← Back to Patent Explorer
US4401777A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable resin composition comprising N-(alkenylphenyl)maleimide and epoxy composition

Assignee: Mitsui Toatsu Chemicals Inc
•
Filing: 1981-10-20
•
Granted: 1983-08-30
•
Expires: 2001-10-20
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Disclosed is a curable resin composition comprising (a) at least one maleimide compound selected from the group consisting of N-(alkenylphenyl)maleimide derivatives, and dimers and polymers thereof and (b) one or more kinds of epoxy resins, each having at least one epoxy group in the unit molecule thereof. The resin composition may contain, besides the above two components, an amino compound as a further component (c). The resin composition may comprise a prepolymer of any two components among the three components (a), (b) and (c) and the remaining component. The resin compositions are useful as molding materials, for the fabrication of laminates, and as varnishes, including insulation varnishes and impregnating varnishes.

Inventors

  • 👤 Hikotada Tsuboi
  • 👤 Motoo Kawamata
  • 👤 Masayuki Oba
  • 👤 Nobuhito Koga

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 11:36
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/12; C08G73/126; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08G73/121; C08G73/122

Claims Analysis

Total Claims: 29
Claim 1
Independent Claim 262 words
A curable resin composition comprising: (a) at least one N-(alkenylphenyl)maleimide represented by the general formula (I): ##STR6## wherein R 1 -R 6 are the same or different from one another and denote independently hydrogen, a hydrocarbon group having 1-20 carbon atoms, a halogen, R 7 O- or ##STR7## group, where R 7 represents a hydrocarbon group having 1-20 carbon atoms or a hydrocarbon group having 1-20 carbon atoms and substituted by one or more halogen atoms, hydroxyl group, cyano group, or a hydrocarbon group substituted by one or more halogens, R 7 O- or ##STR8## group(where R 7 is as defined above), hydroxyl group or cyano group and having 1-20 carbon atoms prior to the substitution, a plurality of R 4 s are the same or different when m 1 stands for a value of 2 or greater, R 3 is coupled with either R 1 or R 2 , thereby forming a ring, X denotes at least one atom or group selected from hydrogen, halogens, hydroxyl group, ##STR9## groups, where R 7 is as defined above, cyano group, nitro group or carboxyl group, a plurality of Xs are the same or different when m 2 stands for a value of 2 or greater, and m 1 , m 2 and m 3 represent independently a positive integer and m 1 ,+m 2 +m 3 =5, dimers of said maleimides and polymers of said maleimides having a polymerization degree of at least 3; and (b) at least one epoxy compound, each having at least one 1,2-epoxy group in the unit molecule thereof.
Claim 2
Dependent Claim 262 words
A curable resin composition comprising: (a) at least one N-(alkenylphenyl)maleimide represented by the general formula (I): ##STR6## wherein R 1 -R 6 are the same or different from one another and denote independently hydrogen, a hydrocarbon group having 1-20 carbon atoms, a halogen, R 7 O- or ##STR7## group, where R 7 represents a hydrocarbon group having 1-20 carbon atoms or a hydrocarbon group having 1-20 carbon atoms and substituted by one or more halogen atoms, hydroxyl group, cyano group, or a hydrocarbon group substituted by one or more halogens, R 7 O- or ##STR8## group(where R 7 is as defined above), hydroxyl group or cyano group and having 1-20 carbon atoms prior to the substitution, a plurality of R 4 s are the same or different when m 1 stands for a value of 2 or greater, R 3 is coupled with either R 1 or R 2 , thereby forming a ring, X denotes at least one atom or group selected from hydrogen, halogens, hydroxyl group, ##STR9## groups, where R 7 is as defined above, cyano group, nitro group or carboxyl group, a plurality of Xs are the same or different when m 2 stands for a value of 2 or greater, and m 1 , m 2 and m 3 represent independently a positive integer and m 1 ,+m 2 +m 3 =5, dimers of said maleimides and polymers of said maleimides having a polymerization degree of at least 3; and (b) at least one epoxy compound, each having at least one 1,2-epoxy group in the unit molecule thereof.
Claim 3
Dependent Claim 39 words
A curable resin composition as claimed in claim 1, wherein said maleimide compound is at least one maleimide compound selected from the group consisting of N-(p-isopropenylphenyl)maleimide, its dimers and its polymers having a polymerization degree of at least 3.
Claim 4
Dependent Claim 20 words
A curable resin composition as claimed in claim 1, wherein said maleimide compound is at least one dimer of N-(p-isopropenylphenyl)maleimide.
Claim 5
Dependent Claim 21 words
A curable resin composition as claimed in claim 1, wherein said maleimide compound is at least one linear dimer of N-(p-isopropenylphenyl)maleimide.
