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US4401754A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photographic emulsion

Assignee: Konica Minolta Inc
•
Filing: 1981-10-30
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Granted: 1983-08-30
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Expires: 2001-10-30
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Abstract

Abstract A silver halide photographic emulsion characterized in that it comprises silver halide grains which are reduction-sensitized during the process of growing said grains and containing a compound of the formula ##STR1## wherein R 1 and R 2 are selected from the group consisting of a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an acyl group and a cycloalkyl group and R 3 , R 4 , R 5 and R 6 are selected from the group consisting of a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an acyl group, a carboxyl group, an aldehyde group, an amino group, a sulfo group, an alkylthio group, an acylamino group, an aryloxy group, an arylthio group, an alkylamino group, an alkoxycabonyl group and a sulfonamide group. The emulsion exhibits both high sensitivity and improved stability as compared with prior art compositions.

Inventors

  • 👤 Akio Suzuki
  • 👤 Hiroaki Shiozawa
  • 👤 Takeo Koitabashi
  • 👤 Hideki Takiguchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 18:25
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/10; G03C1/34; Y; Y10; Y10S; Y10S430/00; Y10S430/141

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 146 words
A silver halide photographic emulsion characterized in that it comprises silver halide grains reduction-sensitized in a process of growing the silver halide grains, and a compound represented by the following General Formula [I]: ##STR31## (wherein R 1 and R 2 are selected from the group consisting of a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an acyl group and a cycloalkyl group and R 3 , R 4 , R 5 and R 6 are selected from the group consisting of a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an acyl group, a carboxyl group, an aldehyde group, an amino group, a sulfo group, an alkylthio group, an acylamino group, an aryloxy group, an arylthio group, an alkylamino group, an alkoxycabonyl group and a sulfonamide group.)
Claim 2
Dependent Claim 146 words
A silver halide photographic emulsion characterized in that it comprises silver halide grains reduction-sensitized in a process of growing the silver halide grains, and a compound represented by the following General Formula [I]: ##STR31## (wherein R 1 and R 2 are selected from the group consisting of a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, an acyl group and a cycloalkyl group and R 3 , R 4 , R 5 and R 6 are selected from the group consisting of a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, an alkoxy group, an acyl group, a carboxyl group, an aldehyde group, an amino group, a sulfo group, an alkylthio group, an acylamino group, an aryloxy group, an arylthio group, an alkylamino group, an alkoxycabonyl group and a sulfonamide group.)
Claim 3
Dependent Claim 28 words
A silver halide photographic emulsion according to claim 1, the silver halide grains are reduction-sensitized by adding a reducing agent and/or a water-soluble silver salt to the emulsion.
Claim 4
Dependent Claim 20 words
A silver halide photographic emulsion according to claim 1, the silver halide grains are further sensitized by gold and/or sulfur.
Claim 5
Dependent Claim 28 words
A silver halide photographic emulsion according to claim 3, the sensitization by gold and/or sulfur is carried out, after completion of the reduction-sensitization of the silver halide grains.
Claim 6
Dependent Claim 18 words
A silver halide photographic emulsion according to claim 2, the reducing agent is thiourea dioxide or stannous chloride.
Claim 7
Dependent Claim 16 words
A silver halide photographic emulsion according to claim 2, the water-soluble silver salt is silver nitrate.
Claim 8
Dependent Claim 36 words
A method for producing a silver halide photographic emulsion comprising: (1) reduction-sensitizing in a process of growing the silver halide grains and (2) adding a compound according to claim 1 to the silver halide photographic emulsion.
Claim 9
Dependent Claim 23 words
A method according to claim 7, reduction-sensitizing is carried out by adding a reducing agent and/or a water-soluble silver salt to the emulsion.
Claim 10
Dependent Claim 15 words
A method according to claim 8, the reducing agent is thiourea dioxide or stannous chloride.
Claim 11
Dependent Claim 13 words
A method according to claim 8, the water-soluble silver salt is silver nitrate.
Claim 12
Dependent Claim 17 words
A method according to claim 7, the silver halide grains are further sensitized by gold and/or sulfur.
Claim 13
Dependent Claim 27 words
A method according to claim 11, the silver halide grains are further sensitized by gold and/or sulfur after completion of the reduction-sensitization of the silver halide grains.
Claim 14
Dependent Claim 36 words
A light-sensitive silver halide photographic material comprising a support and a silver halide photographic emulsion comprising silver halide grains, reduction-sensitized in a process of growing the silver halide grains, and a compound according to claim 1.
Claim 15
Dependent Claim 29 words
A light-sensitive silver halide photographic material according to claim 13, the silver halide grains are reduction-sensitized by adding a reducing agent and/or a water-soluble silver salt to the emulsion.
Claim 16
Dependent Claim 21 words
A light-sensitive silver halide photographic material according to claim 13, the silver halide grains are further sensitized by gold and/or sulfur.
Claim 17
Dependent Claim 30 words
A light-sensitive silver halide photographic material according to claim 13, the silver-halide grains are further sensitized by gold and/or sulfur after completion of the reduction-sensitization of the silver halide grains.
Claim 18
Dependent Claim 19 words
A light-sensitive silver halide photographic material according to claim 14, the reducing agent is thiourea dioxide or stannous chloride.
Claim 19
Dependent Claim 17 words
A light-sensitive silver halide photographic material according to claim 14, the water-soluble silver salt is silver nitrate.

References Cited (Backward Citations)

US3915715A Cited
US4175968A Cited
US4252893A Cited
US4268621A Cited
US4299909A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-29 1987-02-28 1987-08-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-29 1991-02-28 1991-08-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-29 1995-02-28 1995-08-30 $7700.00 Window Closed / Lapsed

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