is converted to sulfur, CO 2 is absorbed to produce a purified gas stream, the reactant material is reduced, and good quality sulfur is produced. The process includes removal of the sulfur and regeneration of the reactant.
Inventors
- 👤 Zaida Diaz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 20:55
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/14; B01D53/1493; B01D53/1418; B01D53/1425; B01D53/1456; B01D53/1462; C; C01; C01B; C01B17/00; C01B17/02; C01B17/04; C01B17/05; Y; Y02; Y02C; Y02C20/00; Y02C20/40; Y02P; Y02P20/00; Y02P20/151
Claims Analysis
Total Claims: 45
Claim 1
Independent Claim
159 words
A process for the removal of H 2 S from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone with an aqueous reactant mixture at a temperature below the melting point of sulfur, the mixture comprising an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the aqueous reactant mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gas stream and an aqueous admixture containing crystalline sulfur and a reduced reactant; (b) removing at least a portion of the crystalline sulfur from the aqueous mixture; (c) regenerating the aqueous admixture in a regeneration zone with oxygen to produce an aqueous reaction mixture containing a regenerated reactant; (d) returning aqueous reaction mixture from the regeneration zone to the contacting zone.
Claim 2
Dependent Claim
159 words
A process for the removal of H 2 S from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone with an aqueous reactant mixture at a temperature below the melting point of sulfur, the mixture comprising an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the aqueous reactant mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gas stream and an aqueous admixture containing crystalline sulfur and a reduced reactant; (b) removing at least a portion of the crystalline sulfur from the aqueous mixture; (c) regenerating the aqueous admixture in a regeneration zone with oxygen to produce an aqueous reaction mixture containing a regenerated reactant; (d) returning aqueous reaction mixture from the regeneration zone to the contacting zone.
Claim 3
Dependent Claim
31 words
The method of claim 1 wherein the stream from which the H 2 S and CO 2 are removed is selected from naturally-occurring gases, synthesis gases, process gases and fuel gases.
Claim 4
Dependent Claim
37 words
The method of claim 1 wherein the sour gaseous stream is selected from natural gas, a stream derived from the gasification of coal, or a hydrocarbon stream, and n is a whole number from 4 through 12.
Claim 5
Dependent Claim
15 words
The process of claim 3 wherein the reactant is the Fe(III) chelate of nitrilotriacetic acid.
Claim 6
Dependent Claim
20 words
The process of claim 4 wherein the modifier is selected from t-butanol, n-pentanol, n-octanol, n-decanol, n-undecanol, n-dodecanol, and mixtures thereof.
Claim 7
Dependent Claim
10 words
The process of claim 4 wherein the modifier is n-decanol.
Claim 8
Dependent Claim
154 words
A process for the removal of H 2 S from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone with an aqueous reactant mixture at a temperature below the melting point of sulfur, the mixture comprising an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the aqueous reactant mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gas stream and an aqueous admixture containing crystalline-sulfur and a reduced reactant; (b) regenerating the aqueous admixture in a regeneration zone with oxygen to produce an aqueous reaction mixture containing a regenerated reactant; (c) removing at least a portion of the crystalline sulfur from the aqueous reaction admixture; (d) returning aqueous reaction mixture from step (c) to the contacting zone.
Claim 9
Dependent Claim
154 words
A process for the removal of H 2 S from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone with an aqueous reactant mixture at a temperature below the melting point of sulfur, the mixture comprising an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the aqueous reactant mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gas stream and an aqueous admixture containing crystalline-sulfur and a reduced reactant; (b) regenerating the aqueous admixture in a regeneration zone with oxygen to produce an aqueous reaction mixture containing a regenerated reactant; (c) removing at least a portion of the crystalline sulfur from the aqueous reaction admixture; (d) returning aqueous reaction mixture from step (c) to the contacting zone.
Claim 10
Dependent Claim
31 words
The method of claim 7 wherein the stream from which the H 2 S and CO 2 are removed is selected from naturally-occurring gases, synthesis gases, process gases and fuel gases.