Claim 6
Dependent Claim 25 words
A curable resin composition as claimed in claim 4, wherein the linear dimer of N-(p-isopropenylphenyl)maleimide is at least one dimer selected from 4-methyl-2,4-bis(p-N-maleimidophenyl)pentene-1 or 4-methyl-2,4-bis(p-N-maleimidophenyl)pentene-2.
Claim 7
Dependent Claim 36 words
A curable resin composition as claimed in claim 1, wherein component (a) is a mixture of N-(p-isopropenylphenyl)maleimide, its dimers, its trimers, and one or more of its polymers having a polymerization degree of at least 4.
Claim 8
Dependent Claim 20 words
A curable resin composition as claimed in claim 6, wherein said mixture contains at least 70% of dimers of N-(p-isopropenylphenyl)maleimide.
Claim 9
Dependent Claim 22 words
A curable resin composition as claimed in claim 1, wherein said epoxy compound include at least one epoxy compound containing benzene rings.
Claim 10
Dependent Claim 20 words
A curable resin composition as claimed in claim 1, wherein said epoxy compound include at least one bisphenol-based epoxy compound.
Claim 11
Dependent Claim 20 words
A curable resin composition as claimed in claim 1, wherein said epoxy compound include at least one novolak-based epoxy compound.
Claim 12
Dependent Claim 24 words
A curable resin composition as claimed in claim 1, wherein the weight ratio of component (b) to component (a) ranges from 3:97 to 97:3.
Claim 13
Dependent Claim 17 words
A curable resin composition as claimed in claim 1, wherein said composition is substantially free of solvent.
Claim 14
Dependent Claim 17 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises an organic solvent.
Claim 15
Dependent Claim 47 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises at least one compound selected from the group consisting of tetrahydrofuran, methylethyl ketone, 1,4-dioxane, acetone, methylisobutyl ketone, dichloromethane, trichloroethane, benzene, toluene, xylene, acetonitrile, 2-methoxyethanol, 2-n-butoxyethanol, 2-ethoxyethylacetate, diethylether, methylcellosolve, ethylcellosolve, N,N-dimethylformamide, N,N-dimethylacetamide and N-methyl-2-pyrrolidone.
Claim 16
Dependent Claim 33 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises at least one compound selected from the group consisting of tetrahydrofuran, methylethyl ketone, 1,4-dioxane, acetone, acetonitrile, methylcellosolve, and ethylcellosolve.
Claim 17
Dependent Claim 23 words
Varnish containing a curable resin composition as claimed in claim 1 and having a resin concentration of from 5 to 80% by weight.
Claim 18
Dependent Claim 23 words
Varnish containing a curable resin composition as claimed in claim 1 and having a resin concentration of from 10 to 70% by weight.
Claim 19
Dependent Claim 42 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises at least one powdery material which is not a resin in a total amout of up to 4 times the total weight of maleimide compounds and epoxy compounds.
Claim 20
Dependent Claim 28 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises a coupling agent in an amount of 0.001-10% by weight of the entire resins.
Claim 21
Dependent Claim 28 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises a coupling agent in an amount of 0.01-5% by weight of the entire resins.
Claim 22
Dependent Claim 40 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises at least one fire retardant and flame resistant agent in an amount of 1-70% by weight of the total weight of maleimide compounds and epoxy compounds.
Claim 23
Dependent Claim 40 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises at least one fire retardant and flame resistant agent in an amount of 5-40% by weight of the total weight of maleimide compounds and epoxy compounds.
Claim 24
Dependent Claim 20 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises a curing agent for component (b).
Claim 25
Dependent Claim 18 words
A curable resin composition as claimed in claim 1, wherein said composition further comprises a radical polymerization initiator.
Claim 26
Dependent Claim 16 words
An article or item obtained by curing a curable resin composition as claimed in claim 1.
Claim 27
Dependent Claim 15 words
A coating film obtained by curing a curable resin composition as claimed in claim 1.
Claim 28
Dependent Claim 15 words
A molded product obtained by curing a curable resin composition as claimed in claim 1.
Claim 29
Dependent Claim 15 words
A laminated product obtained by curing a curable resin composition as claimed in claim 1.

References Cited (Backward Citations)

No citation records indexed.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-29 1987-02-28 1987-08-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-29 1991-02-28 1991-08-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-29 1995-02-28 1995-08-30 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag