Abstract Silica aerogel in the form of a substantially crack-free, preferably transparent block is described, together with a method for the preparation of such aerogel and use thereof in solar panels. The preparation is effected by means of hydrolysis of a tetraalkoxysilane, preferably tetramethoxysilane, in an alcohol, preferably methanol, in the presence of a catalyst, preferably ammonia, for the formation of an alcogel which is aged for approximately 10 days and washed with alcohol for removing water. The alcogel is thereafter treated in an autoclave by means of a temperature increase to above the critical point of the alcohol, isothermic pressure drop by means of the release of alcohol vapor, and temperature drop. The temperature increase, the pressure drop and the temperature drop take place at such low mean rates that the aerogel does not crack. To this end, a total treatment time in the autoclave of at least 24 hours is required. After the autoclave treatment, a heat treatment at 500° to 750° C. is possibly carried out for further improving the transparency of the aerogel.
A product comprising silica aerogel in the form of a moulded, substantially crack-free block with a volume of at least 1 dm 3 , a thickness of at least 1 cm and having pores of approximately 100 A in size, prepared by a method comprising hydrolyzing a silicic acid ester dissolved in an alcohol with water added thereto, in a mould adapted to the desired dimensions, to form a silica alcogel, said hydrolysis being carried out at or below room temperature, washing and aging the alcogel for a period of 2 to 20 days, said washing being performed with an alcohol to remove water from said alcogel, then converting said alcogel to an aerogel by placing it in a closed pressure vessel with alcohol in an amount to at least reach the critical temperature and pressure thereof, subjecting the alcogel-alcohol mixture to a treatment consisting of heating the mixture above the critical point of the alcohol at a mean rate not exceeding 25° C./hr., releasing the alcohol vapor from said vessel to reduce the pressure isothermally at a mean rate not exceeding 10 bars/hr. to atmospheric pressure and then lowering the temperature in said vessel at a mean rate not exceeding 75° C./hr. to ambient temperature, wherein the duration of the treatment in said pressure vessel is at least 24 hours, said silica aerogel block exhibiting a higher transparency than a corresponding block prepared according to said method absent said washing and aging for 2 to 20 days.
Claim 2
Dependent Claim
248 words
A product comprising silica aerogel in the form of a moulded, substantially crack-free block with a volume of at least 1 dm 3 , a thickness of at least 1 cm and having pores of approximately 100 A in size, prepared by a method comprising hydrolyzing a silicic acid ester dissolved in an alcohol with water added thereto, in a mould adapted to the desired dimensions, to form a silica alcogel, said hydrolysis being carried out at or below room temperature, washing and aging the alcogel for a period of 2 to 20 days, said washing being performed with an alcohol to remove water from said alcogel, then converting said alcogel to an aerogel by placing it in a closed pressure vessel with alcohol in an amount to at least reach the critical temperature and pressure thereof, subjecting the alcogel-alcohol mixture to a treatment consisting of heating the mixture above the critical point of the alcohol at a mean rate not exceeding 25° C./hr., releasing the alcohol vapor from said vessel to reduce the pressure isothermally at a mean rate not exceeding 10 bars/hr. to atmospheric pressure and then lowering the temperature in said vessel at a mean rate not exceeding 75° C./hr. to ambient temperature, wherein the duration of the treatment in said pressure vessel is at least 24 hours, said silica aerogel block exhibiting a higher transparency than a corresponding block prepared according to said method absent said washing and aging for 2 to 20 days.