Claim 11
Dependent Claim
37 words
The method of claim 7 wherein the sour gaseous stream is selected from natural gas, a stream derived from the gasification of coal, or a hydrocarbon stream, and n is a whole number from 4 through 12.
Claim 12
Dependent Claim
15 words
The process of claim 9 wherein the reactant is the Fe(III) chelate of nitrilotriacetic acid.
Claim 13
Dependent Claim
20 words
The process of claim 10 wherein the modifier is selected from t-butanol, n-pentanol, n-octanol, n-decanol, n-undecanol, n-dodecanol, and mixtures thereof.
Claim 14
Dependent Claim
10 words
The process of claim 10 wherein the modifier is n-decanol.
Claim 15
Dependent Claim
199 words
A process for the removal of H 2 S and CO 2 from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone at a temperature below the melting point of sulfur with a lean CO 2 -selective liquid absorbent mixture containing an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the lean CO 2 -selective absorbent mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gaseous stream and an absorbent admixture containing absorbed CO 2 , crystalline sulfur, and reduced reactant; (b) removing at least a portion of the crystalline sulfur from the absorbent admixture, and leaving a solution containing absorbed CO 2 and reduced reactant; (c) stripping the solution containing absorbed CO 2 and said reduced reactant to remove CO 2 and regenerating said solution with oxygen to produce a lean CO 2 -selective liquid absorbent mixture containing regenerated reactant, and (d) returning lean CO 2 -selective liquid absorbent mixture containing regenerated reactant to the contacting zone.
Claim 16
Dependent Claim
199 words
A process for the removal of H 2 S and CO 2 from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone at a temperature below the melting point of sulfur with a lean CO 2 -selective liquid absorbent mixture containing an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the lean CO 2 -selective absorbent mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gaseous stream and an absorbent admixture containing absorbed CO 2 , crystalline sulfur, and reduced reactant; (b) removing at least a portion of the crystalline sulfur from the absorbent admixture, and leaving a solution containing absorbed CO 2 and reduced reactant; (c) stripping the solution containing absorbed CO 2 and said reduced reactant to remove CO 2 and regenerating said solution with oxygen to produce a lean CO 2 -selective liquid absorbent mixture containing regenerated reactant, and (d) returning lean CO 2 -selective liquid absorbent mixture containing regenerated reactant to the contacting zone.
Claim 17
Dependent Claim
31 words
The method of claim 13 wherein the stream from which the H 2 S and CO 2 are removed is selected from naturally-occurring gases, synthesis gases, process gases and fuel gases.
Claim 18
Dependent Claim
37 words
The method of claim 13 wherein the sour gaseous stream is selected from natural gas, a stream derived from the gasification of coal, or a hydrocarbon stream, and n is a whole number from 4 through 12.
Claim 19
Dependent Claim
15 words
The process of claim 15 wherein the reactant is the Fe(III) chelate of nitrilotiacetic acid.
Claim 20
Dependent Claim
20 words
The process of claim 16 wherein the modifier is selected from t-butanol, n-pentanol, n-octanol, n-decanol, n-undecanol, n-dodecanol, and mixtures thereof.
Claim 21
Dependent Claim
10 words
The process of claim 16 wherein the modifier is n-decanol.
Claim 22
Dependent Claim
206 words
A process for the removal of H 2 S and CO 2 from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone at a temperature below the melting point of sulfur with a lean CO 2 -selective liquid absorbent mixture containing an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the lean CO 2 -selective absorbent mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gaseous stream and an absorbent mixture containing absorbed CO 2 , crystalline sulfur, and reduced reactant; (b) stripping the solution containing absorbed CO 2 , crystalline sulfur, and said reduced reactant and regenerating said solution with oxygen and producing a lean CO 2 -selective absorbent mixture containing a regenerated reactant and sulfur, (c) removing sulfur from the lean CO 2 -selective absorbent mixture containing the sulfur and the regenerated reactant, and leaving a lean CO 2 -selective liquid absorbent mixture containing regenerated reactant, and (d) returning the CO 2 -selective liquid absorbent mixture containing regenerated reactant to the contacting zone.
Claim 23
Dependent Claim
206 words
A process for the removal of H 2 S and CO 2 from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone at a temperature below the melting point of sulfur with a lean CO 2 -selective liquid absorbent mixture containing an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the lean CO 2 -selective absorbent mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gaseous stream and an absorbent mixture containing absorbed CO 2 , crystalline sulfur, and reduced reactant; (b) stripping the solution containing absorbed CO 2 , crystalline sulfur, and said reduced reactant and regenerating said solution with oxygen and producing a lean CO 2 -selective absorbent mixture containing a regenerated reactant and sulfur, (c) removing sulfur from the lean CO 2 -selective absorbent mixture containing the sulfur and the regenerated reactant, and leaving a lean CO 2 -selective liquid absorbent mixture containing regenerated reactant, and (d) returning the CO 2 -selective liquid absorbent mixture containing regenerated reactant to the contacting zone.
Claim 24
Dependent Claim
31 words
The method of claim 19 wherein the stream from which the H 2 S and CO 2 are removed is selected from naturally-occuring gases, synthesis gases, process gases and fuel gases.
Claim 25
Dependent Claim
37 words
The method of claim 19 wherein the sour gaseous stream is selected from natural gas, a stream derived from the gasification of coal, or a hydrocarbon stream, and n is a whole number from 4 through 12.
Claim 26
Dependent Claim
15 words
The process of claim 21 wherein the reactant is the Fe(III) chelate of nitrilotriacetic acid.
Claim 27
Dependent Claim
20 words
The process of claim 22 wherein the modifier is selected from t-butanol, n-pentanol, n-octanol, n-decanol, n-undecanol, n-dodecanol, and mixtures thereof.
Claim 28
Dependent Claim
10 words
The process of claim 22 wherein the modifier is n-decanol.
Claim 29
Dependent Claim
201 words
A process for the removal of H 2 S and CO 2 from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone at a temperature below the melting point of sulfur with a lean CO 2 -selective liquid absorbent mixture containing an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the lean CO 2 -selective absorbent mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gaseous stream and an absorbent admixture containing absorbed CO 2 , crystalline sulfur, and reduced reactant; (b) removing at least a portion of the crystalline sulfur from the absorbent admixture, and leaving a solution containing absorbed CO 2 and reduced reactant; (c) stripping the solution containing absorbed CO 2 and said reduced reactant to remove CO 2 , and then regenerating said solution with oxygen to produce a lean CO 2 -selective liquid absorbent mixture containing regenerated reactant, and (d) returning lean CO 2 -selective liquid absorbent mixture containing regenerated reactant to the contacting zone.
Claim 30
Dependent Claim
201 words
A process for the removal of H 2 S and CO 2 from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone at a temperature below the melting point of sulfur with a lean CO 2 -selective liquid absorbent mixture containing an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the lean CO 2 -selective absorbent mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gaseous stream and an absorbent admixture containing absorbed CO 2 , crystalline sulfur, and reduced reactant; (b) removing at least a portion of the crystalline sulfur from the absorbent admixture, and leaving a solution containing absorbed CO 2 and reduced reactant; (c) stripping the solution containing absorbed CO 2 and said reduced reactant to remove CO 2 , and then regenerating said solution with oxygen to produce a lean CO 2 -selective liquid absorbent mixture containing regenerated reactant, and (d) returning lean CO 2 -selective liquid absorbent mixture containing regenerated reactant to the contacting zone.
Claim 31
Dependent Claim
31 words
The method of claim 25 wherein the stream from which the H 2 S and CO 2 are removed is selected from naturally-occurring gases, synthesis gases, process gases and fuel gases.
Claim 32
Dependent Claim
29 words
The method of claim 25 wherein the sour gaseous stream is a stream derived from the gasification of coal, and n is a whole number from 4 through 12.
Claim 33
Dependent Claim
15 words
The process of claim 26 wherein the reactant is the FE(III) chelate of nitrilotriacetic acid.
Claim 34
Dependent Claim
20 words
The process of claim 28 wherein the modifier is selected from t-butanol, n-pentanol, n-octanol, n-decanol, n-undecanol, n-dodecanol, and mixtures thereof.
Claim 35
Dependent Claim
10 words
The process of claim 29 wherein the modifier is n-decanol.
Claim 36
Dependent Claim
207 words
A process for the removal of H 2 S and CO 2 from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone at a temperature below the melting point of sulfur with a lean CO 2 -selective liquid absorbent mixture containing an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the lean CO 2 -selective absorbent mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gaseous stream and an absorbent mixture containing absorbed CO 2 , crystalline sulfur, and reduced reactant; (b) stripping the solution containing absorbed CO 2 , crystalline sulfur, and said reduced reactant, and then regenerating said solution with oxygen and producing a lean CO 2 -selective absorbent mixture containing a regenerated reactant and sulfur. (c) removing sulfur from the lean CO 2 -selective absorbent mixture containing the sulfur and the regenerated reactant, and leaving a lean CO 2 -selective liquid absorbent mixture containing regenerated reactant, and (d) returning the CO 2 -selective liquid absorbent mixture containing regenerated reactant to the contacting zone.
Claim 37
Dependent Claim
207 words
A process for the removal of H 2 S and CO 2 from a sour gaseous stream comprising: (a) contacting the sour gaseous stream in a contacting zone at a temperature below the melting point of sulfur with a lean CO 2 -selective liquid absorbent mixture containing an effective amount of an oxidizing polyvalent metal chelate compound and less than 6 percent by weight, based on the weight of the lean CO 2 -selective absorbent mixture, of a modifier selected from compounds having the formula C n H 2n+1 OH, wherein n is a number from 4 through 18, and mixtures thereof, and producing a sweet gaseous stream and an absorbent mixture containing absorbed CO 2 , crystalline sulfur, and reduced reactant; (b) stripping the solution containing absorbed CO 2 , crystalline sulfur, and said reduced reactant, and then regenerating said solution with oxygen and producing a lean CO 2 -selective absorbent mixture containing a regenerated reactant and sulfur. (c) removing sulfur from the lean CO 2 -selective absorbent mixture containing the sulfur and the regenerated reactant, and leaving a lean CO 2 -selective liquid absorbent mixture containing regenerated reactant, and (d) returning the CO 2 -selective liquid absorbent mixture containing regenerated reactant to the contacting zone.
Claim 38
Dependent Claim
31 words
The method of claim 31 wherein the stream from which the H 2 S and CO 2 are removed is selected from naturally-occurring gases, synthesis gases, process gases and fuel gases.
Claim 39
Dependent Claim
29 words
The method of claim 31 wherein the sour gaseous stream is a stream derived from the gasification of coal, and n is a whole number from 4 through 12.
Claim 40
Dependent Claim
15 words
The process of claim 33 wherein the reactant is the Fe(III) chelate of nitrilotriacetic acid.
Claim 41
Dependent Claim
20 words
The process of claim 34 wherein the modifier is selected from t-butanol, n-pentanol, n-octanol, n-decanol, n-undecanol, n-dodecanol, and mixtures thereof.
Claim 42
Dependent Claim
10 words
The process of claim 35 wherein the modifier is n-decanol.
Claim 43
Dependent Claim
35 words
The process of claims 1 through 12 wherein the modifier is present in an amount of from about 0.01 percent to about 4 percent by weight, based on the weight of the aqueous reactant mixture.
Claim 44
Dependent Claim
37 words
The process of claims 13 through 36 wherein the modifier is present in an amount of from about 0.01 percent to about 4 percent by weight, based on the weight of the CO 2 -selective absorbent mixture.
Claim 45
Dependent Claim
55 words
The process of claims 1 through 12 wherein the modifier is present in an amount of from about 0.01 percent, by weight, based on the weight of the aqueous reactant mixture, to an amount which is at or near the saturation level of the modifier in the reaction solution without forming a significant second phase.
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| 3.5 Years (Year 4) | 1986-09-05 | 1987-03-07 | 1987-09-06 | $2000.00 | Window Closed / Lapsed |
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